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  • American Association for the Advancement of Science (AAAS)  (26)
  • 2020-2022
  • 2010-2014  (26)
  • 1
    Publication Date: 2011-03-10
    Description: Micrometer-scale analyses of a calcium-, aluminum-rich inclusion (CAI) and the characteristic mineral bands mantling the CAI reveal that the outer parts of this primitive object have a large range of oxygen isotope compositions. The variations are systematic; the relative abundance of (16)O first decreases toward the CAI margin, approaching a planetary-like isotopic composition, then shifts to extremely (16)O-rich compositions through the surrounding rim. The variability implies that CAIs probably formed from several oxygen reservoirs. The observations support early and short-lived fluctuations of the environment in which CAIs formed, either because of transport of the CAIs themselves to distinct regions of the solar nebula or because of varying gas composition near the proto-Sun.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Simon, Justin I -- Hutcheon, Ian D -- Simon, Steven B -- Matzel, Jennifer E P -- Ramon, Erick C -- Weber, Peter K -- Grossman, Lawrence -- DePaolo, Donald J -- New York, N.Y. -- Science. 2011 Mar 4;331(6021):1175-8. doi: 10.1126/science.1197970.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Astromaterials Research Office KR111, NASA Johnson Space Center, Houston, TX 77058, USA. justin.i.simon@nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21385711" target="_blank"〉PubMed〈/a〉
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 2
    Publication Date: 2010-12-04
    Description: Life is mostly composed of the elements carbon, hydrogen, nitrogen, oxygen, sulfur, and phosphorus. Although these six elements make up nucleic acids, proteins, and lipids and thus the bulk of living matter, it is theoretically possible that some other elements in the periodic table could serve the same functions. Here, we describe a bacterium, strain GFAJ-1 of the Halomonadaceae, isolated from Mono Lake, California, that is able to substitute arsenic for phosphorus to sustain its growth. Our data show evidence for arsenate in macromolecules that normally contain phosphate, most notably nucleic acids and proteins. Exchange of one of the major bio-elements may have profound evolutionary and geochemical importance.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Wolfe-Simon, Felisa -- Switzer Blum, Jodi -- Kulp, Thomas R -- Gordon, Gwyneth W -- Hoeft, Shelley E -- Pett-Ridge, Jennifer -- Stolz, John F -- Webb, Samuel M -- Weber, Peter K -- Davies, Paul C W -- Anbar, Ariel D -- Oremland, Ronald S -- New York, N.Y. -- Science. 2011 Jun 3;332(6034):1163-6. doi: 10.1126/science.1197258. Epub 2010 Dec 2.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉NASA Astrobiology Institute, USA. felisawolfesimon@gmail.com〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21127214" target="_blank"〉PubMed〈/a〉
    Keywords: Arsenates/analysis/*metabolism ; Arsenic/analysis/chemistry/*metabolism ; Bacterial Proteins/analysis/metabolism ; California ; Culture Media ; DNA, Bacterial/*chemistry/metabolism ; Geologic Sediments/microbiology ; Halomonadaceae/cytology/*growth & development/isolation & ; purification/*metabolism ; Molecular Sequence Data ; Phosphates/analysis/*metabolism ; Phosphorus/analysis/chemistry/*metabolism ; Spectrometry, Mass, Secondary Ion ; Vacuoles/ultrastructure ; Water Microbiology
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 3
    Publication Date: 2011-01-08
    Description: Despite recent insight regarding the history and current state of the Moon from satellite sensing and analyses of limited Apollo-era seismic data, deficiencies remain in our understanding of the deep lunar interior. We reanalyzed Apollo lunar seismograms using array-processing methods to search for the presence of reflected and converted seismic energy from the core. Our results suggest the presence of a solid inner and fluid outer core, overlain by a partially molten boundary layer. The relative sizes of the inner and outer core suggest that the core is ~60% liquid by volume. Based on phase diagrams of iron alloys and the presence of partial melt, the core probably contains less than 6 weight % of lighter alloying components, which is consistent with a volatile-depleted interior.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Weber, Renee C -- Lin, Pei-Ying -- Garnero, Edward J -- Williams, Quentin -- Lognonne, Philippe -- New York, N.Y. -- Science. 2011 Jan 21;331(6015):309-12. doi: 10.1126/science.1199375. Epub 2011 Jan 6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉NASA Marshall Space Flight Center, 320 Sparkman Drive, Huntsville, AL 35805, USA. renee.c.weber@nasa.gov〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21212323" target="_blank"〉PubMed〈/a〉
