In:
ChemistrySelect, Wiley, Vol. 4, No. 39 ( 2019-10-24), p. 11572-11577
Abstract:
Monopropargylamine iron(II) tris‐dioximate was easily prepared in a high yield using nucleophilic substitution of its monochloroclathrochelate precursor with propargylamine as a primary aliphatic amine N ‐nucleophile in acetonitrile as a solvent. This complex with terminal C≡C group underwent a 1,3‐dipolar cycloaddition “click”‐reaction with ortho ‐carborane‐1‐methylazide, thus giving a hybrid iron(II) carboranoclathrochelate with ortho ‐carborane‐(12)‐[1,2,3]‐triazolmethylamine fragment in its ribbed substituent, the molecule of which contains two ( i. e . clathrochelate and carborane) terminal cages. These complexes were characterized using elemental analysis, MALDI‐TOF mass, IR, UV‐Vis, 1 H, 1 H{ 11 B}, 11 B, 11 B{ 1 H}, 19 F{ 1 H} and 13 C{ 1 H} NMR spectra, and by single crystal X‐ray diffraction as well.
Type of Medium:
Online Resource
ISSN:
2365-6549
,
2365-6549
DOI:
10.1002/slct.201902888
Language:
English
Publisher:
Wiley
Publication Date:
2019
detail.hit.zdb_id:
2844262-3
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