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  • Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences  (95)
  • 2020-2024  (95)
  • 1
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2024
    In:  Acta Physica Sinica Vol. 73, No. 7 ( 2024), p. 072801-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 73, No. 7 ( 2024), p. 072801-
    Abstract: Neutron capture reaction is one of the neutron reactions and plays an important role in using reactor control rods and shell materials, designing nuclear device structures, and studying nuclear astrophysics S processes and element origins. The 4π BaF 〈 sub 〉 2 〈 /sub 〉 detection device has advantages such as high time resolution, low neutron sensitivity, and high detection efficiency, thus making it suitable for measuring neutron radiation capture reaction cross-section data. In order to fill the gap in our neutron capture reaction data in the keV energy range and improve their accuracy, the Key Laboratory of Nuclear Data at the Chinese Institute of Atomic Energy (CIAE) has established a Gamma Total Absorption Facility (GTAF), which consists of 28 hexagonal BaF 〈 sub 〉 2 〈 /sub 〉 crystals and 12 pentagonal BaF 〈 sub 〉 2 〈 /sub 〉 crystals to form a spherical shell with an external diameter of 25 cm and an internal diameter of 10 cm, covering 95.2% of the solid angles. The Back-n beam line of the Chinese Spallation Neutron Source (CSNS) is a back-streaming white beam line that covers neutron energy ranging from a few eV to several hundred MeV, making it suitable for measuring neutron capture cross-sections. The reaction cross-section data of 〈 sup 〉 197 〈 /sup 〉 Au is measured by using GTAF on the Back-n beam line. The measurement data are preliminarily background deducted through energy screening, PSD method, and crystal multiplicity screening. Subsequently, the background is analyzed and deducted based on the measurement data of 〈 sup 〉 nat 〈 /sup 〉 C and empty samples, and the yield of 〈 sup 〉 197 〈 /sup 〉 Au capture reaction is obtained. Resonance parameters are a set of parameters extracted from experimental data to describe the resonance curve, which can eliminate the influence of experimental conditions on resonance data and are more important than the cross-section obtained from experiments. The resonance energy, neutron resonance width, and gamma resonance width parameters of 〈 sup 〉 197 〈 /sup 〉 Au at 1–100 eV are fitted by using the SAMMY program. From the comparison between the resonance curves obtained from experimental measurements and the resonance parameters obtained from fitting with the ENDF/B-VIII.0 database, it can follow that the experimental measurement results are in good agreement with the database, nevertheless, there exist some differences in the resonance parameter, which may be due to the GTAF energy resolution, Back-n neutron spectrum measurement accuracy, and the experimental background deduction method. Our next work is to identify the sources of difference.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2024
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  • 2
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2021
    In:  Acta Physica Sinica Vol. 70, No. 8 ( 2021), p. 082901-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 70, No. 8 ( 2021), p. 082901-
    Abstract: At present, there exist few proton-beam terminals for the detector calibration in the world. Meanwhile, most of these terminals provide monoenergetic protons. Back-n white neutron source from China Spallation Neutron Source(CSNS) was put into operation in 2018. Based on the white neutron flux ranging from 0.5 eV to 200 MeV from the CSNS Back-n white neutron source, continuous-energy protons involved in a wide energy spectrum can be acquired from the 〈sup〉1〈/sup〉H(n, el) reaction. Adopting this method, a new research platform for researches such as proton calibration is realized at CSNS. As hydrogen exists as gas at normal temperature and pressure, in the selecting of the proton-converting target, the hydrogen-rich compounds are preferential considered. Considering the reaction cross sections of the 〈sup〉1〈/sup〉H(n, el), 〈sup〉12〈/sup〉C(n, p)〈sup〉12〈/sup〉B, 〈sup〉12〈/sup〉C(n, d)〈sup〉11〈/sup〉B, 〈sup〉12〈/sup〉C(n, t)〈sup〉10〈/sup〉B, 〈sup〉12〈/sup〉C(n, 〈sup〉3〈/sup〉He)〈sup〉10〈/sup〉Be, 〈sup〉12〈/sup〉C(n, α)〈sup〉9〈/sup〉Be and 〈sup〉1〈/sup〉H(n, γ)〈sup〉2〈/sup〉H, polyethylene and polypropylene are suitable for serving as targets in this research. Based on a 3U PXIe, digitizers with 1 GSps sampling rate and 12 bit resolution are utilized to digitize and record the output signals of telescopes. The time and amplitude information of each signal are extracted from its recorded waveform. Proton fluxes can be calculated by using the neutron energy spectrum and the cross section of the 〈sup〉1〈/sup〉H(n, el) reaction. Using the γ-flash event as the starting time of the time-of-flight (TOF) and the time information of signal in detector as the stopping time, the kinematic energy of each secondary proton can be deduced from the TOF and the angle of the detector. A calibration