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  • 2020-2022  (10)
  • 1980-1984  (3)
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  • 1
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Loewenstein's rule4 states that during the isomorphous substitution of Si by Al, occupancy of adjacent tetrahedral sites by Al is avoided. An early X-ray crystallographic study1 of Si-Al ordering in the archetypical 2:1 mica muscovite has ted to a model in which the Al centres are arranged in ...
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 296 (1982), S. 549-551 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] The question of the nature of the water in fully hydrated halloysite (designated here as halloysite-10 A) is of great inter-est as it can serve as a model for water absorbed on silicate surfaces. In principle, it should be relatively simple to determine the chemical and physical properties of this ...
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Fresenius' Zeitschrift für analytische Chemie 307 (1981), S. 127-128 
    ISSN: 1618-2650
    Keywords: Best. von Wasser in Kieselgel ; Röntgenfluorescenz-Spektrometrie
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2021-06-21
    Description: We developed a new thermostated ring-shear-apparatus for investigation on hydrate- or ice-bearing sediments. A fluid inlet at the bottom of the static part of the cell and a fluid outlet at the top of the rotating half-cell allow exchanging and pressurizing the pore fluid in the sample cell to a certain value below the pressure providing the normal load that is applied hydraulically via a seal disk using a syringe pump. The volume change in the sample can be derived from the volume received or injected by the pump. The system allows the use of different methods for the formation and controlled decomposition of hydrate before, after, and during a shear test. The ring-shear-cell is designed for a maximum hydraulic pressure of 30 MPa. A commercial hollow shaft servo actuator applies the torque to the rotating half of the sample cell, and a rotary encoder provides information for determining the shear displacement. Stress path investigations in shear rate controlled experiments with large strain are possible with shear rates up to 12.6 mm/s and torques up to 1440 N m. The system design allows for complex experiments studying the behavior of a shear plane in hydrate- and/or ice-bearing sediments, including the decomposition and reformation of hydrate and/or ice under varying pressure and temperature conditions. It is a useful tool to provide experimental data to support research and engineering in solving problems related to permafrost and hydrate-bearing formations. The system performance is demonstrated by examples of tests on hydrate- and ice-bearing sand samples.
    Language: English
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 5
    Publication Date: 2021-09-14
    Description: Geophysical exploration and in particular active-source seismic imaging of geothermal fields is important to assess and optimize the exploitation of natural heat sources for energy production and direct use. The first multi-offset (moving-source) vertical seismic profiling (VSP) experiment over the high-temperature geothermal field in Krafla (Iceland) was carried out in spring 2014 with the aim to test whether VSP is a suitable method to map volcanic stratigraphy, fractures, dykes, steam zones and magmatic bodies at this site and for volcanic environments in general. In this study, we present a workflow for processing the sparse Krafla VSP dataset recorded with receivers in either of two boreholes. The analysis involved first-arrival traveltime inversion and seismic reflection processing. The seismic velocity model obtained by traveltime tomography reveals structural information between the two boreholes and can be linked to an existing geological model, showing that the seismic velocities are mainly controlled by lithology. The zero-offset seismic reflection data were processed into two corridor stacks. Walk-away VSP reflection data were migrated with a novel multicomponent Kirchhoff migration algorithm that includes P- and S-wave isolation to obtain separate PP, PS and SS migrated images. The reflections imaged in the corridor stacks can be linked to the main lithological units known from borehole logging information. Migrated images from the walk-away data reveal reflectors below and to the sides of the two boreholes. Considering à priori information, such as hypocenter locations from earthquake seismology studies, the reflectors can be related to changes in lithology, fault zones, dykes and possibly the top of the Krafla magma chamber. We found that VSP is potentially a useful method to image the key lithological boundaries and volcanic stratigraphy in the complex magmatic environment at Krafla, but à priori information proved to be essential to constrain the processing and interpretation of the sparse array dataset.
    Type: info:eu-repo/semantics/article
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  • 6
    Publication Date: 2021-09-14
    Description: The Krafla geothermal area in northern Iceland comprises one of the best studied examples of a high temperature geothermal field associated with an active volcanic rift zone. Of key importance to improved resource exploration and development in volcanic areas such as Krafla, is the interpretation and understanding of the subsurface geology. Within this study we present results from an integrated analysis of the downhole volcanic stratigraphy from the K-18 borehole within the Krafla caldera based on combined wireline, ditch cuttings, and zero-offset VSP (vertical seismic profile) analyses. This study presents the first published sonic log velocity data from a high temperature geothermal borehole in Iceland and clearly demonstrates the importance of borehole velocity data for improving volcanic facies interpretations. The shallow subsurface geology of the K-18 site from c. 0–380 m comprises an inter-layered sequence of sub-aerial basaltic lavas, hyaloclastites and tuffaceous lithologies of both felsic and basic composition, which are progressively replaced by basaltic sheet intrusions with increasing depth. An interval of variably basic to more evolved mixed tuffaceous facies is identified based on cuttings analysis, gamma and sonic velocities between c. 790–1120 m depth. Discrete high sonic Vp units cut the lower c. 100 m of this interval and are interpreted as either sheet intrusions or lava interiors. At c. 1800 m, a sharp increase in P-wave velocity from c. 4.5 to c. 5.5 km/s, represents the transition from a mixed lava and sheet intrusion dominated sequence, into a dense basic intrusion forming the local basement that persists to the bottom of the borehole at c. 2215 m. Reduced travel time analysis of processed zero-offset VSP results reveal good correspondence with the major stratigraphic boundaries in the borehole, supporting the potential for VSP studies to robustly characterize complex volcanic stratigraphy in high temperature geothermal fields. Finally, the application of percentage-based ditch cuttings analyses methods for volcanic facies analysis in geothermal boreholes is tested and assessed to have future potential.
