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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 73 (1988), S. 9-13 
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract In this article, the crystal structure and superconductivity of a new superconducting phase TlBa2CaCu2O6.5 (T c =72.5 K) in Tl−Ba−Ca−Cu−O system are studied. The crystal structure of the compound TlBa2CaCu2O6.5 has been determined by means of X-ray powder diffraction method. It belongs to primary tetragonal lattice with lattice parameters:a=3.847 Å,c=12.73 Å. Its space group isD 4h 1 −P4/mmm. Each unit cell contains one formular unit. The arrangements of ions in a unit cell are following: 1 Ca, and 1 Tl cations occupy 1(a) and 1(d) equivalent point positions respectively. 2 Cu cations occupy 2(h) (z=0.127) equivalent point positions. 2 Ba cations occupy 2(g) (z=0.281) equivalent point positions. 6.5 O anions respectively occupy 1(b), 2(h) (z=0.281) and 4(i) (z=0.127) equivalent point positions. Occupation factor is 0.929. The crystal structure of TlBa2CaCu2O6.5 is quite similar to those of the other superconducting phases in Tl−Ba−Ca−Cu−O system. All cations are distributed at positions of (0, 0,z) and (1/2, 1/2,z) alternately. The oxygen deficient pseudo-perovskite unit Ba−Cu−Ca−Cu−Ba is separated two Tl−O layers in the crystal structure of Tl2Ba2CaCu2O8. However, the oxygen deficient pseudo-perovskite unit Ba−Cu−Ca−Cu−Ba is separated by single Tl−O layer in the crystal structure of TlBa2CaCu2O6.5. The relations among the crystal structures of the superconducting phases as well as the relation between the crystal structure and superconductivity are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Diabetologia 29 (1986), S. 225-228 
    ISSN: 1432-0428
    Keywords: Crystallin ; glycosylation ; conformation ; diabetes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary Lens crystallins undergo non-enzymatic glycosylation with aging and diabetes mellitus. It is not known, however, whether all crystallins are subject to the same extent of glycosylation. Human diabetic lenses ( ∼80 years of age) were dissected into cortex and nucleus, then fractionated into various crystallins with gel chromatography (Sephacryl S-200, Sephdex G-75 or Bio Gel A-1 5m). The glycosylated crystallins were then separated from the nonglycosylated crystallins by affinity chromatography on Glyco Gel B boronic acid. The percentage of glycosylated crystallin was about 20–30%, and did not differ much among most crystallins, although γ-crystallin has significantly less (p 〈 0.01) glycosylated protein. The extent of glycosylation in the glycosylated crystallins, however, was found to be greater in the high molecular weight crystallins. The extent of glycosylation in α-crystallins is approximately two to four times that observed in β- or γ-crystallin. The extent of glycosylation appears to depend not only on the lysine content, which does not vary much among the crystallins, but also on the accessibility of the surface areas where lysine residues are located. This accessibility depends on the protein conformation and appears to correlate with protein unfolding.
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 41 (1985), S. 1586-1588 
    ISSN: 1420-9071
    Keywords: Mitotic arrestants ; spermatocyte ; chromosomes ; meiotic metaphase accumulation
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Three mitotic arrestants, colchicine, Colcemid and vinblastine, were evaluated for their effects on producing meiotic arrest in the laboratory mouse. Colchicine is the most effective and its effect is both dose- and time-dependent. Treatment of mice with 40 mg/kg of colchicine for 3 h resulted in drastic improvement of the yield and quality of M-II figures. This treatment did not appear to increase the aneuploidy frequency in M-II's.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1432-1203
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Abstract Following fusion with hamster eggs, human sperm chromosomes from six Hodgkin's disease patients were analyzed to determine the genotoxic effects of therapy. Each patient had received two to six cycles of MOPP (nitrogen mustard, vincristine, procarbazine, and prednisone), with or without radiotherapy, from 3 to 20 years before the study. A total of 571 cells from the six patients were analyzed; 9.8% of the cells had structural aberrations, and 1.6% were hyperhaploid. Analysis of 5998 metaphases from a control group of 24 male donors revealed only 6.9% of cells with structural aberrations and 0.8% aneuploidy. The increase in hyperhaploidy in the patients was statistically significant. Thus, results of this study suggest that the MOPP regimen, with or without radiotherapy, is capable of causing chromosome abnormalities in the sperm of Hodgkin's disease patients.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Rock mechanics and rock engineering 27 (1994), S. 115-134 
    ISSN: 1434-453X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: Summary Groundwater control is a means of ensuring that no gas leakage occurs from unlined rock storage caverns. To achieve a better understanding of the principles of gas containment under groundwater and how to obtain maximum gas storage capacity, analyses of groundwater conditions surrounding storage caverns and the effects of different factors on gas storage capacity have been performed and are reported in this paper. The analysis results indicate that the critical gas pressure of a storage facility is considerably less than the natural hydrostatic pressure around the caverns and somewhat less than the water curtain pressure. High gas storage capacity can be obtained by optimizing the design of cavern configuration, water curtain layout, cavern depth, etc. The principles of such optimization are outlined in this paper.
    Type of Medium: Electronic Resource
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  • 6
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A series of Ba2(Y1−x Pr x )Cu3O9−y solid solutions were prepared with the orthorhombic distorted perovskite structure. The compound Ba2PrCu3O9−y belonging to tetragonal system is a good semiconductor. The superconductivity is observed for samples withx〈0.6. With the increase of Y content, the distortion of crystal structure is greater and the superconductive transition temperature of zero resistanceTc(0) raises.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The crystal structure of the superconducting phase TlSr2Ca1−xErxCu2O6.5+x/2 (x=0.5) in the Tl−Sr−Ca−Er−Cu−O system was determined using the X-ray powder diffraction method. It belongs to a primary tetragonal cell with lattice constantsa=3.798,c=12.014 Å, with a space group ofD 4h 1 −P4/mmm. Each unit cell contains one formula unit. The positions of ions in the unit cell are as follows: 0.5 Ca and 0.5 Er cations disorderly occupy 1(d) equivalent point position, each with an occupation factor of 0.5; 1. Tl cation occupies the equivalent point position 1 (a); 2. Cu cations occupy 2 (g) withz=0.365; 2 Sr cations occupy 2(h) withz=0.220; 7 O anions respectively occupy 1(c), 2(g), (z=0.165) and 4(i) (z=0.365) equivalent point positions. The zero-resistance superconducting transition temperatureT c (0) decreased slightly with increased Er content in the Tl−Sr−Ca−Er−Cu−O system. The crystal structure of TlSr2Ca0.5Er0.5Cu2O6.75 is very similar to that of TlBa2CaCu2O6.5 in the Tl−Ba−Ca−Cu−O system or RBa2Cu3O7 in the R−Ba−Cu−O system. In the superconducting phase with an oxygen-deficient perovskite-like structure, the similarity of cation-oxygen coordination polyhedra is important for cation substitution.
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  • 8
    ISSN: 1434-6036
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The crystal structure of one phase of superconductor Y−Ba−Cu−O Compound is analysed by RASA-5RP Four-circle single crystal diffractometer. It is found that the crystal is tetragonal with parametersa=3.8614 Å,b=3.8614 Å,C=11.6803 Å. In the crystal structure Ba situates at the Wyckoff (0, 0, 0.3094) position, Y at the special position (0, 0, 0), Cu ions occupy another special position (0.5, 0.5, 0.5) and the Wyckoff position (0.5, 0.5, 0.1391) with some substitution by Y and some Oxygen vacancies surrounding Cu and Y.
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