experiment on three charged particle telescopes, with each telescope consisting of a silicon detector and a CsI(Tl) detector, is carried out on this research platform. The readout methods of the CsI(Tl) detectors in these three telescopes are different. In the calibration experiment, Δ〈i〉E-〈/i〉〈i〉E〈/i〉 two-dimensional spectra and amplitude-〈i〉E〈/i〉〈sub〉p〈/sub〉 two-dimensional spectra of these telescopes are obtained. Through comparing these particle identification spectra, the SiPM is chosen as the signal readout method for CsI(Tl) detectors in the charged particle telescopes. These researches provide experimental evidence for the construction of the charged particle telescope at Back-n, and also illustrate the feasibility of wide-energy spectrum proton calibration based on the Back-n white neutron source.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2021
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  • 3
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2021
    In:  Acta Physica Sinica Vol. 70, No. 22 ( 2021), p. 222801-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 70, No. 22 ( 2021), p. 222801-
    Abstract: The data of neutron capture cross section are very important for the research of nuclear astrophysics, advanced nuclear energy development. Owing to the limitation of neutron source and detector, the experimental data of neutron capture cross section in an energy range of 1 eV–10 keV were almost blank in China. The first Chinese gamma-ray total absorption facility has been constructed in the key laboratory of nuclear data at China institute of atomic energy, which consists of 40 BaF〈sub〉2〈/sub〉 detector units. The BaF〈sub〉2〈/sub〉 crystal shell with a thickness of 15 cm and an inner radius of 10 cm covers 95.2% of the solid angle. On-line measurement method of neutron capture reaction cross section is established on the back-streaming white neutron source of China spallation neutron source by using the upgraded facility. The cross section of 〈sup〉197〈/sup〉Au neutron capture reaction is measured for the first time under the experimental condition of irregular 30 mm neutron beam spot. The measured position of resonance peak is well consistent with the relevant data of ENDF evaluation database, which verifies the reliability of the measurement device and measurement technology, and thus laying the foundation for the acquisition of high precision cross section in future.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2021
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  • 4
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2020
    In:  Acta Physica Sinica Vol. 69, No. 17 ( 2020), p. 172901-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 69, No. 17 ( 2020), p. 172901-
    Abstract: The back-streaming neutron beam line (Back-n) was built in the beginning of 2018, which is part of the China Spallation Neutron Source (CSNS). The Back-n is the first white neutron beam line in China, and its main application is for nuclear data measurement. For most of neutron-induced nuclear reaction measurements based on white neutron facilities, the beam of gamma rays accompanied with neutron beam is one of the most important experimental backgrounds. The back streaming neutron beam is transported directly from the spallation target to the experimental station without any moderator or shielding, the flux of the in-beam gamma rays in the experimental station is much larger than those of these facilities with neutron moderator and shielding. Therefore, it is necessary to consider the influence of in-beam gamma rays on the experimental results. Studies of the in-beam gamma rays are carried out at the back-n. Monte-Carlo simulation is employed to obtain the energy distribution and the time structure of the in-beam gamma rays. According to the simulation results, when the neutron flight time is longer than 1.0 μs the energy distribution of the in-beam gamma rays does not vary with flight time. Therefore, the time structure of these gamma rays can be measured without the correction of the detection efficiency. In this work, the time structure of the in-beam gamma rays in the low neutron energy region is measured by both direct and indirect methods. In the direct measurement, a 〈sup〉6〈/sup〉Li loaded ZnS(Ag) scintillator is located on the neutron beam line and the time of flight method is used to determine the time structure of neutrons and gamma rays. The gamma rays are separated from neutrons with pulse-shape discrimination. The black filter method is used to verify the particle discrimination results. In the indirect measurement, the C〈sub〉6〈/sub〉D〈sub〉6〈/sub〉 scintillation detectors are used to measure the gamma rays scattered off a Pb sample on the way of the neutron beam. The time structure of the in-beam gamma rays is derived from that of the scattered gamma rays. The experimental results are in good agreement with the simulations with the time-of-flight between 12 μs and 2.0 ms. Besides, according to the simulation results, the intensity of the in-beam gamma rays is 1.21 × 10〈sup〉6〈/sup〉 s〈sup〉–1〈/sup〉·cm〈sup〉–2〈/sup〉 in the center of the experimental station 2 of Back-n, which is 76.5 m away from the spallation target of CSNS.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2020
