Description: We present ten 40Ar/39Ar age determinations, both on primary volcanic deposits and on detrital sanidine, which provide geochronologic control on the MIS 5.5 and MIS 5.3 sea-level indicators that occur at three coastal caves in the central Tyrrhenian Sea of Italy. Samples dated for the present work are as follows: - Two pumice clasts (MOSC-22, MOSC-37) extracted from the sand layers constituting the sedimentary fill of Moscerini Cave, recovered during the original archaeological excavations performed in the year 1949, stored at the IIPU (Istituto Italiano di Paleontolgia Umana) repository in Anagni (Frosinone, italy). These two samples were processed at the rare Gas Laboratory of the University of Wisconsin Madison in March, 2019. - One tephra layer (sample GDC-10) intercalated in the sedimentary fill of Capre Cave collected in June, 2021. - Seven sedimentary sand samples collected at Guattari Cave (GU-1, GU-5, GU-105, GU-116) in June, 2020, and at Capre Cave (GDC-6, GDC-8, GDC-0) in June, 2021 . These dates constrain the age of a Strombus-bearing biodetritic conglomerate associated with a tidal notch occurring at 9.5 m a.s.l. at Cape Circeo between 121.5±5.8 and 116.2±1.2 ka. Moreover, deposition of backbeach deposits intercalated in the sedimentary filling of Guattari and Capre coastal caves is bracketed in the interval 110.4±1.4 ka to 104.9±0.9 ka. Such deposits are directly correlated with a tidal notch at ~2.5 m associated with another biodetritic conglomerate at Cape Circeo. The latter is correlated with the adjacent marine terrace, occurring at 3-5 m in the coast between Capes Circeo and Anzio, for which a maximum age of 100.7±6.6 ka was previously reported. These data provide evidence for a maximum sea level around 9.5 m above the present sea level and a duration of MIS 5.5 highstand until 116 ka, in line with estimation from other regions in the world. In contrast, they suggest a maximum sea level during MIS 5.3 highstand that is similar to the present level, and only ~7 m lower than the MIS 5.5 highstand, challenging the reconstructions of the MIS 5 ice-sheet volumes and derived global sea levels that are based on the benthic oxygen isotope records.

Description: Bio- and magnetostratigraphic age data and nannofossil assemblage analysis from ODP Site 1165 evidence an anomalous warming event of the surface waters in and around Prydz Bay during the Early Pleistocene, approximately 1 Ma. This results from an increase in the abundance of nannofossils at Site 1165, that occurred at 1 Ma. Detailed high-resolution sampling permits a new bio-magnetostratigraphic interpretation for ODP Site 1165. A decrease in delta18O values at Sites 1165 and 1167 also occurs at this time, supporting the presence of warming conditions in the Prydz Bay area. A return to colder surface waters, indicated by the absence or rare occurrence of nannofossils in the upper cores from Site 1165, suggests that more stable glacial conditions existed in the Prydz Bay basin, for the last 900 ka. The biogenic carbonate sequence identified at Site 1167 is similar to the carbonate shales recovered from the Cape Roberts Project 1. Both have been dated at about 1 Ma, supporting the idea that a significant surface waters warming occurred during the Pleistocene. These data and the presence of calcareous nannofossils from locations around the Antarctic continent also suggest that the warming event was not limited to the analysed basin, but it extended around the East Antarctic continent. These new evidence call for a re-evaluation of the notion that the East Antarctic Ice-Sheet has experienced stable conditions similar to today since the late Neogene.