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 4
    Publication Date: 2011-11-19
    Description: The identity of the interstitial light atom in the center of the FeMo cofactor of nitrogenase has been enigmatic since its discovery. Atomic-resolution x-ray diffraction data and an electron spin echo envelope modulation (ESEEM) analysis now provide direct evidence that the ligand is a carbon species.〈br /〉〈br /〉〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3268367/" target="_blank"〉〈img src="https://static.pubmed.gov/portal/portal3rc.fcgi/4089621/img/3977009" border="0"〉〈/a〉   〈a href="https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3268367/" target="_blank"〉This paper as free author manuscript - peer-reviewed and accepted for publication〈/a〉〈br /〉〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Spatzal, Thomas -- Aksoyoglu, Muge -- Zhang, Limei -- Andrade, Susana L A -- Schleicher, Erik -- Weber, Stefan -- Rees, Douglas C -- Einsle, Oliver -- GM45162/GM/NIGMS NIH HHS/ -- R37 GM045162/GM/NIGMS NIH HHS/ -- R37 GM045162-22/GM/NIGMS NIH HHS/ -- Howard Hughes Medical Institute/ -- New York, N.Y. -- Science. 2011 Nov 18;334(6058):940. doi: 10.1126/science.1214025.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institut fur Organische Chemie und Biochemie, Albert-Ludwigs-Universitat Freiburg, Freiburg, Germany.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/22096190" target="_blank"〉PubMed〈/a〉
    Keywords: Azotobacter vinelandii/*chemistry ; Carbon/*chemistry ; Crystallography, X-Ray ; Electron Spin Resonance Spectroscopy ; Models, Molecular ; Molecular Structure ; Molybdoferredoxin/*chemistry ; Nitrogen/chemistry
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 5
    Publication Date: 2013-08-10
    Description: Numerous volatile organic compounds (VOCs) exist in Earth's atmosphere, most of which originate from biogenic emissions. Despite VOCs' critical role in tropospheric chemistry, studies for evaluating their atmosphere-ecosystem exchange (emission and deposition) have been limited to a few dominant compounds owing to a lack of appropriate measurement techniques. Using a high-mass resolution proton transfer reaction-time of flight-mass spectrometer and an absolute value eddy-covariance method, we directly measured 186 organic ions with net deposition, and 494 that have bidirectional flux. This observation of active atmosphere-ecosystem exchange of the vast majority of detected VOCs poses a challenge to current emission, air quality, and global climate models, which do not account for this extremely large range of compounds. This observation also provides new insight for understanding the atmospheric VOC budget.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Park, J-H -- Goldstein, A H -- Timkovsky, J -- Fares, S -- Weber, R -- Karlik, J -- Holzinger, R -- New York, N.Y. -- Science. 2013 Aug 9;341(6146):643-7. doi: 10.1126/science.1235053.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Environmental Science, Policy, and Management, University of California at Berkeley, Berkeley, CA 94720, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/23929979" target="_blank"〉PubMed〈/a〉
    Keywords: Atmosphere/*chemistry ; *Ecosystem ; Mass Spectrometry ; Ozone/analysis/chemistry ; Plants/chemistry ; Volatile Organic Compounds/analysis/*chemistry
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 6
    Publication Date: 2014-08-12
