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  • Wiley  (232)
  • 2015-2019  (232)
  • 1
    Online Resource
    Online Resource
    Oxyresveratrol, a Stilbene Compound from Morus alba L. Twig Extract Active Against Trichophyton rubrum
    Wiley ; 2017
    In:  Phytotherapy Research Vol. 31, No. 12 ( 2017-12), p. 1842-1848
    Details
    In: Phytotherapy Research, Wiley, Vol. 31, No. 12 ( 2017-12), p. 1842-1848
    Abstract: Morus alba L. (mulberry) twig is known to have an inhibitory effect on pathogens in traditional Chinese medicine. In the present study, the dermophytic fungus, Trichophyton rubrum , was used to evaluate the inhibitory effect of total M. alba twig extract and extracts obtained using solvents with different polarities by the method of 96‐well MTT colorimetry. The main active substance was isolated and identified by tracking its activity. In addition, the inhibitory effects of active extracts and a single active substance were investigated in combination with miconazole nitrate. Our data indicated that ethyl acetate extracts of mulberry twig (TEE) exhibited a desired inhibitory activity on T. rubrum with the minimum inhibitory concentration (MIC) of 1.000 mg/mL. With activity tracking, the main substance showing antimicrobial activity was oxyresveratrol (OXY), which was isolated from TEE. Its MIC for inhibiting the growth of T. rubrum was 0.500 mg/mL. The combined use of miconazole nitrate and OXY showed a synergistic inhibitory effect, as shown by a significant decrease in the MIC of both components. Based on the OXY content in TEE, the contribution rate of OXY to the inhibitory effect of TEE on T. rubrum was 80.52%, so it was determined to be the main antimicrobial substance in M. alba twig. Copyright © 2017 John Wiley & Sons, Ltd.
    Type of Medium: Online Resource
    ISSN: 0951-418X , 1099-1573
    URL: Issue
    URL: Article
    DOI: 10.1002/ptr.v31.12
    DOI: 10.1002/ptr.5926
    Language: English
    Publisher: Wiley
    Publication Date: 2017
    detail.hit.zdb_id: 1493490-5
    SSG: 15,3
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  • 2
    Online Resource
    Online Resource
    Hydrogen gas reduces chronic intermittent hypoxia‐induced hypertension by inhibiting sympathetic nerve activity and increasing vasodilator responses via the antioxidation
    Wiley ; 2019
    In:  Journal of Cellular Biochemistry Vol. 120, No. 3 ( 2019-03), p. 3998-4008
    Details
    In: Journal of Cellular Biochemistry, Wiley, Vol. 120, No. 3 ( 2019-03), p. 3998-4008
    Abstract: Molecular hydrogen is reported to be used medically to ameliorate various systemic pathological conditions. This study aimed to investigate the effect of hydrogen (H 2 ) gas on hypertension induced by intermittent hypoxia in rats. The adult rats were exposed to chronic intermittent hypoxia (CIH) 8 hours/day for 5 weeks and/or H 2 gas 2 hours/day. We found that the systolic and diastolic blood pressure (BP) increased significantly in rats exposed to intermittent hypoxia, both of which were markedly attenuated after H treatment. Furthermore, intermittent hypoxia exposure elevated renal sympathetic nerve activity, consistent with plasma norepinephrine. Additionally, H 2 gas significantly improved CIH‐induced abnormal vascular relaxation. Nevertheless, inhalation of H 2 gas alone did not cause such changes. Moreover, H 2 gas‐treated rats exposed to CIH showed a significant reduction in 8‐hydroxy‐2 deoxyguanosine content and increases in superoxide dismutase activity, indicating improved oxidative stress. Taken together, these results indicate that H 2 gas has significant effects on the reduction of BP without any side effects. Mechanistically, inhibition of sympathetic activity and reduction of systemic vascular resistance may participate in this process via the antioxidant activity of H 2 .
