In:
The Journal of Chemical Physics, AIP Publishing, Vol. 33, No. 5 ( 1960-11-01), p. 1324-1331
Abstract:
The equation of motion of a quantum-mechanical two-particle system is solved without approximation in an expansion in Planck's constant. First-order quantum corrections comprising all contributions to the coefficient of ℏ2 in the expansion are derived for the differential scattering cross section and the kinetic-theory transport coefficients. Numerical results are obtained for a simple model of molecular interactions, and lack of agreement is found with work based on the WKB solution of the Schrödinger equation.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1960
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
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