Description: SUMMARY We propose a class of spherical wavelet bases for the analysis of geophysical models and for the tomographic inversion of global seismic data. Its multiresolution character allows for modelling with an effective spatial resolution that varies with position within the Earth. Our procedure is numerically efficient and can be implemented with parallel computing. We discuss two possible types of discrete wavelet transforms in the angular dimension of the cubed sphere. We describe benefits and drawbacks of these constructions and apply them to analyse the information in two published seismic wave speed models of the mantle, using the statistics of wavelet coefficients across scales. The localization and sparsity properties of wavelet bases allow finding a sparse solution to inverse problems by iterative minimization of a combination of the ℓ 2 norm of the data residuals and the ℓ 1 norm of the model wavelet coefficients. By validation with realistic synthetic experiments we illustrate the likely gains from our new approach in future inversions of finite-frequency seismic data.

Description: ABSTRACT Riffle-pool sequences are a common feature of gravel-bed rivers. However, mechanisms of their generation and maintenance are still not fully understood. In this study a monitoring approach similar to the one of Andrews (1979 and 1982) is employed. It focuses on analysing cross-sectional and longitudinal channel geometry of a large floodplain river (Vereinigte Mulde, Sachsen-Anhalt, Germany) with a high temporal and spatial resolution, in order to conclude from stage-dependant morphometric changes to riffle and pool maintaining processes. In accordance with Richards (1976a), Andrews (1979 and 1982) among others, pool cross sections of the Mulde River are narrow and riffle cross sections are wide suggesting that they should rather be addressed as two general types of channel cross-sections than solely as bedforms. At high flows, riffles and pools in the study reaches changed in length and height but not in position. Pools were scoured and riffles aggraded, a development which was reversed during receding flows below the threshold of 0.4·Q bf (40% bankfull discharge). An index for the longitudinal amplitude of riffle-pool sequences, the bed undulation intensity or bedform amplitude, is introduced and proved to be highly significant as a form parameter, its first derivative as a process parameter. The process of pool scour and riffle fill is addressed as bedform maintenance or bedform accentuation. It is indicated by increasing longitudinal bed amplitudes. According to the observed dynamics of bed amplitudes, maintenance of riffle-pool sequences lags behind discharge peaks. Maximum bed amplitudes may be reached with a delay of several days after peak discharges. Increasing bed undulation intensity is interpreted to indicate bed mobility. Post-flood decrease of the bed undulation intensity indicates a retrograde phase when transport from pools to riffles has ceased and bed mobility is restricted to riffle tails and heads of pools. This type of transport behaviour is referred to as disconnected mobility. The comparison of two river reaches, one with undisturbed sediment supply, the other with sediment deficit, suggests that high bed undulation intensity values at low flows indicate sediment deficit and potentially channel degrading conditions. It is more generally hypothesised that channel bed undulations constitute a major component of form roughness and that increased bed amplitudes are an important feature of channel bed adjustment to sediment deficit be it temporally during late floods or permanently due to a supply limitation of bedload. Copyright © 2011 John Wiley & Sons, Ltd.

Description: The asymmetric unit of the title compound, 2C18H12O4·C2H6OS·2H2O, consists of four crystallographically independent molecules of 5-(naphthalen-1-yl)isophthalic acid, two dimethyl sulfoxide and four water molecules. The dihedral angles formed by the the planes of the aromatic fragments of the organic molecules range from 57.4 (1) to 59.1 (1)°. In the crystal, multiple O—H...O hydrogen bonds link the water molecules with the carbonyl and sulfoxide groups, giving rise to double ribbons along the b-axis direction.

Description: In the title compound, C15H11N, the mean planes of the aromatic moieties are inclined to one another by 72.9 (1)°. The crystal is stabilized by π–π stacking interactions between the pyridine rings of inversion-related molecules, with a centroid–centroid distance of 3.772 (2) Å. In addition, C—H...π contacts involving an α-C—H group of the pyridine ring and the nonsubstituted ring of the naphthalene unit are observed, giving rise to a herringbone-type supramolecular architecture of the naphthalene moiety being contained in the molecule.

Description: Crystal Growth & Design DOI: 10.1021/cg200352u

Description: Measurements of trace metal ratios in foraminiferal calcite are routinely used to reconstruct paleoceanographic conditions. Analyses using solution-based inductively coupled plasma mass spectrometry (ICP-MS) require dissolution of the entire foraminifer shell. The potential exists for contamination from adherent clays, mineralized coatings, and other diagenetic components that confound the biogenic trace metal signal. We present results from a cleaning experiment on fossil specimens of the planktic foraminifer Orbulina universa that were cracked into several shell fragments and subjected to different cleaning protocols. We use LA-ICP-MS depth profiling to evaluate the effects of reductive, oxidative, and chelating (DTPA) cleaning protocols on shell Mg/Ca and Ba/Ca ratios. Using the natural pattern of intrashell Mg/Ca heterogeneity exhibited by O. universa , we demonstrate that reductive and oxidative cleaning can dissolve shell calcite from available surfaces, although intrashell Mg/Ca minima and maxima are unaffected. High-resolution depth profiles can be used to identify areas of heterogeneous intrashell Ba/Ca, which can be excluded from computations of whole-shell Ba/Ca. The size and density of shell pores plays a major role in the degree of contamination from sedimentary material. We demonstrate an approach for computing whole-shell Me/Ca ratios from LA-ICP-MS depth profiles that accounts for potential contamination and diagenetic overprinting.

Description: The temporal and magmatic evolution of central Snake River Plain (SRP; Idaho, USA) olivine tholeiites erupted within the past 4 m.y. is evaluated here. This investigation correlates and merges both geochemical and paleomagnetic measurements to constrain the volcanic history recovered from the 340 m Regional Aquifer Systems Analysis (RASA) test well located near Wendell, Idaho. Only a handful of studies have accomplished this task of shedding light on the chemical stratigraphy of the SRP and the petrogenesis of basalts with depth, and therefore through time. Paleomagnetic relationships suggest that time breaks between individual lava flows represent a few years to decades, time breaks between flow groups represent at least a couple of hundred years or possibly much longer, while significant hiatuses in volcanism, revealed by thick sediment packages or polarity reversals (both are evidenced in this well), are inferred to last thousands to tens of thousands of years. Major element geochemistry from 52 basaltic lava flows demonstrates near primitive compositions (i.e., ~10 wt% MgO) and tholeiitic iron enrichment trends, similar to lavas from the eastern SRP. Trace element concentrations are similar to those of ocean island basalts, with enriched Ba and Pb, and light rare earth element (REE)/heavy REE ratios similar to those of many Neogene volcanics of the western Cordillera. When combined, we identify a total of 11 flow groups, which we also classify as fractionation or recharge on the basis of decreasing or increasing MgO weight percent with depth. Taking into consideration these trends, we review the potential recharge, fractionation, and assimilation processes that characterize much of SRP olivine tholeiite, and conclude that assimilation, in combination with fractional crystallization, is the dominant petrogenesis for the basalts in the central SRP. Although fractionation of Wendell parent magmas was accompanied by assimilation of crustal material, this could not have been assimilation of ancient cratonic crust. The geochemical cycles observed in this well are inferred to represent fractionation and recharge of basaltic magma from a series of sill-like layered mafic intrusions located in the middle crust, similar to what has been proposed for the processes that control the eruptive history of basalts in the eastern SRP.

Description: Crystal Growth & Design DOI: 10.1021/cg4010714