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  • 2020-2023  (2)
  • 1970-1974  (2)
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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Semigroup forum 9 (1974), S. 179-180 
    ISSN: 1432-2137
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Mathematik
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 9 (1974), S. 555-557 
    ISSN: 0030-493X
    Schlagwort(e): Chemistry ; Analytical Chemistry and Spectroscopy
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: The fragmentation reaction [C3(H,D)6]+· → [C3(H,D)5]+ + (H, D) has been examined in the metastable decomposition region for two pairs of labelled propenes: CH3CD=CH2,CD3CH=CD2 and CD3CH=CH2, CH3CD=CD2. The results indicate that complete hydrogen scrambling occurs in the propene molecular ion prior to fragmentation. The isotope effect kH/kD is in the range 2·1 to 3·3.
    Zusätzliches Material: 1 Tab.
    Materialart: Digitale Medien
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 3
    Publikationsdatum: 2022-02-07
    Beschreibung: Accurately quantifying tree and forest structure is important for monitoring and understanding terrestrial ecosystem functioning in a changing climate. The emergence of laser scanning, such as Terrestrial Laser Scanning (TLS) and Unoccupied Aerial Vehicle Laser Scanning (UAV-LS), has advanced accurate and detailed forest structural measurements. TLS generally provides very accurate measurements on the plot-scale (a few ha), whereas UAV-LS provides comparable measurements on the landscape-scale (〉10 ha). Despite the pivotal role dense tropical forests play in our climate, the strengths and limitations of TLS and UAV-LS to accurately measure structural metrics in these forests remain largely unexplored. Here, we propose to combine TLS and UAV-LS data from dense tropical forest plots to analyse how this fusion can further advance 3D structural mapping of structurally complex forests. We compared stand (vertical point distribution profiles) and tree level metrics from TLS, UAV-LS as well as their fused point cloud. The tree level metrics included the diameter at breast height (DBH), tree height (H), crown projection area (CPA), and crown volume (CV). Furthermore, we evaluated the impact of point density and number of returns for UAV-LS data acquisition. DBH measurements from TLS and UAV-LS were compared to census data. The TLS and UAV-LS based H, CPA and CV measurements were compared to those obtained from the fused point cloud. Our results for two tropical rainforest plots in Australia demonstrate that TLS can measure H, CPA and CV with an accuracy (RMSE) of 0.30 m (Haverage =27.32 m), 3.06 m2 (CPAaverage =66.74 m2), and 29.63 m3 (CVaverage =318.81 m3) respectively. UAV-LS measures H, CPA and CV with an accuracy (RMSE) of 〈0.40 m, 〈5.50 m2, and 〈30.33 m3 respectively. However, in dense tropical forests single flight UAV-LS is unable to sample the tree stems sufficiently for DBH measurement due to a limited penetration of the canopy. TLS can determine DBH with an accuracy (RMSE) of 5.04 cm, (DBHaverage =45.08 cm), whereas UAV-LS can not. We show that in dense tropical forests stand-alone TLS is able to measure macroscopic structural tree metrics on plot-scale. We also show that UAV-LS can be used to quickly measure H, CPA, and CV of canopy trees on the landscape-scale with comparable accuracy to TLS. Hence, the fusion of TLS and UAV-LS, which can be time consuming and expensive, is not required for these purposes. However, TLS and UAV-LS fusion opens up new avenues to improve stand-alone UAV-LS structural measurements at the landscape-scale by applying TLS as a local calibration tool.
    Materialart: info:eu-repo/semantics/article
    Standort Signatur Einschränkungen Verfügbarkeit
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  • 4
    Publikationsdatum: 2022-08-17
    Beschreibung: Calibration and validation of aboveground biomass (AGB) (AGB) products retrieved from satellite-borne sensors require accurate AGB estimates across hectare scales (1 to 100 ha). Recent studies recommend making use of non-destructive terrestrial laser scanning (TLS) based techniques for individual tree AGB estimation that provide unbiased AGB predictors. However, applying these techniques across large sites and landscapes remains logistically challenging. Unoccupied aerial vehicle laser scanning (UAV-LS) has the potential to address this through the collection of high density point clouds across many hectares, but estimation of individual tree AGB based on these data has been challenging so far, especially in dense tropical canopies. In this study, we investigated how TLS and UAV-LS can be used for this purpose by testing different modelling strategies with data availability and modelling framework requirements. The study included data from four forested sites across three biomes: temperate, wet tropical, and tropical savanna. At each site, coincident TLS and UAV-LS campaigns were conducted. Diameter at breast height (DBH) and tree height were estimated from TLS point clouds. Individual tree AGB was estimated for ≥170 trees per site based on TLS tree point clouds and quantitative structure modelling (QSM), and treated as the best available, non-destructive estimate of AGB in the absence of direct, destructive measurements. Individual trees were automatically segmented from the UAV-LS point clouds using a shortest-path algorithm on the full 3D point cloud. Predictions were evaluated in terms of individual tree root mean square error (RMSE) and population bias, the latter being the absolute difference between total tree sample population TLS QSM estimated AGB and predicted AGB. The application of global allometric scaling models (ASM) at local scale and across data modalities, i.e., field-inventory and light detection and ranging LiDAR metrics, resulted in individual tree prediction errors in the range of reported studies, but relatively high population bias. The use of adjustment factors should be considered to translate between data modalities. When calibrating local models, DBH was confirmed as a strong predictor of AGB, and useful when scaling AGB estimates with field inventories. The combination of UAV-LS derived tree metrics with non-parametric modelling generally produced high individual tree RMSE, but very low population bias of ≤5% across sites starting from 55 training samples. UAV-LS has the potential to scale AGB estimates across hectares with reduced fieldwork time. Overall, this study contributes to the exploitation of TLS and UAV-LS for hectare scale, non-destructive AGB estimation relevant for the calibration and validation of space-borne missions targeting AGB estimation.
    Materialart: info:eu-repo/semantics/article
    Format: application/pdf
    Standort Signatur Einschränkungen Verfügbarkeit
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