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  • 5
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2021
    In:  Acta Physica Sinica Vol. 70, No. 19 ( 2021), p. 197901-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 70, No. 19 ( 2021), p. 197901-
    Abstract: As a novel low-cost semiconductor with extraordinary photoelectric property, the inorganic CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskites have become emerging materials for the next generation of X-ray detectors in the past decade. However, most of recent studies of CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskite X-ray detectors are based on their internal photoelectric effect. Though it is also important and widely used in vacuum X-ray detectors, the external photoelectric effect of CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskite has been rarely studied by now. Thus, the response sensitivity of the CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskite’s external photoelectric effect in the X-ray region is studied in the present paper. First, a 230-nm-thick CsPbI〈sub〉2〈/sub〉Br membrane is prepared on a metal substrate by a conventional one-step deposition method, with a precursor solution used. Then the external photoelectric responsivity and quantum efficiency of the CsPbI〈sub〉2〈/sub〉Br membrane are calibrated in a range from 2000 to 5500 eV at Beijing Synchrotron Radiation Facility. The responsivity is over 5.1 × 10〈sup〉–5〈/sup〉 A/W in the range and the quantum efficiency is over 23%. These calibration data are close to those of a traditional X-ray photoelectric material CsI. The Monte-Carlo method is utilized to simulate the external photoelectric effect of CsPbI〈sub〉2〈/sub〉Br perovskite, and the external photoelectric responsivity is calculated. The calculated data match well with the calibration, proving the Monte-Carlo method feasible for the external photoelectric effect simulation of CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskite. Then the external photoelectric responsivities and quantum efficiencies of CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskites are calculated via the Monte-Carlo method in the X-ray range from 2000 to 10000 eV. The calculated responsivities of different CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskites are all close to the responsivity of CsI, and an order of magnitude higher than that of Au, and the CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 quantum efficiencies also follow a similar scenario. This indicates that CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 perovskites have good external photoelectric properties and potential applications in X-ray vacuum detectors such as photocathode and photomultiplier. The influence of thickness on CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 photoelectric response is also studied in this paper via Monte-Carlo simulation. The results show that the responsivity increases with the material thickness increasing, which is due to the increased X-ray absorption. The responsivities all reach their upper limits at a material thickness of about 150 nm, which means that the electrons generated at 150 nm can hardly escape from the material surface. It is indicated that the thickness of CsPb〈i〉X〈/i〉〈sub〉3〈/sub〉 should be no less than 150 nm to obtain the optimal photoelectric response.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2021
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  • 6
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2023
    In:  Acta Physica Sinica Vol. 72, No. 19 ( 2023), p. 199501-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 72, No. 19 ( 2023), p. 199501-
    Abstract: High altitude detection of astronomical radiation (HADAR) is an innovative array of atmospheric Cherenkov telescopes that employs pure water as its medium. By utilizing large-aperture hemispherical lenses, HADAR can capture atmospheric Cherenkov light, enabling the detection of gamma rays and cosmic rays in the energy range of 10 GeV to 10 TeV. Compared to traditional Imaging Atmospheric Cherenkov telescopes, HADAR offers distinct advantages such as a low energy threshold, high sensitivity, and a wide field of view. The telescope mainly consists of a hemispherical lens with a diameter of 5 m acting as a Cherenkov light collector, a cylindrical metal tank with a 4 m radius and 7 m height, and an imaging system at the bottom of the tank. The sky region covered by HADAR is much larger than the current generation of Imaging Atmospheric Cherenkov Telescopes. The field of view of HADAR can reach up to 60 degrees. Its continuous scanning capability allows for comprehensive observations of gamma-ray sources throughout the entire celestial sphere, making it an ideal instrument for studying transient and variable sources. In this study, the observational capabilities of