    Type of Medium: Online Resource
    ISSN: 0730-2312 , 1097-4644
    URL: Issue
    URL: Article
    DOI: 10.1002/jcb.v120.3
    DOI: 10.1002/jcb.27684
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 1479976-5
    SSG: 12
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  • 3
    Online Resource
    Online Resource
    Rapid and sensitive detection of the phenoxy acid herbicides in environmental water samples by magnetic solid‐phase extraction combined with liquid chromatography–tandem mass spectrometry
    Wiley ; 2018
    In:  Journal of Separation Science Vol. 41, No. 10 ( 2018-05), p. 2221-2228
    Details
    In: Journal of Separation Science, Wiley, Vol. 41, No. 10 ( 2018-05), p. 2221-2228
    Abstract: Phenoxy acid herbicides are widely used herbicides that play an important role in improving the yield and quality of crops. However, some research has shown that this kind of herbicide is poisonous to human and animals. In this study, a rapid and sensitive method was developed for the detection of seven phenoxy acid herbicides in water samples based on magnetic solid‐phase extraction followed by liquid chromatography and tandem mass spectrometry. Magnetic amino‐functionalized multiwalled carbon nanotubes were prepared by mixing bare magnetic Fe 3 O 4 nanoparticles with commercial amino‐functionalized multiwalled carbon nanotubes in water. Then the amino‐functionalized multiwalled carbon nanotubes were used to enrich phenoxy acid herbicides from water samples based on hydrophobic and ionic interactions. The effects of experimental variables on the extraction efficiency have been studied in detail. Under the optimized conditions, the method validation was performed. Good linearities for seven phenoxy acid herbicides were obtained with squared regression coefficients ranging from 0.9971 to 0.9989. The limits of detection ranged from 0.01 to 0.02 μg/L. The method recoveries of seven phenoxy acid herbicides spiked at three concentration levels in a blank sample were from 92.3 to 103.2%, with inter‐ and intraday relative standard deviations less than 12.6%.
    Type of Medium: Online Resource
    ISSN: 1615-9306 , 1615-9314
    URL: Issue
    URL: Article
    DOI: 10.1002/jssc.v41.10
    DOI: 10.1002/jssc.201701325
    RVK:
    VA 5450
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2047990-6
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  • 4
    Online Resource
    Online Resource
    Reaction Mechanism of 3,4‐Dinitrofuroxan Formation from Glyoxime: Dehydrogenation and Cyclization of Oxime
    Wiley ; 2016
    In:  ChemPhysChem Vol. 17, No. 4 ( 2016-02), p. 541-547
    Details
    In: ChemPhysChem, Wiley, Vol. 17, No. 4 ( 2016-02), p. 541-547
    Abstract: The reaction pathway of the formation of 3,4‐dinitrofuroxan from glyoxime is theoretically investigated under experimental conditions with 25 % nitric acid and dinitrogentetroxide reagents to clarify the mechanism of formation of a furoxan ring by glyoxime. The geometric configurations of minima and transition‐state species are optimized at the (U)B3LYP/6‐311++G** level. The CCSD(T) and CASSCF(10e,8o)/CASSCF(9e,8o) single‐point energy corrections at the same level are performed on top of the optimized geometries. A subsequent dynamic correlation by using NEVPT2/6‐311++G**‐level single‐point energy calculations based on the CASSCF results is also performed to obtain accurate energy values. The formation reaction is analyzed from two processes: glyoxime nitration and 3,4‐dinitroglyoxime (nitration product) oxidative cyclization. Calculation results indicate that the electrophilic substitution of nitronium ions from the protonated HNO 3 and the abstraction of hydrogen ions by HNO 3 molecules are requisites of glyoxime nitration. The formation of a furoxan ring from 3,4‐dinitroglyoxime involves two possible mechanisms: 1) oxydehydrogenation by NO 2 molecules and the subsequent torsion of NO radical groups to form a ring and 2) the alternation of dehydrogenation and cyclization. The intermediates and transition states in both routes exhibit monoradical and diradical characteristics. Singlet and triplet reactions are considered for the diradical species. Results show that the singlet reaction mechanism is more favorable for cyclization than the triplet reaction. The formation of a furoxan ring from oxime is in accordance with the stepwise intermolecular dehydrogenation and intramolecular torsion to the ring.
    Type of Medium: Online Resource
    ISSN: 1439-4235 , 1439-7641
    URL: Issue
    URL: Article
    DOI: 10.1002/cphc.v17.4
    DOI: 10.1002/cphc.201500968
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 2025223-7
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  • 5
    Online Resource
    Online Resource
    Suppressing the P2–O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium‐Ion Batteries
    Wiley ; 2016
    In:  Angewandte Chemie International Edition Vol. 55, No. 26 ( 2016-06-20), p. 7445-7449
    Details
    In: Angewandte Chemie International Edition, Wiley, Vol. 55, No. 26 ( 2016-06-20), p. 7445-7449
    Abstract: Room‐temperature sodium‐ion batteries (SIBs) have shown great promise in grid‐scale energy storage, portable electronics, and electric vehicles because of the abundance of low‐cost sodium. Sodium‐based layered oxides with a P2‐type layered framework have been considered as one of the most promising cathode materials for SIBs. However, they suffer from the undesired P2–O2 phase transition, which leads to rapid capacity decay and limited reversible capacities. Herein, we show that this problem can be significantly mitigated by substituting some of the nickel ions with magnesium to obtain Na 0.67 Mn 0.67 Ni 0.33− x Mg x O 2 (0≤ x ≤0.33). Both the reversible capacity and the capacity retention of the P2‐type cathode material were remarkably improved as the P2–O2 phase transition was thus suppressed during cycling. This strategy might also be applicable to the modulation of the physical and chemical properties of layered oxides and provides new insight into the rational design of high‐capacity and highly stable cathode materials for SIBs.
