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  • 2010-2014  (9)
  • 2014  (9)
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  • 2010-2014  (9)
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  • 1
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    AMS (American Meteorological Society)
    In:  Journal of Atmospheric and Oceanic Technology, 31 (1). pp. 181-196.
    Publication Date: 2020-08-04
    Description: We present a detailed quality assessment of a novel underwater sensor for the measurement of CO2 partial pressure (pCO2) based on surface water field deployments carried out between 2008 and 2011. The commercially available sensor, which is based on membrane equilibration and NDIR spectrometry is small and can be integrated into mobile platforms. It is calibrated in water against a proven flow-through pCO2 instrument within a custom-built calibration setup. The aspect of highest concern with respect to achievable data quality of the sensor is the compensation for signal drift inevitably connected to absorption measurements. We use three means to correct for drift effects: (i) a filter correlation or dual-beam setup, (ii) regular zero gas measurements realized automatically within the sensor and (iii) a zero-based transformation of two sensor calibrations flanking the time of sensor deployment. Three sensors were tested against an underway pCO2 system during two major research cruises providing an in situ temperature range from 7.4 to 30.1°C and pCO2 values between 289 and 445 μatm. The average difference between sensor and reference pCO2 was found to be -0.6 ± 3 μatm with a RMSE of 3.7 μatm.
    Type: Article , PeerReviewed
    Format: text
    Format: text
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  • 2
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    In:  [Talk] In: FB2 Seminar, GEOMAR, 26.05.2014, Kiel, Germany .
    Publication Date: 2014-05-28
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 3
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    In:  [Talk] In: Ocean Sciences Meeting 2014, 23.-28.02.2014, Honululu, Hawaii, USA .
    Publication Date: 2014-05-28
    Description: The measurement of dissolved carbon dioxide (CO2) in seawater is important within various scientific disciplines not only limited to chemical oceanography and marine carbon cycle research. Investigations in the field of ocean acidification also benefit from improved measuring technologies for CO2 partial pressure (pCO2). On the one hand, pCO2 is a meaningful stand-alone measuring parameter since it e.g. responds sensitively to biogeochemical processes such as photosynthesis and respiration. On the other hand it is a valuable variable within multi parameter measurements for the determination of the marine carbonate system. Throughout the last years we have developed, improved and assessed the quality of an autonomous underwater pCO2 sensor. Here we present the latest status of that work by discussing field data from various referenced deployments. Aspects covered will be i.a. accuracy, response time and power consumption. The sensor proved a good platform integratabilty and is recently used more often as part of carbonate system sensor suites. Future developments will be outlined.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 4
    Publication Date: 2019-09-23
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 5
    Publication Date: 2019-09-23
    Description: Mussel and seagrass beds are characteristic of the shallow nearshores of the western Baltic Sea, forming a mosaic of habitat. The diverse physiological activities of seagrasses and mussels are affected by seawater carbonate chemistry and in return locally modify it. Seagrass photosynthesis decreases seawater CO2 concentration at daytime and increases it at night through respiration. This dynamic creates very favorable chemical condition to calcification at daytime but turn the habitat corrosive to calcium carbonates at night. In contrast, mussel respiration releases CO2, with the potential of locally changing the carbonate chemistry, turning the environment more favorable for photosynthesis by adjacent seagrass. Mussel calcification has the potential for reducing alkalinity (uptake of CO32-) thereby increasing CO2 concentration in seawater and reciprocally once dead, due to the dissolution of the shells. To capture these interactions between habitats, we 1) used a combination of state-of-the-art technologies to create an in-situ high precision carbonate sensor suite and 2) deployed it in August and September 2013 at the interface between a seagrass and a mussel patch submitted to series of down- and upwelling events.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 6
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    In:  [Talk] In: Oceanology International, 11.-13.03.2014, London, UK .
    Publication Date: 2019-09-23
    Type: Conference or Workshop Item , NonPeerReviewed
    Format: text
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  • 7
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    In:  [Talk] In: Ocean Sciences Meeting 2014, 23.-28.02.2014, Honululu, Hawaii, USA .
    Publication Date: 2019-09-23
    Description: Total alkalinity (TA) is one of the four measurable parameters (TA, DIC, pH, pCO2) characterizing the carbonate system in seawater. TA is important for numerous research activities such as ocean acidification observation or carbon capture and storage (CCS) scenarios. Furthermore, TA gives precious information about many physical and biogeochemical processes such as dissolution or precipitation of calcium carbonate minerals, aerobic or anaerobic respiration as well as the mixing of water bodies. While autonomous sensors for pH and pCO2 are commercially available, there is none for TA yet that allows for measurements at sufficiently high spatial and temporal resolution. We present our latest development status of a robust and automated TA measuring system based on sample acidification and subsequent spectrophotometric pH determination. Measurement data is shown and discussed. We outline the next steps to be taken towards a fully automated, easy to use and commercially available system for discrete sample measurements and autonomous surface water applications.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 8
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    In:  [Poster] In: Ocean Sciences Meeting 2014, 23.-28.02.2014, Honululu, Hawaii, USA .
    Publication Date: 2014-05-30
    Description: Understanding the global carbon cycle and its variation requires a dense network of observations. Despite a growing data base for marine CO2 surface observations (SOCAT v2) large parts of the oceans still remain uncharted both in space and time (e.g., Southern Ocean, Arabian Sea). Moreover, the impact of mesoscale processes on the marine carbon cycle is still not well understood due to a lack of high resolution in situ observations. Recently, small-sized and submersible pCO2 and O2 sensors can be used to overcome these constraints. Thus, next to ship-based observations new platform technologies such as profiling floats or gliders come into reach. Two science showcases in the eastern tropical North Atlantic will be presented to demonstrate the potential of such autonomous observations: 1) Measurements of pCO2 and O2 performed on a profiling float were used to derive precise air-sea fluxes and production estimates which are consistent with time-series data from the Cape Verde Ocean Observatory (CVOO) and 2) a suite of synergetic autonomous O2 observations (glider, float, mooring) revealed mesoscale processes that featured unexpected open ocean subsurface hypoxia and anoxia.
    Type: Conference or Workshop Item , NonPeerReviewed
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  • 9
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    In:  International Ocean Systems, 18 (2).
    Publication Date: 2017-01-24
    Description: The world's oceans are an important sink for increasing anthropogenic CO2 emissions. Since the middle of the 18th century, the world's oceans have absorbed about 41% of anthropogenic CO2. As CO2 forms carbonic acid in water, CO2 absorption also has an effect on seawater pH. This decrease in seawater pH - of about 0.1pH units so far - is also known as ocean acidification and it amounts to an increase in acid concentration of approximately 30%. In order to track corresponding changes in the carbonate system there is a need for innovative sensors.
    Type: Article , NonPeerReviewed
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