HADAR are thoroughly investigated using the latest 4FGL-DR3 and 4LAC-DR3 gamma-ray source catalogs from Fermi-LAT. For extragalactic sources, the energy spectra in the high energy range have been extrapolated to the very high energy range, taking into account the absorption effect caused by extragalactic background light. By comparing the extrapolated results with existing VHE experimental data, the feasibility of this extrapolation method has been demonstrated. Through simulated analyses of the significance of these sources, it is anticipated that HADAR will detect a total of 93 gamma-ray sources with a significance exceeding 5 standard deviations during one year of operation. These sources comprise 45 galactic sources, 39 extragalactic sources, 3 sources of unknown type, and 6 unassociated sources.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2023
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  • 7
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 0, No. 0 ( 2023), p. 0-
    Abstract: Laser point-scanning fluorescence microscopy has emerged as an indispensable tool in the field of life science research, owing to its merits of exceptional resolution, heightened sensitivity, remarkable specificity, and three-dimensional optical-sectioning capability, and dynamic imaging. However, conventional laser point-scanning fluorescence microscopy confronts a profound array of challenges in the rapidly evolving field of life sciences, due to the limitations imposed by optical diffraction and point scanning detection. Over the past two decades, substantial advancements have been made in super-resolution fluorescence microscopic imaging techniques. Researchers have developed various high spatial and temporal resolution point-scanning microtechnic, which hold great significance for biological optical imaging and other related applications. Regrettably, there are still few review articles covering the recent progress of this fields. It is essential to provide a comprehensive review of laser point-scanning fluorescence microscopy techniques for their future developments and trends. This article primarily introduces the basic principles and recent advances in different point-scanning fluorescence microscopy techniques from dual perspectives:temporal and spatial resolution, then summarizes the progress and applications of high spatio-temporal resolution microscopic imaging techniques based on point-scanning mode, and finally discusses the future trends and challenges of high spatio-temporal resolution point scanning fluorescence microscopic imaging.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2023
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  • 8
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 69, No. 22 ( 2020), p. 228501-
    Abstract: Lithium (Li) metal is regarded as one of the most promising anodes in the next-generation high-energy-density rechargeable batteries due to its ultrahigh theoretical specific capacity and low reduction potential. Nevertheless, the unstable solid electrolyte interphase on the surface of Li metal anode and the nonuniform Li deposition seriously hinder its practical applications. Currently, mild conditions are employed in the researches of Li metal anode, which is of great significance for fundamentally understanding the physicochemical features of the anode interface and the mechanisms of Li deposition. However, practical conditions including ultrathin Li metal anode (〈 50 μm), low negative/positive electrode areal capacity ratio (〈 3.0), and lean electrolyte (〈 3.0 g·Ah〈sup〉–1〈/sup〉) are the premise to realize high energy density of Li metal batteries (〉 350 W·h·kg〈sup〉–1〈/sup〉). Herein, the gaps of Li metal anode under mild and practical conditions in terms of the cycling stability and surface morphology are compared and the reasons for the gaps are analyzed carefully. The total quantity of active Li metal decreases and the utilization depth of Li per cycle has been greatly improved under practical conditions. Therefore, the huge volume fluctuation and uneven Li deposition result in ceaseless destruction and regeneration of solid electrolyte interphase, and thus consuming the lean electrolyte and generating a large quantity of dead Li rapidly. Consequently, the polarization voltage of Li metal anode increases rapidly and the cycling stability of Li metal batteries deteriorates evidently under practical conditions. Moreover, the electrochemical reaction of Li metal anode is accelerated while fast charge/discharge process is employed, which further aggravates the stability of Li metal anode. This work reveals the challenges of Li metal anode under practical conditions and present the perspectives for the further researches in practical Li metal anode, which conduces to the solid development of high-energy-density Li metal batteries.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2020
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  • 9
    Online Resource
    Online Resource
    Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences ; 2023
