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  • Nature Research  (2)
  • Europen Association of Geochemistry  (1)
  • 2020-2024  (3)
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  • 1
    Publication Date: 2024-02-07
    Description: The high latitude regions play a key role in regulating the marine biogeochemical cycling of barium (Ba) and the pre-formed Ba isotope compositions in the global ocean. In this study, we present 17 new depth profiles of dissolved Ba concentrations ([Ba]) and isotope compositions (δ138Ba) from the high latitude Atlantic, Pacific and Southern Oceans to trace the ventilation of deep waters in the Southern Ocean and their subsequent transport throughout the global ocean. Our data reveal how biogeochemical processes in the Southern Ocean generate distinct δ138Ba signatures of upper ocean water masses, and that large scale ocean circulation constrains the meridional gradient of δ138Ba distributions in the deep Atlantic Ocean. The significant increase in [Ba] of deep waters in the North Pacific is mainly achieved through dissolution of sinking particles which adds a δ138Ba signal comparable to the deep Pacific Ocean.
    Type: Article , PeerReviewed
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  • 2
    Publication Date: 2024-02-07
    Description: North African greening phases, during which large rivers ran through the Sahara Desert, occurred repeatedly during the Quaternary and are regarded as key periods for the development of past human populations. However, the timing and mechanisms responsible for the reactivation of the presently dormant fluvial systems remain highly uncertain. Here we present hydroclimate changes over the past 160,000 years, reconstructed from analyses of the provenance of terrestrial sediments in a marine sediment record from the Gulf of Sirte (offshore Libya). By combining high-resolution proxy data with transient Earth system model simulations, we are able to identify the various drivers that led to the observed shifts in hydroclimate and landscapes. We show that river runoff occurred during warm interglacial phases of Marine Isotope Stages 1 and 5 due to precession-forced enhancements in the summer and autumn rainfall over the entire watershed, which fed presently dry river systems and intermittent coastal streams. In contrast, shorter-lasting and less-intense humid events during glacial Marine Isotope Stages 3 and 4 were related to autumn and winter precipitation over the Libyan coastal regions driven by Mediterranean storms. Our results reveal large shifts in hydroclimate environments during the last glacial cycle, which probably exerted a strong evolutionary and structural control on past human populations, potentially pacing their dispersal across northern Africa.
    Type: Article , PeerReviewed
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  • 3
    Publication Date: 2024-02-08
    Description: The Amazon River accounts for 20% of global freshwater runoff and supplies vital trace metals to the Atlantic Ocean. Suspended particles within its plume are thought to partially dissolve, constituting a large potential source of metals, which is, however, not well constrained. Here we used combined neodymium (Nd) and hafnium (Hf) isotopes to disprove the release of Nd and Hf from particles as the cause of the observed dissolved concentration increases and isotopic variability across the plume. Instead, the changes reflect admixture of nearby Pará River freshwater with exceptionally high dissolved Nd and Hf concentrations contributing 45–100% of the riverine fraction to the southern and outer estuary. This result led us to develop an empirical relationship between riverine Nd concentration and pH to revise the global dissolved riverine Nd flux, which accordingly is at least three times higher than commonly used estimates. Future work should focus on contributions of low-pH rivers to global metal fluxes.
    Type: Article , PeerReviewed
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