Abstract: Abstract. The paper introduces the first TROPOMI-based sulfur dioxide (SO2) emissions estimates for point sources. A total of about 500 continuously emitting point sources releasing about 10 kt yr−1 to more than 2000 kt yr−1 of SO2, previously identified from Ozone Monitoring Instrument (OMI) observations, were analyzed using TROPOMI (TROPOspheric Monitoring Instrument) measurements for 1 full year from April 2018 to March 2019. The annual emissions from these sources were estimated and compared to similar estimates from OMI and Ozone Mapping Profiling Suite (OMPS) measurements. Note that emissions from many of these 500 sources have declined significantly since 2005, making their quantification more challenging. We were able to identify 274 sources where annual emissions are significant and can be reliably estimated from TROPOMI. The standard deviations of TROPOMI vertical column density data, about 1 Dobson unit (DU, where 1 DU =2.69×1016 molecules cm−2) over the tropics and 1.5 DU over high latitudes, are larger than those of OMI (0.6–1 DU) and OMPS (0.3–0.4 DU). Due to its very high spatial resolution, TROPOMI produces 12–20 times more observations over a certain area than OMI and 96 times more than OMPS. Despite higher uncertainties of individual TROPOMI observations, TROPOMI data averaged over a large area have roughly 2–3 times lower uncertainties compared to OMI and OMPS data. Similarly, TROPOMI annual emissions can be estimated with uncertainties that are 1.5–2 times lower than the uncertainties of annual emissions estimates from OMI. While there are area biases in TROPOMI data over some regions that have to be removed from emission calculations, the absolute magnitude of these are modest, typically within ±0.25 DU, which can be comparable with SO2 values over large sources.

Abstract: Abstract. The TROPOspheric Monitoring Instrument (TROPOMI) aboard the Sentinel-5 Precursor satellite (launched on 13 October 2017) is a nadir-viewing spectrometer measuring reflected sunlight in the ultraviolet, visible, near-infrared, and shortwave infrared spectral ranges. The measured spectra are used to retrieve total columns of trace gases, including nitrogen dioxide (NO2). For ground validation of these satellite measurements, Pandora spectrometers, which retrieve high-quality NO2 total columns via direct-sun measurements, are widely used. In this study, Pandora NO2 measurements made at three sites located in or north of the Greater Toronto Area (GTA) are used to evaluate the TROPOMI NO2 data products, including a standard Royal Netherlands Meteorological Institute (KNMI) tropospheric and stratospheric NO2 data product and a TROPOMI research data product developed by Environment and Climate Change Canada (ECCC) using a high-resolution regional air quality forecast model (in the air mass factor calculation). It is found that these current TROPOMI tropospheric NO2 data products (standard and ECCC) met the TROPOMI design bias requirement (〈 10 %). Using the statistical uncertainty estimation method, the estimated TROPOMI upper-limit precision falls below the design requirement at a rural site but above in the other two urban and suburban sites. The Pandora instruments are found to have sufficient precision (〈 0.02 DU) to perform TROPOMI validation work. In addition to the traditional satellite validation method (i.e., pairing ground-based measurements with satellite measurements closest in time and space), we analyzed TROPOMI pixels located upwind and downwind from the Pandora site. This makes it possible to improve the statistics and better interpret the high-spatial-resolution measurements made by TROPOMI. By using this wind-based validation technique, the number of coincident measurements can be increased by about a factor of 5. With this larger number of coincident measurements, this work shows that both TROPOMI and Pandora instruments can reveal detailed spatial patterns (i.e., horizontal distributions) of local and transported NO2 emissions, which can be used to evaluate regional air quality changes. The TROPOMI ECCC NO2 research data product shows improved agreement with Pandora measurements compared to the TROPOMI standard tropospheric NO2 data product (e.g., lower multiplicative bias at the suburban and urban sites by about 10 %), demonstrating benefits from the high-resolution regional air quality forecast model.

Abstract: We evaluate total‐column ozone trends for 1979–2000 and 1997–2020 For 1997–2020, we find significant global‐ and Southern‐Hemisphere‐mean positive trends The effective radiative forcing of ozone‐depleting substances is now more consistent with three previous evaluations