    Type of Medium: Online Resource
    ISSN: 1433-7851 , 1521-3773
    URL: Issue
    URL: Article
    DOI: 10.1002/anie.v55.26
    DOI: 10.1002/anie.201602202
    RVK:
    VA 2100
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 2011836-3
    detail.hit.zdb_id: 123227-7
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  • 6
    Online Resource
    Online Resource
    Motor dual‐task T imed U p & G o test better identifies prefrailty individuals than single‐task T imed U p & G o test
    Wiley ; 2015
    In:  Geriatrics & Gerontology International Vol. 15, No. 2 ( 2015-02), p. 204-210
    Details
    In: Geriatrics & Gerontology International, Wiley, Vol. 15, No. 2 ( 2015-02), p. 204-210
    Abstract: The present study investigated whether dual‐task T imed U p & G o tests ( TUG ) could identify prefrail individuals more sensitively than the single‐task TUG ( TUG single ) in community‐dwelling middle‐aged and older adults. Methods This cross‐sectional study recruited adults aged 50 years and older who actively participated in local community programs. Time taken to complete single‐task TUG and dual‐task TUG , carrying a cup of water ( TUG manual ) or carrying out serial‐3 subtraction ( TUG cognitive ) while executing TUG , was measured. Prefrailty status was defined based on F ried's phenotypic definition. Results Of the 65 participants (mean age 71.5 ± 8.1 years), 33.3% of the 12 middle‐aged (50–64 years) and 62.3% of the 53 older (≥65 years) adults were prefrail, mainly as a result of weak grip strength. The receiver operating characteristic curve analyses for differentiating prefrailty from non‐frailty showed that the area under the curve ( AUC ) for TUG manual (0.73, 95% CI 0.60–0.86) was better than that for TUG single (0.67, 95% CI 0.54–0.80), whereas the AUC value was not significant for TUG cognitive (0.60, 95% CI 0.46–0.74). The optimal cut‐off points for detecting prefrailty using TUG single , TUG manual and TUG cognitive were 7.7 s (sensitivity 68%), 8.2 s (sensitivity 83%), and 14.3 s (sensitivity 29%), respectively. After adjusting for age, logistic regression analyses showed that individuals with TUG manual 8.2 s or slower were 7.2‐fold more likely to have prefrailty than those with TUG manual faster than 8.2 s. Conclusion TUG manual is more valid and sensitive than TUG single in identifying prefrail individuals. The TUG manual thus could serve as a screening tool for early detection of individuals with prefrailty in community‐dwelling middle‐aged and older adults. Geriatr Gerontol Int 2015; 15: 204–210.
    Type of Medium: Online Resource
    ISSN: 1444-1586 , 1447-0594
    URL: Issue
    URL: Article
    DOI: 10.1111/ggi.2015.15.issue-2
    DOI: 10.1111/ggi.12258
    Language: English
    Publisher: Wiley
    Publication Date: 2015
    detail.hit.zdb_id: 2078308-5
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  • 7
    Online Resource
    Online Resource
    Tumour necrosis factor‐α‐induced protein 8‐like 2 is a novel regulator of proliferation, migration, and invasion in human rectal adenocarcinoma cells
    Wiley ; 2019
    In:  Journal of Cellular and Molecular Medicine Vol. 23, No. 3 ( 2019-03), p. 1698-1713
    Details
    In: Journal of Cellular and Molecular Medicine, Wiley, Vol. 23, No. 3 ( 2019-03), p. 1698-1713
    Abstract: Tumour necrosis factor‐α‐induced protein 8‐like 2 (TIPE2) is a tumour suppressor in many types of cancer. However, the mechanism of action of TIPE2 on the growth of rectal adenocarcinoma is unknown. Our results showed that the expression levels of TIPE2 in human rectal adenocarcinoma tissues were higher than those in adjacent non‐tumour tissues. Overexpression of TIPE2 reduced the proliferation, migration, and invasion of human rectal adenocarcinoma cells and down‐regulation of TIPE2 showed reverse effects. TIPE2 overexpression increased apoptosis through down‐regulating the expression levels of Wnt3a, phospho (p)‐β‐Catenin, and p‐glycogen synthase kinase‐3β in rectal adenocarcinoma cells, however, TIPE2 knockdown exhibited reverse trends. TIPE2 overexpression decreased autophagy by reducing the expression levels of p‐Smad2, p‐Smad3, and transforming growth factor‐beta (TGF‐β) in rectal adenocarcinoma cells, however, TIPE2 knockdown showed opposite effects. Furthermore, TIPE2 overexpression reduced the growth of xenografted human rectal adenocarcinoma, whereas TIPE2 knockdown promoted the growth of rectal adenocarcinoma tumours by modulating angiogenesis. In conclusion, TIPE2 could regulate the proliferation, migration, and invasion of human rectal adenocarcinoma cells through Wnt/β‐Catenin and TGF‐β/Smad2/3 signalling pathways. TIPE2 is a potential therapeutic target for the treatment of rectal adenocarcinoma.
