Description: Samples for total organic carbon (TOC) analysis were collected on WOCE Line P15S (0° to 67°S along 170°W) and from 53° to 67°S along 170°E in the western South Pacific, and on Line I8 (5°N to 43°S along 80°/90°E) in the central Indian Ocean. TOC concentrations in the upper ocean varied greatly between the regions studied. Highest surface TOC concentrations (81-85 µM C and 68-73 µM C) were observed in the warmest waters (〉27°C) of the western South Pacific and central Indian Oceans, respectively. Lowest surface TOC concentrations (45-65 µM C) were recorded in the southernmost waters occupied (〉50°S along 170°W and 170°E). Deep water (〉1000 m) TOC concentrations were uniform across all regions analyzed, averaging between 42.3 and 43 µM C (SD: ±0.9 µM C). Mixing between TOC-rich surface waters and TOC-poor deep waters was indicated by the strong correlations between TOC and temperature (r2〉0.80, north of 45°S) and TOC and density (r2〉0.50, southernmost regions). TOC was inversely correlated with apparent oxygen utilization (AOU) along isopycnal surfaces north of the Polar Frontal Zone (PFZ) and at depths 〈500 m. The TOC:AOU molar ratios at densities of sigmaT 23-27 ranged from -0.15 to -0.34 in the South Pacific and from -0.13 to -0.31 in the Indian Ocean. These ratios indicate that TOC oxidation was responsible for 21%-47% and 18%-43% of oxygen consumption in the upper South Pacific and Indian Oceans, respectively. At greater depths, TOC did not contribute to the development of AOU. There was no evidence for significant export of dissolved and suspended organic carbon along isopycnal surfaces that ventilate near the PFZ.

Description: Dissolved and particulate organic matter was measured during six cruises to the southern Ross Sea. The cruises were conducted during late austral winter to autumn from 1994 to 1997 and included coverage of various stages of the seasonal phytoplankton bloom. The data from the various years are compiled into a representative seasonal cycle in order to assess general patterns of dissolved organic matter (DOM) and particulate organic matter (POM) dynamics in the southern Ross Sea. Dissolved organic carbon (DOC) and particulate organic carbon (POC) were at background concentrations of approximately 42 and 3 µM C, respectively, during the late winter conditions in October. As the spring phytoplankton bloom progressed, organic matter increased, and by January DOC and POC reached as high as 30 and 107 µM C, respectively, in excess of initial wintertime conditions. Stocks and concentrations of DOC and POC returned to near background values by autumn (April). Approximately 90% of the accumulated organic matter was partitioned into POM, with modest net accumulation of DOM stocks despite large net organic matter production and the dominance of Phaeocystis antarctica. Changes in NO3 concentration from wintertime values were used to calculate the equivalent biological drawdown of dissolved inorganic carbon (DICequiv). The fraction of DICequiv drawdown resulting in net DOC production was relatively constant (ca. 11%), despite large temporal and spatial variability in DICequiv drawdown. The C : N (molar ratio) of the seasonally produced DOM had a geometric mean of 6.2 and was nitrogen-rich compared to background DOM. The DOM stocks that accumulate in excess of deep refractory background stocks are often referred to as "semi-labile" DOM. The "semi-labile" pool in the Ross Sea turns over on timescales of about 6 months. As a result of the modest net DOM production and its lability, the role DOM plays in export to the deep sea is small in this region.