Description: Magnetostratigraphic studies of Paleogene sediments piston-cored on Maud Rise, Weddell Sea (ODP Sites 689 and 690), are a cornerstone of Southern Ocean Paleogene and Neogene chronostratigraphy. However, parts of previous magnetostratigraphic interpretations have been called into question, and recent reinvestigation of the upper Paleocene-middle Eocene portion of Site 690 suggested that the records might be contaminated by spurious magnetizations, which raises doubts about the reliability of these important records. We undertook a high-resolution magnetostratigraphic study of Eocene-Oligocene u-channel samples from ODP Holes 689B, 689D, 690B, and 690C in order to address these concerns. A pervasive overprint appears to be present below the middle Eocene, which compromises magnetobiostratigraphic interpretations for the upper Cretaceous and lower Paleogene. Nevertheless, our new results provide a robust record of geomagnetic field behavior from 38.5 to 25 Ma and confirm the reliability of these sediments for calibration of biostratigraphic datum events during a crucial phase of earth history when major Antarctic ice sheets developed. Also, comparison of magnetozone thicknesses in multiple holes at the same site indicates that ~1.2-1.8 m of the stratigraphic record is missing at each core break, which corresponds to time breaks of 120-360 k.y. Lack of a continuous record within a single hole renders useless spectral analyses for investigating long geomagnetic and paleoclimatic time series. This observation reinforces the need for coring of multiple offset holes to obtain continuous paleoceanographic records. Sedimentary hiatuses have been identified only at the deeper of the two investigated sites (Site 690), which could mark a local response to the onset of the Antarctic Circumpolar Current.

Description: An exceptional triple palynological signal (unusually high abundance of marine, freshwater, and terrestrial palynomorphs) recovered from a core collected during the 2007 ANDRILL (Antarctic geologic drilling program) campaign in the Ross Sea, Antarctica, provides constraints for the Middle Miocene Climatic Optimum. Compared to elsewhere in the core, this signal comprises a 2000-fold increase in two species of dinoflagellate cysts, a synchronous five-fold increase in freshwater algae, and up to an 80-fold increase in terrestrial pollen, including a proliferation of woody plants. Together, these shifts in the palynological assemblages ca. 15.7 Ma ago represent a relatively short period of time during which Antarctica became abruptly much warmer. Land temperatures reached 10 °C (January mean), estimated annual sea-surface temperatures ranged from 0 to 11.5 °C, and increased freshwater input lowered the salinity during a short period of sea-ice reduction.

Description: We provide a dataset of 40Ar/39Ar age constraints for seven samples of sedimentary deposits recovered from a 120 m deep borehole drilled in the city of Rome in the year 2022. Twenty to thirty sanidine crystals were separated from the sandy matrix of the gravel beds obtained from the borehole. Each gravel bed is part of an aggradational succession deposited in response to sea-level rise in the delta of the Paleo-Tiber River during the late Lower Pleistocene. These aggradational successions are characterized by a sharp boundary that separates a layer of well-rounded limestone and chert pebbles, with diameters reaching up to approximately 10 cm, embedded in a matrix of silty sand (0.5-1.0 mm). This layer is distinct from another layer of mostly clayey (〈0.004 mm) and sandy (〈0.5 mm) sediments that is several meters thick. Based on the conceptual model of aggradational successions proposed by Marra et al. (2016, doi:10.1016/j.epsl.2016.05.037), the sharp sedimentary boundaries are used as a proxy for glacial terminations. The achieved geochronologic constraints allow for an overall good correlation between each aggradational succession, represented by the basal coarse gravel abruptly transitioning to sandy clay sediments, and each period of sea-level rise inferred from the d18O curve in the interval encompassing MIS 19 through MIS 37, 780 through 1250 ka.

