Description: Water samples collected from various depths of offshore South China and Philippine Seas were exposed to solar-simulated radiation. Photomineralization of dissolved organic carbon (DOC) and photobleaching of chromophoric DOM (CDOM) and its humic-like fluorescent constituent (FDOM) were observed in all samples.

Description: Two stations were visited in the western tropical Pacific Ocean: The South-East Asia Time-series Station (SEATS) in the northern South China Sea (SCS) and station F2 in the Philippine Sea, ~230 km to the northeast of the Luzon Strait. Water samples were taken aboard the R/V Dong-Fang-Hong 2 in July and August 2017 from 13 depths between 5 m and 3800 m at SEATS and 11 depths between 5 m and 3200 m at F2 using Niskin bottles mounted on a SeaBird 911 conductivity-temperature-depth (CTD) rosette sampler. Vertical distribution of temperature and salinity with a depth interval of 1 m were obtained by CTD.

Description: Two stations were visited in the western tropical Pacific Ocean: The South-East Asia Time-series Station (SEATS) in the northern South China Sea (SCS) and station F2 in the Philippine Sea, ~230 km to the northeast of the Luzon Strait. Water samples were taken aboard the R/V Dong-Fang-Hong 2 in July and August 2017 from 13 depths between 5 m and 3800 m at SEATS and 11 depths between 5 m and 3200 m at F2 using Niskin bottles mounted on a SeaBird 911 conductivity-temperature-depth (CTD) rosette sampler. Lab irradiation experiments of samples from different sampling depth were carried out. The samples were irradiated for 6 days under a SUNTEST XLS+ solar simulator equipped with a 1.5 kW xenon lamp and a special UV filter to remove radiation at wavelengths 〈290 nm. The samples before and after irradiation were defined as 'unirradiated samples' and 'irradiated samples', respectively. This table lists the chemical and optical properties of dissolved organic matter at different sampling depth before and after 6-d irradiation.

Description: Two stations were visited in the western tropical Pacific Ocean: The South-East Asia Time-series Station (SEATS) in the northern South China Sea (SCS) and station F2 in the Philippine Sea, ~230 km to the northeast of the Luzon Strait. Water samples were taken aboard the R/V Dong-Fang-Hong 2 in July and August 2017 from 13 depths between 5 m and 3800 m at SEATS and 11 depths between 5 m and 3200 m at F2 using Niskin bottles mounted on a SeaBird 911 conductivity-temperature-depth (CTD) rosette sampler. The percentage change of different parameters was calculated as the ratio of the signal difference of property X before and after irradiation to that before irradiation.

Description: Two stations were visited in the western tropical Pacific Ocean: The South-East Asia Time-series Station (SEATS) in the northern South China Sea (SCS) and station F2 in the Philippine Sea, ~230 km to the northeast of the Luzon Strait. Water samples were taken aboard the R/V Dong-Fang-Hong 2 in July and August 2017 from 13 depths between 5 m and 3800 m at SEATS and 11 depths between 5 m and 3200 m at F2 using Niskin bottles mounted on a SeaBird 911 conductivity-temperature-depth (CTD) rosette sampler. A time-course irradiation with sampling time at 0, 1, 3, 5, 7, and 10 d was conducted for the bottommost samples from SEATS and F2. The value of different parameters was calculated as the ratio of the signal of property X at irradiation time t to that at time zero.

Description: Two stations were visited in the western tropical Pacific Ocean: The South-East Asia Time-series Station (SEATS) in the northern South China Sea (SCS) and station F2 in the Philippine Sea, ~230 km to the northeast of the Luzon Strait. Water samples were taken aboard the R/V Dong-Fang-Hong 2 in July and August 2017 from 13 depths between 5 m and 3800 m at SEATS and 11 depths between 5 m and 3200 m at F2 using Niskin bottles mounted on a SeaBird 911 conductivity-temperature-depth (CTD) rosette sampler. A time-course dark incubation (50 days) with sampling time at 0, 3, 7, 11, 15, 23, 34 and 50 d was conducted for the bottommost sample from F2 with and without prior exposure to solar radiation. The value of different parameters was calculated as the ratio of the signal of property X at irradiation time t to that at time zero.

Description: Carbonyl sulfide (OCS) and carbon disulfide (CS2) are volatile sulfur gases that are naturally formed in seawater and exchanged with the atmosphere. OCS is the most abundant sulfur gas in the atmosphere, and CS2 is its most important precursor. They have gained interest due to their direct (OCS) or indirect (CS2 via oxidation to OCS) contribution to the stratospheric sulfate aerosol layer. Furthermore, OCS serves as a proxy to constrain terrestrial CO2 uptake by vegetation. Oceanic emissions of both gases contribute a major part to their atmospheric concentration. Here we present a database of previously published and unpublished, mainly ship-borne measurements in seawater and the marine boundary layer for both gases, available at https://doi.pangaea.de/10.1594/PANGAEA.905430 (Lennartz et al., 2019). The database contains original measurements as well as data digitalized from figures in publications from 42 measurement campaigns, i.e. cruises or time series stations, ranging from 1982 to 2019. OCS data cover all ocean basins except for the Arctic Ocean, as well as all months of the year, while the CS2 dataset shows large gaps in spatial and temporal coverage. Concentrations are consistent across different sampling and analysis techniques for OCS. The database is intended to support the identification of global spatial and temporal patterns and to facilitate the evaluation of model simulations.

Description: The air–sea exchange and oceanic cycling of greenhouse gases (GHG), including carbon dioxide (CO2), nitrous oxide (N2O), methane (CH4), carbon monoxide (CO), and nitrogen oxides (NOx ¼ NO þ NO2), are fundamental in controlling the evolution of the Earth’s atmospheric chemistry and climate. Significant advances have been made over the last 10 years in understanding, instrumentation and methods, as well as deciphering the production and consumption pathways of GHG in the upper ocean (including the surface and subsurface ocean down to approximately 1000 m). The global ocean under current conditions is now well established as a major sink for CO2, a major source for N2O and a minor source for both CH4 and CO. The importance of the ocean as a sink or source of NOx is largely unknown so far. There are still considerable uncertainties about the processes and their major drivers controlling the distributions of N2O, CH4, CO, and NOx in the upper ocean. Without having a fundamental understanding of oceanic GHG production and consumption pathways, our knowledge about the effects of ongoing major oceanic changes—warming, acidification, deoxygenation, and eutrophication—on the oceanic cycling and air–sea exchange of GHG remains rudimentary at best. We suggest that only through a comprehensive, coordinated, and interdisciplinary approach that includes data collection by global observation networks as well as joint process studies can the necessary data be generated to (1) identify the relevant microbial and phytoplankton communities, (2) quantify the rates of ocean GHG production and consumption pathways, (3) comprehend their major drivers, and (4) decipher economic and cultural implications of mitigation solutions