GLORIA

GEOMAR Library Ocean Research Information Access

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Publication Date: 2016-03-15
    Description: The detection of existence of fullerenes (C60 and C70) makes it necessary to explore whether soot nanoparticles can participate in new nanometer-sized particle formation and growth in the atmosphere. This study describes a theoretical investigation at multiple levels on the role of the fullerenes (as model compounds to represent nanoparticles of soot) in the formation of complexes with a common atmospheric nucleating precursor (sulfuric acid, SA) and a biogenic organic acid (cis-pinonic acid, CPA), as well as initial growth of nano-sized biogenic aerosols. Quantum chemical density-functional theory calculations identify the formation of stable fullerene-[CPA-SA] ternary complexes, which likely leads to an enhanced nucleation of SA with CPA. Relevant thermochemical parameters including the changes of Gibbs free energy, enthalpy, and entropy for the complex formation also support that fullerene-[CPA-SA] is most likely to be a newly formed nuclei. The sizes of the critical nucleus of the fullerene-[CPA-SA-H2O] systems were found to be approximately 1.3 nm by large-scale molecular dynamics simulations. This study may provide a new insight into the mechanisms underlying the formation of new particle in the atmospheric environment.
    Electronic ISSN: 2073-4433
    Topics: Geosciences
    Published by MDPI Publishing
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 2
    Publication Date: 2017-12-08
    Description: Understanding the magnitude of intra-Asian crustal shortening and the collision age of Lhasa–Qiangtang terranes requires quantitative constraints on the crustal motion. The key to this is defining the palaeogeography of the Tibetan Plateau, which constitutes a poorly known factor over the entire convergence history. New detrital zircon U–Pb geochronological and palaeomagnetic data from the terrestrial Abushan Formation in the Qiangtang terrane demonstrate that central Tibet was located at 27.5 ± 3.0°N during the time interval of ~111–83 Ma. Our results suggest 7.5 ± 2.9° continental shortening has occurred between central Qiangtang and Mongolia during the India–Asia convergence. Declination anomaly indicates the central Qiangtang terrane has experienced significant clockwise rotation (57.3 ± 3.9°) relative to stable Eurasia. The compilation of palaeomagnetic results since the Cretaceous reveals ~8.5° northward drift of the Lhasa terrane from 123 ± 9 to 97 ± 7 Ma and the palaeolatitudinal overlap between the Lhasa and Qiangtang terranes after ~111–103 Ma. Together with the onset age of the terrestrial Abushan Formation, our results provide the youngest timing ( ca. ~111–103 Ma) for the closure of the Bangong Meso-Tethys Ocean, as well as for the final collision of the Lhasa and Qiangtang terranes.
    Print ISSN: 0072-1050
    Electronic ISSN: 1099-1034
    Topics: Geosciences
    Published by Wiley-Blackwell
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 3
    Publication Date: 2017-11-21
    Description: Hydrogen band electromagnetic ion cyclotron (EMIC) waves have received much attention recently because they are found to frequently span larger spatial areas than the other band EMIC waves. Using test particle simulations, we study the nonlinear effects of hydrogen band EMIC waves on ring current H + ions. A dimensionless parameter R is used to characterize the competition between wave-induced and adiabatic motions. The results indicate that there are three regimes of wave-particle interactions for typical 35 keV H + ions at L =5: diffusive (quasi-linear) behavior when α eq ≤ 35° ( R ≥ 2.45), the nonlinear phase trapping when 35° 〈 α eq 〈 50° (0.75 〈 R 〈 2.45), and both the nonlinear phase bunching and phase trapping when α eq ≥ 50° ( R ≤ 0.75). The phase trapping can transport H + ions towards large pitch angle, while the phase bunching has the opposite effect. The phase trapped H + ions can be significantly accelerated (from 35 keV to over 500 keV) in about 4 minutes, and thus contribute to the formation of high energy components of ring current ions. The results suggest that the effect of hydrogen band EMIC waves is not ignorable in the nonlinear acceleration and resonance scattering of ring current H + ions.