Description: The site for CRP-3, 12 km east of Cape Roberts (77.006°S; 103.719°E)was selecte to overlap the lower Oligocene strata cored in nearby CRP-2/2A, and to sample the oldest strata in the Victoria Land Basin (VLB) for Paleogene climatic and tectonic history. As it transpired there was underlap of the order of 10s of metres. CRP-3 was cored from 3 to 939 mbsf (metres below the sea floor), with a core recovery of 97%. Coring took place from October 9 to November 19, 1999, on 2.0 to 2.2 m of sea ice and through 295 in of water. The Cenozoic strata cored were mostly g1acially influenced marine sediments of early Oligocene age, though they may be earliest Eocene near the base, where at 823 mbsf Devonian Beacon sandstone was encountered. Following CRP-1 and CRP-2/2A, CRP-3 completes the coring of 1500 m of strata on the western margin of the VLB. Core fractures and other physical properties, such as sonic velocity, density and magnetic susceptibility, were measured throughout the core. Down-hole logs for these and other properties were taken from 20 down to 900-919 mbsf. Also, vertical seismic profile data were gathered from shots offset both along strike and up dip from the hole. Sonic velocities in CRP-3 are close to 2.0 km/s in the upper 80 m, but become significantly faster below 95 mbsf, averaging 3.2+0.6 km/s to the bottom of the hole. An exception to this is an interval of dolerite conglomerate from 790 to c. 820 mbsf with a velocity of c. 4.5 km/s. Dip of the strata also increases down-hole from 10° in the upper 100 m to around 22° at the bottom. Over 3000 fractures were logged through the hole, and borehole televiewer imagery was obtained for most of the hole for orienting core and future stress field analysis. Two high-angle crush zones, interpreted as faults, were encountered at c. 260 and c. 540 mbsf, but no stratigraphic displacement could be recognised. A third fault zone is inferred from a low angle shear zone in the upper part of a coarse dolerite conglomerate from 790 to 805 mbsf. Temperature gradient was found to be 28.5°.km-1. Basement strata cored from 823 mbsf to the bottom of the hole are largely light-reddish brown medium-grained sandstone (quartz-cemented quartzarenite) with abundant well-defined parallel lamination. These features are comparable with the middle Devonian part of the Beacon Supergroup, possibly the Arena Sandstone. This interval also includes a body of intrusive rock from 901 to 920 mbsf. It has brecciated contacts and is highly altered but some tholeiitic affinity can be recognised in the trace element chemistry. Its age is unknown. Post-Beacon sedimentation began on deeply eroded quartzarenite with the deposition of a thin sandstone breccia and conglomerate, probably as terrestrial talus, followed by dolerite conglomerate and minor sandstone of probable fluvial origin to 790 mbsf. Sedimentation continued in a marine setting, initially sandstone and conglomerate, but above c. 330 mbsf the strata include mudstone and diamictite also. The older sandstone and conglomerate beds are seen as the products of rapid episodic sedimentation. They are interpreted by some as the product of glaciofluvial discharge into shallow coastal waters, and others as a result of sediment gravity flows, perhaps glacially sourced, into deeper water. The core above c. 330 mbsf has facies that allow the recognition of cyclic sequences similar to those in CRP-2A. Fourteen unconformity-bounded sequences have been recognised from 330 mbsf to the sea floor, and are interpreted in terms of glacial advance and retreat, and sea level fall and rise. Detailed lithological descriptions on a scale of 1 :20 are presented for the full length of the core, along with core box images, as a 300 page supplement to this issue. The strata cored by CRP-3 are for the most part poorly fossiliferous, perhaps as a consequence of high sedimentation rates. Nevertheless the upper 200 m includes several siliceous microfossil- and calcareous nannoplankton-bearing intervals. Siliceous microfossils, including diatoms, ebrideans, chrysophycean cysts and silicoflagellates are abundant and well-preserved in the upper 67 m - below this level samples are barren or poorly preserved, but contain residual floras that indicate assemblages were once rich. No siliceous microfossils were found below 193 mbsf. Calcareous nannofossil have a similar distribution but are generally well preserved. Foraminifera, marine and terrestrial palynomorphs, and marine macrofossils were found consistentlsy down to c. 330 mbsf and sporadically to 525 mbsf. The taxa suggest marine deposition in water depth of c. 50 to 120 m. Below 525 mbsf no microfossils were found, apart from mudstone with similar marine and terrestrial palynomorphs at 781 mbsf, and rare miospores in the conglomerate below 790 mbsf. The terrestrial miospore record, which include several species of Nothofagus and podocarpaceous conifers, suggest low diversity woody vegetation, implying a cold temperate to periglacial climate for the