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  • 2020-2024  (10)
  • 1
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: Bottle, Niskin; carbon monoxide; Carbon monoxide; DATE/TIME; DEPTH, water; Event label; Faro_2021-01; Faro_2021-02; Faro_2021-03; Faro_2021-04; Faro_2021-05; Faro_2021-06; Faro_2021-07; Faro_2021-08; Faro_2021-09; Faro_2021-10; Faro_2021-11; Faro_2021-12; Faro_2021-13; Faro_2021-14; NIS; Station label
    Type: Dataset
    Format: text/tab-separated-values, 56 data points
    Location Call Number Limitation Availability
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  • 2
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: Bottle, Niskin; carbon monoxide; Carbon monoxide; Carbon monoxide, disequilibrium; Carbon monoxide, dissolved, equilibrium; Carbon monoxide, flux; Event label; Faro_2021-08; Faro_2021-09; Faro_2021-10; Faro_2021-11; Faro_2021-12; Faro_2021-14; NIS; Station label; Wind speed
    Type: Dataset
    Format: text/tab-separated-values, 36 data points
    Location Call Number Limitation Availability
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  • 3
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: Ammonium; Bottle, Niskin; carbon monoxide; Carbon monoxide; Carbon monoxide, dry air; Chlorophyll a; DEPTH, water; Event label; Faro_2021-01; Faro_2021-02; Faro_2021-03; Faro_2021-04; Faro_2021-05; Faro_2021-06; Faro_2021-07; Faro_2021-08; Faro_2021-09; Faro_2021-10; Faro_2021-11; Faro_2021-12; Faro_2021-13; Faro_2021-14; Fluorescence, dissolved organic matter; NIS; Nitrate; pH; Phosphate; Salinity; Saturation ratio; Station label; Temperature, water; Wind speed
    Type: Dataset
    Format: text/tab-separated-values, 153 data points
    Location Call Number Limitation Availability
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  • 4
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: Absorption coefficient; carbon monoxide; Ria Formosa Lagoon; Wavelength
    Type: Dataset
    Format: text/tab-separated-values, 1549 data points
    Location Call Number Limitation Availability
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  • 5
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: carbon monoxide; Carbon monoxide; Incubation duration; Station label; Treatment
    Type: Dataset
    Format: text/tab-separated-values, 51 data points
    Location Call Number Limitation Availability
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  • 6
    Publication Date: 2024-02-16
    Description: Discrete water samples for determining CO concentrations were collected using a Niskin bottle at approximately 1 m water depth from a small boat at 14 stations in the western part of the Ria Formosa Lagoon. Samples were taken in the late afternoon (~17:00h local time) on 25 May 2021. The sampling was repeated at approximately the same time on 26 May 2021. Additionally, atmospheric samples for CO were collected at Stations 8, 9, 10, 11, 12, and 14 on 26 May 2021. Incubation experiment using waters from the effluent of the aquaculture facility Estação Piloto de Piscicultura em Olhão (EPPO) at the Instituto Português do Mar e da Atmosfera, I. P. (IPMA, I. P.) in Olhão. Seawater was collected in 3.5 L UV-transparent incubation bottles and were placed into 200 L incubation enclosures (incubators) at CCMAR of the University of Algarve in Faro. Bottles were incubated under light and dark conditions to investigate photochemical CO production. A total of 16 bottles (separated equally) were distributed between two incubators. One incubator was set to light conditions (Group A), and the other was set to dark conditions (Group B). The experiments were carried out for 48 h, with sampling from the incubation bottles conducted at time points 0, 24, and 48 h. At each time point (14:00 h local time), triplicate samples were collected to determine dissolved CO concentrations and CDOM absorbance. Chlorophyll a (Chl-a), fluorescent dissolved organic matter (FDOM), salinity, pH, and water temperature (T) were measured on board in 0.5 m water depth using a calibrated EXO2 multiparameter sonde (YSI Inc. Yellow Springs, Ohio, USA).
