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  • Chemistry  (4)
  • 2015-2019
  • 1990-1994
  • 1985-1989  (4)
  • 1935-1939
  • 1985  (4)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 327 (1985), S. 399-410 
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Photoinduced Electron Transfer between Arenediazonium Cations and AnionsAnions X⊖ can act as donors in electron transfer reactions to photoexcited arenediazonium ions. The yield of the arene formed in this reaction increases with decreasing electrochemical oxidation potential EoxD of X⊖ (X⊖ = BPh4⊖, Br⊖, HOOC—COO⊖, Cl⊖, BF4⊖). The oxidized donor X· (Cl·, ·COO⊖) and aryl radicals Ar· benig intermediates of the reductive dediazoniation of ArN2⊖ can be detected by spin trapping with nitrosodurene (ND) and phenyl-tert-butylnitrone (PBN). A solvent effect in the electron transfer reaction is interpreted in terms of ion pairing, where the electron transfer is favored by preorientation and a short distance between the electron donor and the acceptor previous to excitation of ArN2⊖ by light.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 57 (1985), S. 395-409 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dosage of solids and liquids. Dosage of reaction components is an important step in chemical engineering processes. In an age of increasing automation, the development of dosage procedures is highly topical; electronics and data processing have long made inroads into dosage procedures. However, today's more stringent demands with regard to pressure, temperature, viscosity, and abrasion necessitate intensified research and development efforts. The present article considers mainly volumetric and geometric dosage methods. The many types of metering pumps cover a large area of dosage of liquids. Minimal flow rates, pressures up to several 1000 bar, and also dangerous and difficult fluids can all be safely handled. Leakproof designs with membranes, tubes, or bellows as displacement devices are particularly important nowadays. Volumetric dosage of solids requires establishment of a reproducible packing density. The survey considers the principle methods of dosage (also against pressure) with special emphasis on screw dosage. Gravimetric dosage methods are extremely reliable and accurate but generally require volumetric systems for energy supply. Especially when used in combination with metering pumps or screw dosage, differential balances have numerous possible applications.
    Additional Material: 25 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 57 (1985), S. 218-229 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Leakfree oscillating positive-displacement pumps - state of the art and trends of development. Leak- and maintenance-free oscillating positive-displacement pumps are very important for avoiding pollution and improving the reliability of plants. Technical progress in the field of hydraulic diaphragm- and tube-pumps for high pressures are explained. The actual data (pressure, efficiency, temperature) and experience with different fluids are surveyed. The various hydraulic control systems, the diaphragm design, and methods for rupture-control are compared. Further development trends are explained.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 20 (1985), S. 266-267 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Limitation Availability
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