hinterland throughout the period recorded by CRP-3. Important components of the warmer Eocene flora, known from erratics in southern McMurdo Sound, are missing, through the dominance of smectite in clay from strata below 650 mbsf suggests that the landscape prior to the timne of deposition had experienced a more temperate weathering regime. Biostratigraphy for ihe upper part of CRP-3 is provided by diatoms and calcareous nannofossils. The first appearance of Cavitatus jouseanus at 48 mbsf suggests an age of arround 31 Ma for this horizon. The last appearance of Transverspontis pulcheroides at 114 mbsf in an interval of relatively high abundance indicates a reasonably sound age for this horizon at 32.5 ± 0.5 Ma. The absence of particular resistant diatoms that are older than 33 Ma supports an age that is younger than this for the upper 200 m of CRP-3. Marine palynomorphs, which occur sporadically down to 525 mbsf and in a single occurrence at 781 inbsf, have biostratigraphical potential once the many new species in this and other CRP cores are described, and F0 and LO datums established. The mudstone at 781 mbsf has a new clinocyst species, rare Lejeunecysta cysts and a variety of acritarchs and prasinophytes, a varied marine assemblage that is quite different from and presumably younger than the well known Transantarctic Flora of mid to late Eocene age. On this basis and for the moment we conclude that the oldest strata in CRP-3 are earliest Oligocene (or possibly latest Eocene) in age - c. 34 Ma. Over 1l00 samples were taken for magnetic studies. Four magnetozones were recognisd on the basis of NRM intensity and magnetic susceptibility, reflecting the change in sediment composition between quartz sand-dominated and dolerite-dominated. For this report there was time only to produce a magnetostratigraphy for the upper 350 m. This interval is largely of reversed polarity (5 normal intervals total 50 of the 350 m), in contrast to the dominantly normal polarities of CRP-2/2A, and is inferred to be Chron C12R. This extends from 30.9 to 33 Ma. consistent with the biostratigraphic datums from the upper part of CRP-3. The lower limit of reversed polarity has yet to be established. The short period normal events are of interest as they may represent cryptochrons or even polarity changes not recognised in the Geomagnetic Polarity Time Scale. Erosion of the adjacent Transantarctic Mountains through the Kirkpatrick Basalt (Jurassic tholeiitic flows) and dolerite-intruded Beacon Supergroup (Devonian-Triassic sandstone) into granitic basement beneath is recorded by petrographical studies of clast and sand grain assemblages from CRP-3. The clasts in the lower 30 m of the Cenozoic section are almost entirely dolerite apart from a few blocks from the Beacon Supergroup beneath. Above this, however, both dolerite and granitoids are ubiquitous, the latter indicating that erosion had reached down to granitic basement even as the first sediment was accumulating in the VLB. No clasts or sand grains of the McMurdo Volcanic Group were found, but rare silt-size brown volcanic glass occurs in smear slides through most of CRP-3, and is interpreted as distal air fall from alkaline volcanism in northern Victoria Land. Jurassic basalt occurs as clasts sporadically throughout the sequence: in the sand fraction they decline upwards in abundance. The influence of the Devonian Beacon Supergroup is most striking for the interval from 600 to 200 mbsf, where quartz grains, from 10 to 50% of them rounded, dominate the sand fraction. Laminae of coal granules from the overlying Permian coal measures in all but the upper 150 in of the CRP-3 sequence show that these also were being eroded actively at this time. CRP-3 core completed the stratigraphical sampling of the western margin of the VLB by not only coring the oldest strata (Seismic Unit V5) but also the basin floor beneath. This has several important tectonic implications: - most of the Kirkpatrick Basalt and the Beacon Supergroup with the sills of Ferrar Dolerite have been eroded by the time down-faulting displaced the Beacon to form the basin floor. - matching the Beacon strata at the bottom of CRP-3 with the equivalent strata in the adjacent mountains suggests c. 3000 m of down-to-the-east displacement across the Transantarctic Mountain Front as a consequence of rifting and subsequent tectonic activity. - the age of the oldest Cenozoic strata in CRP-3 (c. 34 Ma), which are also the oldest strata in this section of the VLB, most likely represents the initiation of the rift subsidence of this part of the West Antarctic Rift System. This age for the oldest VLB fill is much younger than previously supposed by several tens of millions of years, but is consistent with newly documented sea floor spreading data immediately north of the northern Victoria Land continental margin. These new data sets will drive a re-evaluation of the relationship between initiation of uplift of the Transantarctic Mountains (currently c.55 Ma) and VLB subsidence.