    Type: info:eu-repo/semantics/article
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  • 7
    Publication Date: 2021-09-14
    Description: Among geothermal exploration methods, active surface seismic methods have played only a minor role to date. Especially in high-temperature volcanic systems, reflection seismic data often reveal poor delineation of volcanic features, due to the internal heterogeneity of volcanic sequences. To enhance the vertical resolution, one possibility is the application of downhole seismic methods like vertical seismic profiling (VSP). A test experiment was carried out in the Krafla high-temperature geothermal field, NE-Iceland, to assess the ability of VSP to image subsurface structures, such as fractures, zones of high permeability, magmatic bodies, and zones of supercritical fluids and steam. Logging in such hostile environments is technical challenging in many aspects, but mainly due to the high temperature impact on the downhole electronic components of the measuring equipment. This requires a thorough pre-examination and implementation of the measurement, especially to avoid delays and tool failures. This paper presents results of zero- and far-offset VSP data from the K-18 borehole from within the Krafla caldera, which reveal good correlation with the surrounding lithology. The raw three-component seismic data display a good signal-to-noise ratio and dominant signal frequencies between 20 and 40 Hz, down to c. 2200 m depth, for air gun and explosive sources, respectively. A zero-offset source comparison was also conducted to assess the use of different impulsive sources for future VSP surveys in similar settings. By applying a standard VSP processing, we identified stratigraphic boundaries between lavas, hyaloclastites, and intrusions, which are in good agreement with existing well data. For the zero-offset VSP, both P- and S-wave velocity models were calculated and a depth-converted corridor stack was determined. In addition, multicomponent Kirchhoff depth migration and Fresnel volume migration were tested around the borehole. The 3D results are promising, but the specific shape and lateral extent of the reflectors could not be determined due to the restriction to only two sources and the insufficient spatial coverage (aperture). Our study demonstrates that vertical seismic profiles can clearly detect variations in the subsurface volcanic stratigraphy in high-temperature geothermal fields. A more detailed reservoir characterization can be achieved by further data integration, enhanced survey design including more source positions, and improved processing and imaging techniques, such as full-waveform inversion.
    Language: English
    Type: info:eu-repo/semantics/article
    Format: application/pdf
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  • 8
    Publication Date: 2020-11-18
    Description: Salt rocks serve as host rock for technical caverns due to their impermeability but their can also be influenced by fluid migration due to geological fracture zones. Seismic methods can be used to monitor cavernous structures in the transition zone between cavity and undisturbed salt rocks. Around an artificially created cavity (field-test cavern) in a salt pillar with a volume of approximately 100 litre, travel time tomography was utilized to image structures related to caverns and fluid-storage. Seismic surveys were performed at different stages of an experimental simulation of gas-water-rock interaction in the field-test cavern aiming for a better understanding of the multiphase system in the cavern-near area. The baseline survey (1) was carried out using 8 three-component piezo-electrical sensor rods and a seismic vibrator source at the surface of the salt pillar, first without an installed field-test cavern. After drilling and installing the field-test cavern, seismic cross-hole measurements were performed after producing partial vacuum in the test cavern (2) and infill of gas (3) and water (4). To finalize the field experiments the last seismic survey (5) was again conducted at the surface of the salt pillar as a repeat measurement to the baseline survey. The seismic monitoring of the salt pillar was carried out in a frequency range of 100 Hz to 14000 Hz allowing a spatial resolution in the cm-range. This was followed by pre-processing of the seismic data sets to apply the picked travel times in a tomography program. On the basis of the tomography results and reflection seismic data we want to assess the potential enlargement of the field-test cavern due to water-infill and to image the differences between unaffected salt rocks, cavernous structures and developing transition zones.
    Language: English
    Type: info:eu-repo/semantics/conferenceObject
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  • 9
    Publication Date: 2020-12-14
    Description: One important scientific objective of the national research project SUGAR – Submarine Gas Hydrate Reservoirs was the development, improvement, and test of innovative concepts for the production of methane from natural gas hydrate reservoirs. Therefore, different production methods, such as the thermal stimulation using in situ combustion, the chemical stimulation via injection of CO2 as a gaseous, liquid or supercritical phase and depressurization were tested alone or in combination at different scales. In the laboratory experiments these ranged from pore and hydrate grain scale to 425-L reactor volume, whereas numerical models were applied to describe the related processes from molecular to reservoir scale. In addition, the numerical simulations also evaluated the feasibility and efficiency of the application of these methods in selected areas, such as the Danube Paleodelta in the Black Sea, addressing the two dominant methane hydrate reservoir settings, buried channel-levee and turbidite systems. It turned out, that the injection of CO2 or a CO2–N2 gas mixture is not applicable for the Danube Paleodelta in the Black Sea, because the local pressure and temperature conditions are too close to the equilibrium conditions of both, the CO2 hydrate and a CO2–N2 mixed hydrate stability fields. Experiments using thermal stimulation and depressurization showed promising results but also some issues, such as sufficient heat transfer. In summary it can be said that the applicability and efficiency of each method has to be proven for each specific hydrate reservoir conditions. Based on the results obtained by numerical simulations the most promising and safe method for the production of CH4 from hydrate bearing sediments in the Danube Paleodelta would be the depressurization technique. This study summarizes the main experimental and modeling results.
    Type: info:eu-repo/semantics/article
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  • 10
    Publication Date: 2020-12-14
    Type: info:eu-repo/semantics/article
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