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  • Wiley  (3)
  • 2015-2019  (3)
  • 1
    In: ChemSusChem, Wiley, Vol. 11, No. 6 ( 2018-03-22), p. 1040-1047
    Abstract: Catalytic conversion of CO 2 into chemicals is a critical issue for energy and environmental research. Among such reactions, converting CO 2 into CO has been regarded as a significant foundation to generate a liquid fuels and chemicals on a large scale. In this work, zeolitic imidazolate framework‐derived N‐doped carbon‐supported metal carbide catalysts (M/ZIF‐8‐C; M=Ni, Fe, Co and Cu) with highly dispersed metal carbide were prepared for selective CO 2 hydrogenation. Under the same metal loadings, catalytic activity for CO 2 hydrogenation to CO follows the order: Ni/ZIF‐8‐C≈Fe/ZIF‐8‐C 〉 Co/ZIF‐8‐C 〉 Cu/ZIF‐8‐C. These catalysts are composed of carbide or metal supported on pyridinic N sites within the N‐doped carbon structure. ZIF‐8‐derived pyridinic nitrogen and carbide effect CO 2 adsorption, whereas dispersed Ni or Fe carbide and metal species serve as an active site for CO 2 hydrogenation. The supported Ni catalyst exhibits extraordinary catalytic performance, which results from high dispersion of the metal and exposure of the carbide. Based on high‐sensitivity low‐energy ion scattering (HS‐LEIS) and line scan results, density functional theory (DFT) was used to understand reaction mechanism of selective CO 2 hydrogenation over Ni/ZIF‐8‐C. The product CO is derived mainly from the direct cleavage of C−O bonds in CO 2 * rather than decomposition of COOH*. The CO* desorption energy on Ni/ZIF‐8‐C is lower than that for further hydrogenation and dissociation. Comparison of Ni/ZIF‐8‐C with ZIF‐8‐C indicates that the combined effects of the highly dispersed metal or carbide and weak CO adsorption result in high CO selectivity for CO 2 hydrogenation.
    Type of Medium: Online Resource
    ISSN: 1864-5631 , 1864-564X
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 2411405-4
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  • 2
    In: International Journal of Climatology, Wiley, Vol. 38, No. 14 ( 2018-11), p. 5220-5230
    Abstract: Using observed and reanalysed data sets, we investigate the potential role of Atlantic Multi‐decadal Oscillations (AMO) in weakening the in‐phase association between Indian summer monsoon rainfall (ISMR) and following Australian summer monsoon rainfall (ASMR) during the 1932–1966 period. This weakened inter‐monsoon link was earlier attributed to a complete breakdown of the El Niño–Southern Oscillation (ENSO) links with the ASMR. We now find that this weakening was associated with strengthening of low‐level westerlies and an increase in local low‐level convergence in the northern Australia associated with the warm phase of the AMO during this period. This increased background convergence resulted in relatively enhanced ASMR during the El Niño summers during this period.
    Type of Medium: Online Resource
    ISSN: 0899-8418 , 1097-0088
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2018
    detail.hit.zdb_id: 1491204-1
    SSG: 14
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  • 3
    In: Hydrological Processes, Wiley, Vol. 30, No. 9 ( 2016-04-30), p. 1315-1329
    Abstract: The catchments in the Loess Plateau, in China's middle reaches of the Yellow River Basin, experienced unprecedented land use changes in the last 50 years as a result of large‐scale soil conservation measure to control soil erosion. The climate of the region also exhibited some levels of change with decreased precipitation and increased temperature. This study combined the time‐trend analysis method with a sensitivity‐based approach and found that annual streamflow in the Loess Plateau decreased significantly since the 1950s and surface runoff trends appear to dominate the streamflow trends in most of the catchments. Annual baseflow exhibited mostly downward trends, but significant upward trends were also observed in 3 out of 38 gauging stations. Mean annual streamflow during 1979−2010 decreased by up to 65% across the catchments compared with the period of 1957−1978, indicating significant changes in the hydrological regime of the Loess Plateau. It is estimated that 70% of the streamflow reduction can be attributed to land use change, while the remaining 30% is associated with climate variability. Land use change because of the soil conservation measures and reduction in precipitation are the key drivers for the observed streamflow trends. These findings are consistent with results of previous studies for the region and appear to be reasonable given the accelerated level of the soil conservation measures implemented since the late 1970s. Changes in sea surface temperature in the Pacific Ocean, as indicated by variations in El Niño–Southern Oscillation and phase shifts of the Pacific Decadal Oscillation, appear to have also affected the annual streamflow trends. The framework described in this study shows promising results for quantifying the effects of land use change and climate variability on mean annual streamflow of catchments within the Loess Plateau. Copyright © 2015 John Wiley & Sons, Ltd.
    Type of Medium: Online Resource
    ISSN: 0885-6087 , 1099-1085
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 1479953-4
    SSG: 14
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