In:
Zeitschrift für anorganische und allgemeine Chemie, Wiley, Vol. 647, No. 23-24 ( 2021-12-10), p. 2219-2225
Abstract:
Two new coordination polymers [Cu( L )(phen)] n ( 1 ) and {[Mn 2 ( L ) 2 (phen) 2 ]⋅H 2 O} n ( 2 , H 2 L is 4,4′‐(azanediylbis(methylene))dibenzoic acid, phen is o ‐phenanthroline) were synthesized using hydrothermally method. Complexes 1 and 2 were characterized by powder XRD, FT‐IR, elemental analysis, thermogravimetry, and X‐ray single‐crystal diffraction. Complex 1 belongs to monoclinic system with space group P 2 1 / n while complex 2 belongs to triclinic system with space group P ī. Complex 1 is 1D coordination polymers while complex 2 is 2D coordination polymers. Hirshfeld surface analysis of 1 and 2 were investigated and discussed in detail. Moreover, Magnetic studies reveal that complex 2 displays dominant antiferromagnetic interactions between Mn II ions through syn‐syn ‐carboxyl bridges.
Type of Medium:
Online Resource
ISSN:
0044-2313
,
1521-3749
DOI:
10.1002/zaac.v647.23-24
DOI:
10.1002/zaac.202100236
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
201094-X
detail.hit.zdb_id:
1481139-X
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