In:
Dalton Transactions, Royal Society of Chemistry (RSC), Vol. 51, No. 34 ( 2022), p. 12915-12920
Abstract:
The mechanism of carbamate activation promoted by different metal ions has been explored in this work. The reaction of the carbamate ligand H 2 L with chloride metal salts (M = Ni, Cu, Zn, Cd) leads to the coordination of the metal ions to the ligand, causing hydrolysis of the systems. This self-immolation process results in mononuclear dihydrazone complexes, carbon dioxide and the release of alcohol species from the pendant groups of the carbamate ligand. The conditions under which this process occurs have been studied in detail.
Type of Medium:
Online Resource
ISSN:
1477-9226
,
1477-9234
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
1472887-4
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