    Description: Climate warming is expected to reduce oxygen (O2) supply to the ocean and expand its oxygen minimum zones (OMZs). We reconstructed variations in the extent of North Pacific anoxia since 1850 using a geochemical proxy for denitrification (delta(15)N) from multiple sediment cores. Increasing delta(15)N since ~1990 records an expansion of anoxia, consistent with observed O2 trends. However, this was preceded by a longer declining delta(15)N trend that implies that the anoxic zone was shrinking for most of the 20th century. Both periods can be explained by changes in winds over the tropical Pacific that drive upwelling, biological productivity, and O2 demand within the OMZ. If equatorial Pacific winds resume their predicted weakening trend, the ocean's largest anoxic zone will contract despite a global O2 decline.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Deutsch, Curtis -- Berelson, William -- Thunell, Robert -- Weber, Thomas -- Tems, Caitlin -- McManus, James -- Crusius, John -- Ito, Taka -- Baumgartner, Timothy -- Ferreira, Vicente -- Mey, Jacob -- van Geen, Alexander -- New York, N.Y. -- Science. 2014 Aug 8;345(6197):665-8. doi: 10.1126/science.1252332.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉School of Oceanography, University of Washington, Seattle, WA, USA. cdeutsch@uw.edu. ; Department of Earth Sciences, University of Southern California, Los Angeles, CA, USA. ; Department of Earth and Ocean Sciences, University of South Carolina, Columbia, SC, USA. ; School of Oceanography, University of Washington, Seattle, WA, USA. ; College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, OR, USA. ; U.S. Geological Survey, University of Washington School of Oceanography, Seattle, WA, USA. ; School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA. ; Departamento de Oceanografia Biologica, Centro de Investigacion Cientifica y de Educacion Superior de Ensenada, Baja California, Mexico. ; Lamont-Doherty Earth Observatory of Columbia University, Palisades, NY, USA. Department of Physical Sciences, Kingsborough Community College, City University of New York, New York, NY, USA. ; Lamont-Doherty Earth Observatory of Columbia University, Palisades, NY, USA.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/25104384" target="_blank"〉PubMed〈/a〉
    Keywords: Anaerobiosis ; Denitrification ; *Global Warming ; Oxygen/*analysis ; Pacific Ocean ; Seawater/*chemistry ; *Tropical Climate ; *Wind
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  • 7
    Publication Date: 2011-03-12
    Description: T-shaped molecules with a rod-like aromatic core and a flexible side chain form liquid crystal honeycombs with aromatic cell walls and a cell interior filled with the side chains. Here, we show how the addition of a second chain, incompatible with the first (X-shaped molecules), can form honeycombs with highly complex tiling patterns, with cells of up to five different compositions ("colors") and polygonal shapes. The complexity is caused by the inability of the side chains to separate cleanly because of geometric frustration. Furthermore, a thermoreversible transition was observed between a multicolor (phase-separated) and a single-color (mixed) honeycomb phase. This is analogous to the Curie transition in simple and frustrated ferro- and antiferromagnets; here spin flips are replaced by 180 degrees reorientations of the molecules.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Zeng, Xiangbing -- Kieffer, Robert -- Glettner, Benjamin -- Nurnberger, Constance -- Liu, Feng -- Pelz, Karsten -- Prehm, Marko -- Baumeister, Ute -- Hahn, Harald -- Lang, Heinrich -- Gehring, Gillian A -- Weber, Christa H M -- Hobbs, Jamie K -- Tschierske, Carsten -- Ungar, Goran -- New York, N.Y. -- Science. 2011 Mar 11;331(6022):1302-6. doi: 10.1126/science.1193052.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Materials Science and Engineering, University of Sheffield, Sheffield, UK.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21393540" target="_blank"〉PubMed〈/a〉
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  • 8
    Publication Date: 2011-08-27
    Description: Previous high-resolution x-ray powder diffraction and transmission electron microscopy studies of the zeolite SSZ-57 could not fully elucidate the structural basis for its puzzling adsorption behavior, which appears to be intermediate between that of a medium- (10-ring) and a large-pore (12-ring) zeolite. Now by applying advanced crystallographic techniques (structure solution in four-dimensional space and interpretation of three-dimensional diffuse scattering by Monte Carlo simulation) and crystal chemistry considerations to high-quality single-crystal x-ray diffraction data collected on a microcrystal (about 2 micrometers by 2 micrometers by 8 micrometers), we have been able to derive a comprehensive description of its silicate framework structure. The framework is related to that of ZSM-11 but is commensurately modulated along the c axis (P4m2, a = b = 20.091 A, c = 110.056 A) to yield a structure with a 12-ring:10-ring ratio of 1:15. Disorder of the 12-rings results in a three-dimensional 10-ring channel system with large isolated pockets. The structure helps to clarify the material's catalytic activity.