    Print ISSN: 0094-8276
    Electronic ISSN: 1944-8007
    Topics: Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 4
    Publication Date: 2018-10-12
    Description: In order to explore the thermal kinetics of nano Al-micro MnO 2 thermite system, the Al/MnO 2 thermite sample was mixed by the ultrasonic dispersion method. On the basis of the study of thermal decomposition of MnO 2 powder, the thermal performance of the sample was study by simultaneous thermal analysis technique at the temperature range from room temperature to 1000°C, which could found the thermite reaction occurred in 650-660°C before the melting of Al, which belongs to solid state reactions with the 350 J/g heat releasing. Besides, the microstructure changes of the thermite during reaction were observed by field emission scanning electron microscope (FE-SEM). Based on the TG-DSC test with multiple heating rates and using of the activation energy calculated by Kissniger method, it could be proved the sample had good stability and safety performance.
    Print ISSN: 1755-1307
    Electronic ISSN: 1755-1315
    Topics: Geography , Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 5
    Publication Date: 2018-10-12
    Description: To explore the reaction characteristics and mechanism of Al/MnO 2 thermite, selecting the high purity micron grade Al and MnO 2 powder, the Al/MnO 2 thermite sample was mixed by the ultrasonic dispersion method. On the basis of the study of thermal decomposition of MnO 2 powder, the thermal performance of the sample was study by simultaneous thermal analysis technique at the temperature range from room temperature to 900°C, and the reaction products were analyzed by X-ray diffraction (XRD). The microstructure changes of the thermite during reaction were observed by field emission scanning electron microscope (FE-SEM). The results showed that the MnO 2 has two processes of thermal decomposition during the temperature rising, and the reaction products were Mn 2 O 3 and Mn 3 O 4 , and the onset temperature were 498.3°C and 781.5°C, the heat release were - 197.1J/g and -57.4 J/g, respectively. Al/...
    Print ISSN: 1755-1307
    Electronic ISSN: 1755-1315
    Topics: Geography , Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 6
    Publication Date: 2017-07-03
    Description: Mining tailings as a raw material for preparing autoclaved bricks have attracted much attention. The tailings subjected to milling always have the characteristic of fine granularity. However, the proportion of the fine aggregates in autoclaved bricks was very low using the current gradation formula, which impeded the utilization of the tailings. In this work, a novel model of aggregate gradation for autoclaved bricks from tailings has been presented, which was established through the following steps: (1) 91 groups of autoclaved bricks with different aggregate gradations were prepared, with the proportion of the fine aggregates (−0.15 mm) in the range of 40% to 100%; and (2) the particle size distributions of the finest and coarsest aggregates in the high-strength region were fitted to establish the model. The proportion of the fine aggregates calculated by the model could increase significantly compared with that using the current formula. To verify the novel model, autoclaved bricks from iron ore tailings were prepared using the model, with their mechanical and freezing resistance properties meeting the requirement of the highest-strength level. It was observed by SEM that the autoclaved bricks had compact structures with a few small pores owing to the reasonable aggregate gradation.
    Electronic ISSN: 2075-163X
    Topics: Geosciences
    Published by MDPI Publishing
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 7
    Publication Date: 2015-04-17
    Description: For scientific and sustainable management of water resources, hydrologic and meteorologic data series need to be often extended. This paper proposes a hybrid approach, named WA-CM (Wavelet Analysis-Cloud Model), for data series extension. Wavelet analysis has time-frequency localization features, known as ‘mathematics microscope,’ that can decompose and reconstruct hydrologic and meteorologic series by wavelet transform. The cloud model is a mathematical representation of fuzziness and randomness, and has strong robustness for uncertain data. The WA-CM approach first employs the wavelet transform to decompose the measured non-stationary series and then uses the cloud model to develop an extension model for each decomposition layer series. The final extension is obtained by summing the results of extension of each layer. Two kinds of meteorologic and hydrologic data sets with different characteristics and different influence of human activity from 6 (3 pairs) representative stations are used to illustrate the WA-CM approach. The approach is also compared with four other methods, which are conventional Correlation Extension (CE) method, Kendall-Theil Robust Line method (KTRL), Artificial Neural Network (ANN) method (BP, MLP and RBF), and single Cloud Model (CM) method. To evaluate the model performance completely and thoroughly, five measures are used, which are RE, MRE, SD-RE, RMSE and TIC. Results show that the WA-CM approach is effective, feasible and accurate, and is found to be better than other four methods compared. The theory employed and the approach developed here can be applied to extension of data in other areas as well.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 8
