In:
Angewandte Chemie, Wiley, Vol. 132, No. 49 ( 2020-12), p. 22293-22300
Abstract:
The capability to significantly shorten the synthetic period of a broad spectrum of open organic materials presents an enticing prospect for materials processing and applications. Herein we discovered 1,2,4‐triazolium poly(ionic liquid)s (PILs) could serve as a universal additive to accelerate by at least one order of magnitude the growth rate of representative imine‐linked crystalline open organics, including organic cages, covalent organic frameworks (COFs), and macrocycles. This phenomenon results from the active C5‐protons in poly(1,2,4‐triazolium)s that catalyze the formation of imine bonds, and the simultaneous salting‐out effect (induced precipitation by decreasing solubility) that PILs exert on these crystallizing species.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v132.49
DOI:
10.1002/ange.202008415
Language:
English
Publisher:
Wiley
Publication Date:
2020
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505868-5
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506609-8
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514305-6
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505872-7
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1479266-7
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506259-7
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