Publication Date:
2012-11-13
Description:
In the mixed-ligand metal–organic title polymeric compound, [Zn(C 10 H 8 O 4 )(C 10 H 16 N 6 )] n or [Zn(PBEA)(BTH)] n [H 2 PBEA is benzene-1,4-diacetic acid and BTH is 1,6-bis(1,2,4-triazol-1-yl)hexane], the asymmetric unit contains a Zn II atom, one half of a BTH ligand and one half of a doubly deprotonated H 2 PBEA ligand. Each Zn II centre lies on a crystallographic twofold rotation axis and is four-coordinated by two O atoms from two distinct PBEA 2− ligands and two N atoms from two different BTH ligands in a {ZnO 2 N 2 } coordination environment. The three-dimensional topology of the title compound corresponds to that of a fivefold interpenetrating diamond-like metal–organic framework.
Print ISSN:
0108-2701
Electronic ISSN:
1600-5759
Topics:
Chemistry and Pharmacology
,
Geosciences
,
Physics
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