    Publication Date: 2015-12-22
    Description: The discovery of natural gas reservoirs with high and varying CO 2 content (5% to 98%) in China has attracted worldwide attention. In this paper, the phase diagram of natural gas with different CO 2 content was calculated and drawn by PVT Sim 100 which was fitted by experimental data based on the Ruska PVT 2730 apparatus. Both the real critical parameters and the pseudo-critical para­meters were calculated and compared. Also, the phase state of natural gas along the wellbore in a representative well under both shut-in and flowing conditions was analyzed. In addition, to clarifying the phase transition process, videos of a gas sample showed variation between supercritical state to gas-liquid state with isobaric cooling and heating up between 35°C and 25°C. Moreover, the compressibility factor (Z-factor) of the natural gas with different CO 2 content was chosen as one of the key physical parameters of natural gas to measure at pressures ranging from atmospheric pressure to 45 MPa and temperatures ranging from 40°C to 140°C experimentally. Results show that the Z factor decreases with the increase of CO 2 content in natural gas at isothermal conditions, and increases with the increase of temperature. Furthermore, a new model is proposed to predict pressure and Z factor. The varying CO 2 -CH 4 concentrations of this reservoir are relevant to gas compositions which may arise in depleted natural gas reservoirs used for geologic carbon sequestration. © 2015 Society of Chemical Industry and John Wiley & Sons, Ltd
    Electronic ISSN: 2152-3878
    Topics: Energy, Environment Protection, Nuclear Power Engineering , Geosciences
    Published by Wiley-Blackwell
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 9
    Publication Date: 2016-12-13
    Description: The generation of secondary convection, following an earlier episode of convection, within a heavy-rain-producing mesoscale convective system (MCS) along a mei-yu front in eastern China on 6-8 July 2013 is studied based on convection-permitting WRF simulations. The initiation of the secondary convection is found to be directly linked to the downward development of a mesoscale convective vortex (MCV) spawn by the MCS. In the early and mature stage, the MCV center is located at the middle troposphere; it descends gradually with time as the parent MCS began to decay, with the associated convection transitioning from deep to shallow convection. The descent of the MCV occurs in response to the lowering of the maximum diabatic heating within the convective system, which increases positive potential vorticity down below. When the MCV reaches the lower troposphere, it becomes coupled with the prefrontal southwesterly low-level jet (LLJ). The confluence of the MCV rotational flow with the LLJ notably enhances the convergence on the southern flank of the MCV, where the secondary convection is triggered and swapped through the southeastern flank of the MCV. Unlike that found in the MCV of the U.S. central plains, the cold pool produced by the mei-yu frontal MCS is rather weak and shallow, and appears to play only a minor role in promoting convection. The balanced isentropic lifting by the MCV circulation is also weak, although the MCV circulation does help localize the secondary convection.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
  • 10
    Publication Date: 2017-02-03
    Description: How the materials derived from the stagnant Pacific slab contributed to the mantle sources of the mafic rocks in east China is still in hot debate. In this work, δ 18 O (V-SMOW) values of clinopyroxene phenocrysts in the OIB type mafic rocks from 106 Ma to 60 Ma in the east North China Craton (NCC) were measured by secondary ion mass spectrometry (SIMS). Our data show that for all of the samples, the δ 18 O cpx are dominantly higher than that of the cpx from N-MORB (5.4 ~ 5.8‰), which confirms the role of recycled oceanic crust (ROC) in their mantle sources. Combining the δ 18 O data of basalts and the lithospheric mantle in the literature, we found that in the southeast NCC, upper and lower ROC components alternately appeared in the mantle sources of basalts, but these ROC components are consistently different from that in the lithospheric mantle, while in the northern NCC, the recycled components in the sources seem to be persistently from upper ROC. These observations suggest that 1) these mafic OIB-type rocks are most likely derived from the convective asthenosphere and 2) the contribution of components from the Pacific oceanic slab into the NCC upper mantle was dynamic, without a simple temporal trend. This new knowledge calls for the reconsideration of the existing models of the thinning process of the NCC lithospheric mantle, and it warns against simply using the chemical composition of basalts to infer the evolution of lithosphere.
    Print ISSN: 0148-0227
    Topics: Geosciences , Physics
    Location Call Number Limitation Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...