Description: Hydrocarbon seepage is a widespread process at the continental margins of the Gulf of Mexico. We used a multidisciplinary approach, including multibeam mapping and visual seafloor observations with different underwater vehicles to study the extent and character of complex hydrocarbon seepage in the Bay of Campeche, southern Gulf of Mexico. Our observations showed that seafloor asphalt deposits previously only known from the Chapopote Knoll also occur at numerous other knolls and ridges in water depths from 1230 to 3150 m. In particular the deeper sites (Chapopopte and Mictlan knolls) were characterized by asphalt deposits accompanied by extrusion of liquid oil in form of whips or sheets, and in some places (Tsanyao Yang, Mictlan, and Chapopote knolls) by gas emission and the presence of gas hydrates in addition. Molecular and stable carbon isotopic compositions of gaseous hydrocarbons suggest their primarily thermogenic origin. Relatively fresh asphalt structures were settled by chemosynthetic communities including bacterial mats and vestimentiferan tube worms, whereas older flows appeared largely inert and devoid of corals and anemones at the deep sites. The gas hydrates at Tsanyao Yang and Mictlan Knolls were covered by a 5-to-10 cm-thick reaction zone composed of authigenic carbonates, detritus, and microbial mats, and were densely colonized by 1–2 m-long tube worms, bivalves, snails, and shrimps. This study increased knowledge on the occurrences and dimensions of asphalt fields and associated gas hydrates at the Campeche Knolls. The extent of all discovered seepage structure areas indicates that emission of complex hydrocarbons is a widespread, thus important feature of the southern Gulf of Mexico.

Description: This study investigates the distribution and evolution of seafloor seepage in the vicinity of the salt front, i.e., the seaward boundary of salt-induced deformation in the Lower Congo Basin (LCB). Seafloor topography, backscatter data and TV-sled observations indicate active fluid seepage from the seafloor directly at the salt front, whereas suspected seepage sites appear to be inactive at a distance of 〉10 km landward of the deformation front. High resolution multichannel seismic data give detailed information on the structural development of the area and its influence on the activity of individual seeps during the geologic evolution of the salt front region. The unimpeded migration of gas from fan deposits along sedimentary strata towards the base of the gas hydrate stability zone within topographic ridges associated with relatively young salt-tectonic deformation facilitates seafloor seepage at the salt front. Bright and flat spots within sedimentary successions suggest geological trapping of gas on the flanks of mature salt structures in the eastern part of the study area. Onlap structures associated with fan deposits which were formed after the onset of salt-tectonic deformation represent potential traps for gas, which may hinder gas migration towards seafloor seeps. Faults related to the thrusting of salt bodies seawards also disrupt along-strata gas migration pathways. Additionally, the development of an effective gas hydrate seal after the cessation of active salt-induced uplift and the near-surface location of salt bodies may hamper or prohibit seafloor seepage in areas of advanced salt-tectonic deformation. This process of seaward shifting active seafloor seepage may propagate as seaward migrating deformation affects Congo Fan deposits on the abyssal plain. These observations of the influence of the geologic evolution of the salt front area on seafloor seepage allows for a characterization of the large variety of hydrocarbon seepage activity throughout this compressional tectonic setting.

Description: Authigenic carbonate deposits have been sampled with the remotely operated vehicle 'MARUM-QUEST 4000 m' from five methane seeps between 731 and 1823 m water depth along the convergent Makran continental margin, offshore Pakistan (northern Arabian Sea). Two seeps on the upper slope are located within the oxygen minimum zone (OMZ; ca. 100 to 1100 m water depth), the other sites are situated in oxygenated water below the OMZ (below 1100 m water depth). The carbonate deposits vary with regard to their spatial extent, sedimentary fabrics, and associated seep fauna: Within the OMZ, carbonates are spatially restricted and associated with microbial mats, whereas in the oxygenated zone below the OMZ extensive carbonate crusts are exposed on the seafloor with abundant metazoans (bathymodiolin mussels, tube worms, galatheid crabs). Aragonite and Mg-calcite are the dominant carbonate minerals, forming common early diagenetic microcrystalline cement and clotted to radial-fibrous cement. The delta18O carbonate values range from 1.3 to 4.2 per mil V-PDB, indicating carbonate precipitation at ambient bottom-water temperature in shallow sediment depth. Extremely low delta13Ccarbonate values (as low - 54.6per mil V-PDB) point to anaerobic oxidation of methane (AOM) as trigger for carbonate precipitation, with biogenic methane as dominant carbon source. Prevalence of biogenic methane in the seepage gas is corroborated by delta13C methane values ranging from - 70.3 to - 66.7per mil V-PDB, and also by back-calculations considering delta 13C methane values of carbonate and incorporated lipid biomarkers.