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Baerlocher, Christian -- Weber, Thomas -- McCusker, Lynne B -- Palatinus, Lukas -- Zones, Stacey I -- New York, N.Y. -- Science. 2011 Aug 26;333(6046):1134-7. doi: 10.1126/science.1207466.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Laboratory of Crystallography, Eidgenossische Technische Hochschule (ETH) Zurich, CH-8093 Zurich, Switzerland.〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21868674" target="_blank"〉PubMed〈/a〉
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  • 9
    Publication Date: 2011-12-07
    Description: The timing of the last maximum extent of the Antarctic ice sheets relative to those in the Northern Hemisphere remains poorly understood. We develop a chronology for the Weddell Sea sector of the East Antarctic Ice Sheet that, combined with ages from other Antarctic ice-sheet sectors, indicates that the advance to and retreat from their maximum extent was within dating uncertainties synchronous with most sectors of Northern Hemisphere ice sheets. Surface climate forcing of Antarctic mass balance would probably cause an opposite response, whereby a warming climate would increase accumulation but not surface melting. Our new data support teleconnections involving sea-level forcing from Northern Hemisphere ice sheets and changes in North Atlantic deep-water formation and attendant heat flux to Antarctic grounding lines to synchronize the hemispheric ice sheets.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Weber, Michael E -- Clark, Peter U -- Ricken, Werner -- Mitrovica, Jerry X -- Hostetler, Steven W -- Kuhn, Gerhard -- New York, N.Y. -- Science. 2011 Dec 2;334(6060):1265-9. doi: 10.1126/science.1209299.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Institute of Geology and Mineralogy, University of Cologne, 50674 Cologne, Germany. michael.weber@uni-koeln.de〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/22144623" target="_blank"〉PubMed〈/a〉
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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  • 10
    Publication Date: 2011-01-08
    Description: Methane was the most abundant hydrocarbon released during the 2010 Deepwater Horizon oil spill in the Gulf of Mexico. Beyond relevancy to this anthropogenic event, this methane release simulates a rapid and relatively short-term natural release from hydrates into deep water. Based on methane and oxygen distributions measured at 207 stations throughout the affected region, we find that within ~120 days from the onset of release ~3.0 x 10(10) to 3.9 x 10(10) moles of oxygen were respired, primarily by methanotrophs, and left behind a residual microbial community containing methanotrophic bacteria. We suggest that a vigorous deepwater bacterial bloom respired nearly all the released methane within this time, and that by analogy, large-scale releases of methane from hydrate in the deep ocean are likely to be met by a similarly rapid methanotrophic response.〈br /〉〈span class="detail_caption"〉Notes: 〈/span〉Kessler, John D -- Valentine, David L -- Redmond, Molly C -- Du, Mengran -- Chan, Eric W -- Mendes, Stephanie D -- Quiroz, Erik W -- Villanueva, Christie J -- Shusta, Stephani S -- Werra, Lindsay M -- Yvon-Lewis, Shari A -- Weber, Thomas C -- New York, N.Y. -- Science. 2011 Jan 21;331(6015):312-5. doi: 10.1126/science.1199697. Epub 2011 Jan 6.〈br /〉〈span class="detail_caption"〉Author address: 〈/span〉Department of Oceanography, Texas A&M University, College Station, TX 77843-3146, USA. jkessler@ocean.tamu.edu〈br /〉〈span class="detail_caption"〉Record origin:〈/span〉 〈a href="http://www.ncbi.nlm.nih.gov/pubmed/21212320" target="_blank"〉PubMed〈/a〉
    Keywords: Atlantic Ocean ; Bacteria/classification/growth & development/*metabolism ; Biodegradation, Environmental ; *Environmental Pollution ; Hydrocarbons/analysis ; Methane/analysis/*metabolism ; Molecular Sequence Data ; Oxidation-Reduction ; Oxygen/*analysis ; Oxygen Consumption ; *Petroleum ; Phylogeny ; Seawater/chemistry/*microbiology
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    Topics: Biology , Chemistry and Pharmacology , Computer Science , Medicine , Natural Sciences in General , Physics
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