In:
Applied Physics Letters, AIP Publishing, Vol. 87, No. 25 ( 2005-12-19)
Abstract:
We have monitored the optical luminescence from ZnS nanowires as a function of x-ray energy at the Zn L edge (1022 eV). The x-ray absorption spectrum obtained using the 338 nm, band edge emission as a signal resembles that of the wurtzite form of ZnS, while that obtained using the 430 and 520 nm defect emissions, resembles that of the sphalerite phase. Wurtzite is the dominant phase of the wire, while sphalerite is only found at the end of the wire adjacent to the gold particle used for nucleation and in small, highly localized regions of the wire. Therefore, the present results support the idea that the defect luminescence centers are caused by Au ions (520 nm) and vacancies (430 nm), which are located in regions of sphalerite and show how x-ray excited optical luminescence may be used to probe the local environment of such centers.
Type of Medium:
Online Resource
ISSN:
0003-6951
,
1077-3118
Language:
English
Publisher:
AIP Publishing
Publication Date:
2005
detail.hit.zdb_id:
211245-0
detail.hit.zdb_id:
1469436-0
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