Description: Highlights: • Clay dehydration water expelled from buried sediments drives mud volcanism. • Rise of fluids mediated by crustal-scale strike-slip faults cross-cutting wedge. • On active accretionary wedge, petroleum accumulations were dismantled in Neogene. • 4He enrichment and δ13C-CH4 ~−50‰ in fluids reflect an open hydrocarbon system. • Petroleum pools remain on shallow margin. Microbial gas vented out of active wedge. Abstract: A geochemical study of the composition of hydrocarbon gases and helium isotopes (3He/4He) in fluids from Mud Volcanoes (MVs) located on and out of the active accretionary wedge of the Gulf of Cadiz (GoC) provides information on fluid sources and migrations in deeply buried sediments. The GoC is a tectonically active segment of the Africa-Iberia plate boundary occluded beneath the thick sediments of an accretionary wedge dissected by crustal-scale strike-slip faults. Initially built during the Miocene Gibraltar Arc subduction, the wedge has since developed toward the W-NW in an oblique convergent setting. Interstitial water expelled from clays undergoing diagenesis in buried sediments drives mud volcanism on the wedge, with MVs located along strike-slip faults mediating fluid ascent. The large excess of radiogenic helium (4He) in all GoC fluids agrees with a clay mineral dehydration source of water. Hydrocarbon gases from all deepwater MVs bear methane having similar stable carbon isotope compositions of ~−50‰VPDB whether fluids are highly enriched in methane relative to heavier homologues (C2+) or not (Methane / (Ethane + Propane) ~10 to 10,000). We suggest that methane with −50‰VPDB was largely diffused out of early generating source rocks, and became dissolved in the water expelled by the buried sediments. Consistently, low 3He/4He ratios suggest an open hydrocarbon system: Petroleum accumulations and 3He dissolved in the original sedimentary pore water have mostly escaped into the water column during the major Late Neogene compressional events. At present, some MVs vent CH4-rich fluids from dewatering sediments, while other structures located on active thrusts additionally vent C2+-rich gases generated by active Cretaceous source intervals. By contrast, evaporitic seals preserved petroleum accumulations on the shallow Moroccan Margin, while the westernmost MVs located out of the accretionary wedge vent microbial gas.

Description: Carbon dioxide (CO2) capture and storage (CCS) has been discussed as a potentially significant mitigation option for the ongoing climate warming. Natural CO2 release sites serve as natural laboratories to study subsea CO2 leakage in order to identify suitable analytical methods and numerical models to develop best-practice procedures for the monitoring of subseabed storage sites. We present a new model of bubble (plume) dynamics, advection-dispersion of dissolved CO2, and carbonate chemistry. The focus is on a medium-sized CO2 release from 294 identified small point sources around Panarea Island (South-East Tyrrhenian Sea, Aeolian Islands, Italy) in water depths of about 40–50 m. This study evaluates how multiple CO2 seep sites generate a temporally variable plume of dissolved CO2. The model also allows the overall flow rate of CO2 to be estimated based on field measurements of pH. Simulations indicate a release of ∼6900 t y–1 of CO2 for the investigated area and highlight an important role of seeps located at 〉20 m water depth in the carbon budget of the Panarea offshore gas release system. This new transport-reaction model provides a framework for understanding potential future leaks from CO2 storage sites.

Description: Highlights • CO2 gas bubbles are completely dissolved within 2 m above the seabed. • CO2 is not emitted into the atmosphere but retained in the North Sea. • Dissolved CO2 is rapidly dispersed by tidal currents in the North Sea. • Harmful effects on benthic biota occur in the direct vicinity of the leak. • Monitoring has to be performed at the seabed and close to the leak. Abstract Existing wells pose a risk for the loss of carbon dioxide (CO2) from storage sites, which might compromise the suitability of carbon dioxide removal (CDR) and carbon capture and storage (CCS) technologies as climate change mitigation options. Here, we show results of a controlled CO2 release experiment at the Sleipner CO2 storage site and numerical simulations that evaluate the detectability and environmental consequences of a well leaking CO2 into the Central North Sea (CNS). Our field measurements and numerical results demonstrate that the detectability and impact of a leakage of 〈55 t yr−1 of CO2 would be limited to bottom waters and a small area around the leak, due to rapid CO2 bubble dissolution in seawater within the lower 2 m of the water column and quick dispersion of the dissolved CO2 plume by strong tidal currents. As such, the consequences of a single well leaking CO2 are found to be insignificant in terms of storage performance. Only prolonged leakage along numerous wells might compromise long-term CO2 storage and may adversely affect the local marine ecosystem. Since many abandoned wells leak natural gas into the marine environment, hydrocarbon provinces with a high density of wells may not always be the most suitable areas for CO2 storage.