    Type of Medium: Online Resource
    ISSN: 1582-1838 , 1582-4934
    URL: Issue
    URL: Article
    DOI: 10.1111/jcmm.2019.23.issue-3
    DOI: 10.1111/jcmm.14065
    Language: English
    Publisher: Wiley
    Publication Date: 2019
    detail.hit.zdb_id: 2076114-4
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  • 8
    Online Resource
    Online Resource
    Layered Oxide Cathodes for Sodium‐Ion Batteries: Phase Transition, Air Stability, and Performance
    Wiley ; 2018
    In:  Advanced Energy Materials Vol. 8, No. 8 ( 2018-03)
    Details
    In: Advanced Energy Materials, Wiley, Vol. 8, No. 8 ( 2018-03)
    Abstract: The increasing demand for replacing conventional fossil fuels with clean energy or economical and sustainable energy storage drives better battery research today. Sodium‐ion batteries (SIBs) are considered as a promising alternative for grid‐scale storage applications due to their similar “rocking‐chair” sodium storage mechanism to lithium‐ion batteries, the natural abundance, and the low cost of Na resources. Searching for appropriate electrode materials with acceptable electrochemical performance is the key point for development of SIBs. Layered transition metal oxides represent one of the most fascinating electrode materials owing to their superior specific capacity, environmental benignity, and facile synthesis. However, three major challenges (irreversible phase transition, storage instability, and insufficient battery performance) are known for cathodes in SIBs. Herein, a comprehensive review on the latest advances and progresses in the exploration of layered oxides for SIBs is presented, and a detailed and deep understanding of the relationship of phase transition, air stability, and electrochemical performance in layered oxide cathodes is provided in terms of refining the structure–function–property relationship to design improved battery materials. Layered oxides will be a competitive and attractive choice as cathodes for SIBs in next‐generation energy storage devices.
    Type of Medium: Online Resource
    ISSN: 1614-6832 , 1614-6840
    URL: Issue
    URL: Article
    DOI: 10.1002/aenm.v8.8
    DOI: 10.1002/aenm.201701912
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2594556-7
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  • 9
    Online Resource
    Online Resource
    Suppressing the P2–O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium‐Ion Batteries
    Wiley ; 2016
    In:  Angewandte Chemie Vol. 128, No. 26 ( 2016-06-20), p. 7571-7575
    Details
    In: Angewandte Chemie, Wiley, Vol. 128, No. 26 ( 2016-06-20), p. 7571-7575
    Abstract: Room‐temperature sodium‐ion batteries (SIBs) have shown great promise in grid‐scale energy storage, portable electronics, and electric vehicles because of the abundance of low‐cost sodium. Sodium‐based layered oxides with a P2‐type layered framework have been considered as one of the most promising cathode materials for SIBs. However, they suffer from the undesired P2–O2 phase transition, which leads to rapid capacity decay and limited reversible capacities. Herein, we show that this problem can be significantly mitigated by substituting some of the nickel ions with magnesium to obtain Na 0.67 Mn 0.67 Ni 0.33− x Mg x O 2 (0≤ x ≤0.33). Both the reversible capacity and the capacity retention of the P2‐type cathode material were remarkably improved as the P2–O2 phase transition was thus suppressed during cycling. This strategy might also be applicable to the modulation of the physical and chemical properties of layered oxides and provides new insight into the rational design of high‐capacity and highly stable cathode materials for SIBs.
    Type of Medium: Online Resource
    ISSN: 0044-8249 , 1521-3757
    URL: Issue
    URL: Article
    DOI: 10.1002/ange.v128.26
    DOI: 10.1002/ange.201602202
    RVK:
    VA 2100
    RVK:
    VN 5020
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 505868-5
    detail.hit.zdb_id: 506609-8
    detail.hit.zdb_id: 514305-6
    detail.hit.zdb_id: 505872-7
    detail.hit.zdb_id: 1479266-7
    detail.hit.zdb_id: 505867-3
    detail.hit.zdb_id: 506259-7
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  • 10
    Online Resource
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    Subzero‐Temperature Cathode for a Sodium‐Ion Battery
    Wiley ; 2016
    In:  Advanced Materials Vol. 28, No. 33 ( 2016-09), p. 7243-7248
    Details
    In: Advanced Materials, Wiley, Vol. 28, No. 33 ( 2016-09), p. 7243-7248
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    URL: Article
    DOI: 10.1002/adma.v28.33
    DOI: 10.1002/adma.201600846
    RVK:
    UA 1538
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 1474949-X
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