In:
Materials Science Forum, Trans Tech Publications, Ltd., Vol. 443-444 ( 2004-1), p. 345-348
Abstract:
The crystal structure of new Prussian blue analogue samples,
KCu[Fe 1-x Co x (CN) 6 ], KNi[Fe 1-x Co x (CN) 6 ] and Fe[Fe 1-x Co x (CN) 6 ], was solved on the base of the model from Keggin and Miles [1] and refined by the Rietveld method [2] from conventional X-ray powder diffraction data. These compounds form mixed crystals for all Fe/Co ratios. The crystal structure of the KCu[Fe 0.3 Co 0.7 (CN) 6 ], KNi[Fe 0.3 Co 0.7 (CN) 6 ] and Fe[Fe 0.8 Co 0.2 (CN) 6 ] is presented in detail. For both potassium containing compounds the disorder in the potassium arrangement is the most obvious characteristic.
Type of Medium:
Online Resource
ISSN:
1662-9752
DOI:
10.4028/www.scientific.net/MSF.443-444
DOI:
10.4028/www.scientific.net/MSF.443-444.345
Language:
Unknown
Publisher:
Trans Tech Publications, Ltd.
Publication Date:
2004
detail.hit.zdb_id:
2047372-2
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