    Keywords: carbon monoxide; Ria Formosa Lagoon
    Type: Dataset
    Format: application/zip, 5 datasets
    Location Call Number Limitation Availability
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  • 7
    Publication Date: 2024-01-10
    Description: Carbon monoxide (CO) is an atmospheric trace gas that plays a crucial role in the oxidizing capacity of the Earth’s atmosphere. Moreover, it functions as an indirect greenhouse gas, influencing the lifetimes of potent greenhouse gases such as methane. Albeit being an overall source of atmospheric CO, the role of coastal regions in the marine cycling of CO and how its budget can be affected by anthropogenic activities, remain uncertain. Here, we present the first measurements of dissolved CO in the Ria Formosa Lagoon, an anthropogenically influenced system in southern Portugal. The dissolved CO concentrations in the surface layer ranged from 0.16 to 3.1 nmol L−1 with an average concentration of 0.75 ± 0.57 nmol L−1. The CO saturation ratio ranged from 1.7 to 32.2, indicating that the lagoon acted as a source of CO to the atmosphere in May 2021. The estimated average sea-to-air flux density was 1.53 μmol m−2 d−1, mainly fueled by CO photochemical production. Microbial consumption accounted for 83 % of the CO production, suggesting that the resulting CO emissions to the atmosphere were modulated by microbial consumption in the surface waters of the Ria Formosa Lagoon. The results from an irradiation experiment with aquaculture effluent water indicated that aquaculture facilities in the Ria Formosa Lagoon seem to be a negligible source of atmospheric CO.
    Type: Article , NonPeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: archive
    Location Call Number Limitation Availability
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  • 8
    Publication Date: 2024-02-07
    Description: Nitric oxide (NO) is an atmospheric pollutant and climate forcer as well as a key intermediary in the marine nitrogen cycle, but the ocean’s NO contribution and production mechanisms remain unclear. Here, high-resolution NO observations were conducted simultaneously in the surface ocean and the lower atmosphere of the Yellow Sea and the East China Sea; moreover, NO production from photolysis and microbial processes was analyzed. The NO sea–air exchange showed uneven distributions (RSD = 349.1%) with an average flux of 5.3 ± 18.5 × 10–17 mol cm–2 s–1. In coastal waters where nitrite photolysis was the predominant source (89.0%), NO concentrations were remarkably higher (84.7%) than the overall average of the study area. The NO from archaeal nitrification accounted for 52.8% of all microbial production (11.0%). We also examined the relationship between gaseous NO and ozone which helped identify sources of atmospheric NO. The sea-to-air flux of NO in coastal waters was narrowed by contaminated air with elevated NO concentrations. These findings indicate that the emissions of NO from coastal waters, mainly controlled by reactive nitrogen inputs, will increase with the reduced terrestrial NO discharge.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Limitation Availability
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  • 9
    Publication Date: 2024-02-07
    Description: Nitric oxide (NO) is a short-lived intermediate of the oceanic nitrogen cycle, and it is produced by biological and photochemical processes in the ocean. Nitrogen dioxide (NO2) is a reactive atmospheric compound which has not been determined in the ocean so far. Here, we present the setup and validation of a novel continuous underway measurement system to measure dissolved NO and NO2 in the surface ocean. The system consists of a seawater/gas equilibration component coupled to a chemiluminescence detector. It was successfully deployed during a 12 day cruise to the East China Sea in May 2018. Dissolved NO and NO2 surface concentrations ranged from 〈limit of detection (LOD) to 98 × 10-12 mol L-1 and 〈LOD to 83 × 10-12 mol L-1, respectively. The ECS was supersaturated with NO but significantly undersaturated with NO2, indicating that the surface waters were a source for atmospheric NO but a sink for atmospheric NO2 at the time of our measurements.
    Type: Article , PeerReviewed
    Format: text
    Location Call Number Limitation Availability
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  • 10
    Publication Date: 2023-05-16
    Description: Carbon monoxide (CO) is an atmospheric trace gas that plays a crucial role in the oxidizing capacity of the Earth’s atmosphere. Moreover, it functions as an indirect greenhouse gas, influencing the lifetimes of potent greenhouse gases such as methane. Albeit being an overall source of atmospheric CO, the role of coastal regions in the marine cycling of CO and how its budget can be affected by anthropogenic activities, remain uncertain. Here, we present the first measurements of dissolved CO in the Ria Formosa Lagoon, an anthropogenically influenced system in southern Portugal. The dissolved CO concentrations in the surface layer ranged from 0.16 to 3.1 nmol L−1 with an average concentration of 0.75 ± 0.57 nmol L−1. The CO saturation ratio ranged from 1.7 to 32.2, indicating that the lagoon acted as a source of CO to the atmosphere in May 2021. The estimated average sea-to-air flux density was 1.53 μmol m−2 d−1, mainly fueled by CO photochemical production. Microbial consumption accounted for 83 % of the CO production, suggesting that the resulting CO emissions to the atmosphere were modulated by microbial consumption in the surface waters of the Ria Formosa Lagoon. The results from an irradiation experiment with aquaculture effluent water indicated that aquaculture facilities in the Ria Formosa Lagoon seem to be a negligible source of atmospheric CO.
    Type: Article , PeerReviewed , info:eu-repo/semantics/article
    Format: text
    Format: archive
    Location Call Number Limitation Availability
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