Description: Thirty years after oxygen isotope records from microfossils deposited in ocean sediments confirmed the hypothesis that variations in the Earth's orbital geometry control the ice ages (Hays et al., 1976, doi:10.1126/science.194.4270.1121), fundamental questions remain over the response of the Antarctic ice sheets to orbital cycles (Raymo and Huybers, 2008, doi:10.1038/nature06589). Furthermore, an understanding of the behaviour of the marine-based West Antarctic ice sheet (WAIS) during the 'warmer-than-present' early-Pliocene epoch (~5-3 Myr ago) is needed to better constrain the possible range of ice-sheet behaviour in the context of future global warming (Solomon et al., 2007). Here we present a marine glacial record from the upper 600 m of the AND-1B sediment core recovered from beneath the northwest part of the Ross ice shelf by the ANDRILL programme and demonstrate well-dated, ~40-kyr cyclic variations in ice-sheet extent linked to cycles in insolation influenced by changes in the Earth's axial tilt (obliquity) during the Pliocene. Our data provide direct evidence for orbitally induced oscillations in the WAIS, which periodically collapsed, resulting in a switch from grounded ice, or ice shelves, to open waters in the Ross embayment when planetary temperatures were up to ~3° C warmer than today ( Kim and Crowley, 2000, doi:10.1029/1999PA000459) and atmospheric CO2 concentration was as high as ~400 p.p.m.v. (van der Burgh et al., 1993, doi:10.1126/science.260.5115.1788, Raymo et al., 1996, doi:10.1016/0377-8398(95)00048-8). The evidence is consistent with a new ice-sheet/ice-shelf model (Pollard and DeConto, 2009, doi:10.1038/nature07809) that simulates fluctuations in Antarctic ice volume of up to +7 m in equivalent sea level associated with the loss of the WAIS and up to +3 m in equivalent sea level from the East Antarctic ice sheet, in response to ocean-induced melting paced by obliquity. During interglacial times, diatomaceous sediments indicate high surface-water productivity, minimal summer sea ice and air temperatures above freezing, suggesting an additional influence of surface melt (Huybers, 2006, doi:10.1126/science.1125249) under conditions of elevated CO2.

Description: The Paleocene-Eocene Thermal Maximum (PETM) is the most studied global warming event of a series of Paleocene-Eocene carbon cycle perturbations called hyperthermals. PETM origins have been associated with volcanic-related carbon emissions; however, other carbon cycle feedbacks were required to develop a large hyperthermal such as the PETM. The orbital configuration in which the PETM occurred is still unclear despite possible orbital controls on the PETM triggering. This dataset contains X-Ray Fluorescence (XRF) data (Fe, Ca, and Si) from Contessa Road (Italy), a sedimentary section with reduced calcium carbonate dissolution compared to deep ocean sites. Astrochronological age models and probabilistic assessments reveal that the PETM onset appeared close to both short and long eccentricity maxima, which suggests that orbitally controlled insolation variations may have thermally destabilized carbon reservoirs that worked as PETM positive carbon cycle feedbacks.