    In:  Acta Physica Sinica Vol. 72, No. 4 ( 2023), p. 049501-
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 72, No. 4 ( 2023), p. 049501-
    Abstract: The High Altitude Detection of Astronomical Radiation (HADAR) experiment is a refracting terrestrial telescope array based on the atmospheric Cherenkov imaging technique. It is a hybrid array consisting of four water-lens telescopes and a surrounding scintillation detector array for observing Cherenkov light induced by 10 GeV–10 TeV cosmic rays and gamma rays in the atmosphere. The water-lens telescope mainly consists of a hemispherical lens with a diameter of 5 m acting as a Cherenkov light collector, a cylindrical metal tank with a 4 m radius and 7 m height, and an imaging system at the bottom of the tank. The sky region covered by HADAR is much larger than the current generation of Imaging Atmospheric Cherenkov Telescopes, and even the CTA. The field-of-view (FOV) of HADAR can reach up to 60 degrees. The HADAR experiment possesses the advantages of a large field-of-view and low energy threshold, so it can continuously scan wide portions of the sky and easily observe extragalactic gamma-ray sources. The majority of the extragalactic gamma-ray sources detected at very high energy (VHE) energies are active galactic nuclei (AGNs). In this study, we present the potential of using the HADAR experiment for detecting AGN. Based on the AGN catalog sources of the Fermi Large Area Telescope (Fermi-LAT), the observed energy is extrapolated to the VHE range. The VHE gamma rays propagating over cosmological distances can interact with the low-energy of the extragalactic background light (EBL) and produce electron-positron pairs. Therefore, we consider the absorption effects of different EBL models when calculating the expected gamma ray spectra of the AGN sample. We select the sample with redshift measurements and locations inside the FOV of HADAR from 4LAC catalog. In total, there are 375 BL Lacertae objects (BL Lacs) and 289 flat-spectrum radio quasars (FSRQs) satisfying the selection conditions. The integral gamma ray spectra are derived and compared with the sensitivity curve of HADAR, the number of sources with fluxes above the sensitivity of HADAR is counted. Further, we calculate the statistical significance of HADAR for AGN source observation based on the equi-zenith angle sky scanning analysis method. The simulation results reveal that a total of 31 sources of Fermi-LAT AGN can be detected by HADAR with a significance greater than five standard deviations over a one-year survey period, most of which are BL Lacs.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2023
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  • 10
    In: Acta Physica Sinica, Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences, Vol. 72, No. 9 ( 2023), p. 097101-
    Abstract: Grain size refinement is the vital stratagem for improving mechanical properties of Bi〈sub〉2〈/sub〉Te〈sub〉3〈/sub〉-based thermoelectric material. However, the donor-like effect induced by grain size refinement seriously deteriorates the thermoelectric properties especially near room temperature. Once the donor-like effect is generated, it is very difficult to eliminate the donor-like effect by the simple heat treatment process and other processes. In this study, the influences of particle size on the donor-like effect and thermoelectric properties are systematically studied for Bi〈sub〉2〈/sub〉Te〈sub〉3〈/sub〉-based compounds. As the particle size decreases, the donor-like effect is enhanced significantly. The oxygen-induced donor-like effect dramatically increases the carrier concentration from 3.36× 10〈sup〉19〈/sup〉 cm〈sup〉–3〈/sup〉 for 10 M sintered sample to 7.33×10〈sup〉19〈/sup〉 cm〈sup〉–3〈/sup〉 for 120 M sintered sample, which is largely beyond the optimal carrier concentration of 2.51×10〈sup〉19〈/sup〉 cm〈sup〉–3〈/sup〉 and seriously deteriorates the thermoelectric properties. However, when the particle size of the powder is 1–2 mm, the Seebeck coefficient of –195 μV/K and the carrier concentration of 3.36×10〈sup〉19〈/sup〉 cm〈sup〉–3〈/sup〉 near room temperature are achieved, which are similar to those of the ZM sample with the Seebeck coefficient of –203 μV/K and the carrier concentration of 2.51×10〈sup〉19〈/sup〉 cm〈sup〉–3〈/sup〉. The powders without the obvious donor-like effect can be used as the excellent raw material for powder metallurgy process. A maximum 〈i〉ZT〈/i〉 value of 0.75 is achieved for the 18 M sintered sample. The excellent thermoelectric properties are expected to be obtained by enhancing the texture further. This study provides a new way to regulate and effectively suppress the generation of the donor-like effect, and provides an important guidance for the preparation of materials with excellent thermoelectric and mechanical properties by powder metallurgy process.
    Type of Medium: Online Resource
    ISSN: 1000-3290 , 1000-3290
    Language: Unknown
    Publisher: Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
    Publication Date: 2023
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