In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 70, No. 5 ( 2015-5-1), p. 311-316
Abstract:
An organic-inorganic hybrid compound based on {PMo 12 } layers, [Ag(pz) 2 ] 6 [PMo 12 O 40 ] 2 ·3H 2 O 1 (pz = pyrazole), has been hydrothermally synthesized and characterized by elemental analysis, TG, IR spectroscopy, and single-crystal X-ray diffraction. Two crystallographically independent [PMo 12 O 40 ] 3– clusters are arranged in an AB–AB mode to give two kinds of supramolecular layers. The layers are further connected in a special alternating mode by [Ag(pz) 2 ] + linkers to form complex 3-D supramolecular network. Compound 1 exhibits good electrocatalytic activity in the reduction of hydrogen peroxide and shows fluorescence in the solid state at room temperature.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2014-0239
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2015
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
Permalink