Abstract: —J. BLUNDEN, T. BOYER, AND E. BARTOW-GILLIES Earth’s global climate system is vast, complex, and intricately interrelated. Many areas are influenced by global-scale phenomena, including the “triple dip” La Niña conditions that prevailed in the eastern Pacific Ocean nearly continuously from mid-2020 through all of 2022; by regional phenomena such as the positive winter and summer North Atlantic Oscillation that impacted weather in parts the Northern Hemisphere and the negative Indian Ocean dipole that impacted weather in parts of the Southern Hemisphere; and by more localized systems such as high-pressure heat domes that caused extreme heat in different areas of the world. Underlying all these natural short-term variabilities are long-term climate trends due to continuous increases since the beginning of the Industrial Revolution in the atmospheric concentrations of Earth’s major greenhouse gases. In 2022, the annual global average carbon dioxide concentration in the atmosphere rose to 417.1±0.1 ppm, which is 50% greater than the pre-industrial level. Global mean tropospheric methane abundance was 165% higher than its pre-industrial level, and nitrous oxide was 24% higher. All three gases set new record-high atmospheric concentration levels in 2022. Sea-surface temperature patterns in the tropical Pacific characteristic of La Niña and attendant atmospheric patterns tend to mitigate atmospheric heat gain at the global scale, but the annual global surface temperature across land and oceans was still among the six highest in records dating as far back as the mid-1800s. It was the warmest La Niña year on record. Many areas observed record or near-record heat. Europe as a whole observed its second-warmest year on record, with sixteen individual countries observing record warmth at the national scale. Records were shattered across the continent during the summer months as heatwaves plagued the region. On 18 July, 104 stations in France broke their all-time records. One day later, England recorded a temperature of 40°C for the first time ever. China experienced its second-warmest year and warmest summer on record. In the Southern Hemisphere, the average temperature across New Zealand reached a record high for the second year in a row. While Australia’s annual temperature was slightly below the 1991–2020 average, Onslow Airport in Western Australia reached 50.7°C on 13 January, equaling Australia's highest temperature on record. While fewer in number and locations than record-high temperatures, record cold was also observed during the year. Southern Africa had its coldest August on record, with minimum temperatures as much as 5°C below normal over Angola, western Zambia, and northern Namibia. Cold outbreaks in the first half of December led to many record-low daily minimum temperature records in eastern Australia. The effects of rising temperatures and extreme heat were apparent across the Northern Hemisphere, where snow-cover extent by June 2022 was the third smallest in the 56-year record, and the seasonal duration of lake ice cover was the fourth shortest since 1980. More frequent and intense heatwaves contributed to the second-greatest average mass balance loss for Alpine glaciers around the world since the start of the record in 1970. Glaciers in the Swiss Alps lost a record 6% of their volume. In South America, the combination of drought and heat left many central Andean glaciers snow free by mid-summer in early 2022; glacial ice has a much lower albedo than snow, leading to accelerated heating of the glacier. Across the global cryosphere, permafrost temperatures continued to reach record highs at many high-latitude and mountain locations. In the high northern latitudes, the annual surface-air temperature across the Arctic was the fifth highest in the 123-year record. The seasonal Arctic minimum sea-ice extent, typically reached in September, was the 11th-smallest in the 43-year record; however, the amount of multiyear ice—ice that survives at least one summer melt season—remaining in the Arctic continued to decline. Since 2012, the Arctic has been nearly devoid of ice more than four years old. In Antarctica, an unusually large amount of snow and ice fell over the continent in 2022 due to several landfalling atmospheric rivers, which contributed to the highest annual surface mass balance, 15% to 16% above the 1991–2020 normal, since the start of two reanalyses records dating to 1980. It was the second-warmest year on record for all five of the long-term staffed weather stations on the Antarctic Peninsula. In East Antarctica, a heatwave event led to a new all-time record-high temperature of −9.4°C—44°C above the March average—on 18 March at Dome C. This was followed by the collapse of the critically unstable Conger Ice Shelf. More than 100 daily low sea-ice extent and sea-ice area records were set in 2022, including two new all-time annual record lows in net sea-ice extent and area in February. Across the world’s oceans, global mean sea level was record high for the 11th consecutive year, reaching 101.2 mm above the 1993 average when satellite altimetry measurements began, an increase of 3.3±0.7 over 2021. Globally-averaged ocean heat content was also record high in 2022, while the global sea-surface temperature was the sixth highest on record, equal with 2018. Approximately 58% of the ocean surface experienced at least one marine heatwave in 2022. In the Bay of Plenty, New Zealand’s longest continuous marine heatwave was recorded. A total of 85 named tropical storms were observed during the Northern and Southern Hemisphere storm seasons, close to the 1991–2020 average of 87. There were three Category 5 tropical cyclones across the globe—two in the western North Pacific and one in the North Atlantic. This was the fewest Category 5 storms globally since 2017. Globally, the accumulated cyclone energy was the lowest since reliable records began in 1981. Regardless, some storms caused massive damage. In the North Atlantic, Hurricane Fiona became the most intense and most destructive tropical or post-tropical cyclone in Atlantic Canada’s history, while major Hurricane Ian killed more than 100 people and became the third costliest disaster in the United States, causing damage estimated at $113 billion U.S. dollars. In the South Indian Ocean, Tropical Cyclone Batsirai dropped 2044 mm of rain at Commerson Crater in Réunion. The storm also impacted Madagascar, where 121 fatalities were reported. As is typical, some areas around the world were notably dry in 2022 and some were notably wet. In August, record high areas of land across the globe (6.2%) were experiencing extreme drought. Overall, 29% of land experienced moderate or worse categories of drought during the year. The largest drought footprint in the contiguous United States since 2012 (63%) was observed in late October. The record-breaking megadrought of central Chile continued in its 13th consecutive year, and 80-year record-low river levels in northern Argentina and Paraguay disrupted fluvial transport. In China, the Yangtze River reached record-low values. Much of equatorial eastern Africa had five consecutive below-normal rainy seasons by the end of 2022, with some areas receiving record-low precipitation totals for the year. This ongoing 2.5-year drought is the most extensive and persistent drought event in decades, and led to crop failure, millions of livestock deaths, water scarcity, and inflated prices for staple food items. In South Asia, Pakistan received around three times its normal volume of monsoon precipitation in August, with some regions receiving up to eight times their expected monthly totals. Resulting floods affected over 30 million people, caused over 1700 fatalities, led to major crop and property losses, and was recorded as one of the world’s costliest natural disasters of all time. Near Rio de Janeiro, Brazil, Petrópolis received 530 mm in 24 hours on 15 February, about 2.5 times the monthly February average, leading to the worst disaster in the city since 1931 with over 230 fatalities. On 14–15 January, the Hunga Tonga-Hunga Ha'apai submarine volcano in the South Pacific erupted multiple times. The injection of water into the atmosphere was unprecedented in both magnitude—far exceeding any previous values in the 17-year satellite record—and altitude as it penetrated into the mesosphere. The amount of water injected into the stratosphere is estimated to be 146±5 Terragrams, or ∼10% of the total amount in the stratosphere. It may take several years for the water plume to dissipate, and it is currently unknown whether this eruption will have any long-term climate effect.