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  • Copernicus GmbH  (11)
  • Westerhold, Thomas  (11)
  • 1
    In: Climate of the Past, Copernicus GmbH, Vol. 13, No. 9 ( 2017-09-11), p. 1129-1152
    Abstract: Abstract. To fully understand the global climate dynamics of the warm early Eocene with its reoccurring hyperthermal events, an accurate high-fidelity age model is required. The Ypresian stage (56–47.8 Ma) covers a key interval within the Eocene as it ranges from the warmest marine temperatures in the early Eocene to the long-term cooling trends in the middle Eocene. Despite the recent development of detailed marine isotope records spanning portions of the Ypresian stage, key records to establish a complete astronomically calibrated age model for the Ypresian are still missing. Here we present new high-resolution X-ray fluorescence (XRF) core scanning iron intensity, bulk stable isotope, calcareous nannofossil, and magnetostratigraphic data generated on core material from ODP Sites 1258 (Leg 207, Demerara Rise), 1262, 1263, 1265, and 1267 (Leg 208, Walvis Ridge) recovered in the equatorial and South Atlantic Ocean. By combining new data with published records, a 405 kyr eccentricity cyclostratigraphic framework was established, revealing a 300–400 kyr long condensed interval for magnetochron C22n in the Leg 208 succession. Because the amplitudes are dominated by eccentricity, the XRF data help to identify the most suitable orbital solution for astronomical tuning of the Ypresian. Our new records fit best with the La2010b numerical solution for eccentricity, which was used as a target curve for compiling the Ypresian astronomical timescale (YATS). The consistent positions of the very long eccentricity minima in the geological data and the La2010b solution suggest that the macroscopic feature displaying the chaotic diffusion of the planetary orbits, the transition from libration to circulation in the combination of angles in the precession motion of the orbits of Earth and Mars, occurred  ∼  52 Ma. This adds to the geological evidence for the chaotic behavior of the solar system. Additionally, the new astrochronology and revised magnetostratigraphy provide robust ages and durations for Chrons C21n to C24n (47–54 Ma), revealing a major change in spreading rates in the interval from 51.0 to 52.5 Ma. This major change in spreading rates is synchronous with a global reorganization of the plate–mantle system and the chaotic diffusion of the planetary orbits. The newly provided YATS also includes new absolute ages for biostratigraphic events, magnetic polarity reversals, and early Eocene hyperthermal events. Our new bio- and magnetostratigraphically calibrated stable isotope compilation may act as a reference for further paleoclimate studies of the Ypresian, which is of special interest because of the outgoing warming and increasingly cooling phase. Finally, our approach of integrating the complex comprehensive data sets unearths some challenges and uncertainties but also validates the high potential of chemostratigraphy, magnetostratigraphy, and biostratigraphy in unprecedented detail being most significant for an accurate chronostratigraphy.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2017
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  • 2
    Online Resource
    Online Resource
    Copernicus GmbH ; 2017
    In:  Climate of the Past Vol. 13, No. 7 ( 2017-07-05), p. 779-793
    In: Climate of the Past, Copernicus GmbH, Vol. 13, No. 7 ( 2017-07-05), p. 779-793
    Abstract: Abstract. Isotope stratigraphy has become the method of choice for investigating both past ocean temperatures and global ice volume. Lisiecki and Raymo (2005) published a stacked record of 57 globally distributed benthic δ18O records versus age (LR04 stack). In this study LR04 is compared to high-resolution records collected at all of the sites drilled during ODP Leg 154 on the Ceara Rise, in the western equatorial Atlantic Ocean. Newly developed software is used to check data splices of the Ceara Rise sites and better align out-of-splice data with in-splice data. Core images recovered from core table photos are depth and age scaled and greatly assist in the data analysis. The entire splices of ODP sites 925, 926, 927, 928 and 929 were reviewed. Most changes were minor although several were large enough to affect age models based on orbital tuning. A Ceara Rise composite record of benthic δ18O is out of sync with LR04 between 1.80 and 1.90 Ma, where LR04 exhibits two maxima but Ceara Rise data contain only one. The interval between 4.0 and 4.5 Ma in the Ceara Rise compilation is decidedly different from LR04, reflecting both the low amplitude of the signal over this interval and the limited amount of data available for the LR04 stack. A regional difference in benthic δ18O of 0.2 ‰ relative to LR04 was found. Independent tuning of Site 926 images and physical property data to the Laskar et al. (2004) orbital solution and integration of available benthic stable isotope data from the Ceara Rise provides a new regional reference section for the equatorial Atlantic covering the last 5 million years.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2017
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  • 3
    In: Climate of the Past, Copernicus GmbH, Vol. 15, No. 5 ( 2019-09-16), p. 1715-1739
    Abstract: Abstract. Coherent variation in CaCO3 burial is a feature of the Cenozoic eastern equatorial Pacific. Nevertheless, there has been a long-standing ambiguity in whether changes in CaCO3 dissolution or changes in equatorial primary production might cause the variability. Since productivity and dissolution leave distinctive regional signals, a regional synthesis of data using updated age models and high-resolution stratigraphic correlation is an important constraint to distinguish between dissolution and production as factors that cause low CaCO3. Furthermore, the new chronostratigraphy is an important foundation for future paleoceanographic studies. The ability to distinguish between primary production and dissolution is also important to establish a regional carbonate compensation depth (CCD). We report late Miocene to Holocene time series of XRF-derived (X-ray fluorescence) bulk sediment composition and mass accumulation rates (MARs) from eastern equatorial Pacific Integrated Ocean Drilling Program (IODP) sites U1335, U1337, and U1338 and Ocean Drilling Program (ODP) site 849, and we also report bulk-density-derived CaCO3 MARs at ODP sites 848, 850, and 851. We use physical properties, XRF bulk chemical scans, and images along with available chronostratigraphy to intercorrelate records in depth space. We then apply a new equatorial Pacific age model to create correlated age records for the last 8 Myr with resolutions of 1–2 kyr. Large magnitude changes in CaCO3 and bio-SiO2 (biogenic opal) MARs occurred within that time period but clay deposition has remained relatively constant, indicating that changes in Fe deposition from dust is only a secondary feedback to equatorial productivity. Because clay deposition is relatively constant, ratios of CaCO3 % or biogenic SiO2 % to clay emulate changes in biogenic MAR. We define five major Pliocene–Pleistocene low CaCO3 % (PPLC) intervals since 5.3 Ma. Two were caused primarily by high bio-SiO2 burial that diluted CaCO3 (PPLC-2, 1685–2135 ka, and PPLC-5, 4465–4737 ka), while three were caused by enhanced dissolution of CaCO3 (PPLC-1, 51–402 ka, PPLC-3, 2248–2684 ka, and PPLC-4, 2915–4093 ka). Regional patterns of CaCO3 % minima can distinguish between low CaCO3 caused by high diatom bio-SiO2 dilution versus lows caused by high CaCO3 dissolution. CaCO3 dissolution can be confirmed through scanning XRF measurements of Ba. High diatom production causes lowest CaCO3 % within the equatorial high productivity zone, while higher dissolution causes lowest CaCO3 percent at higher latitudes where CaCO3 production is lower. The two diatom production intervals, PPLC-2 and PPLC-5, have different geographic footprints from each other because of regional changes in eastern Pacific nutrient storage after the closure of the Central American Seaway. Because of the regional variability in carbonate production and sedimentation, the carbonate compensation depth (CCD) approach is only useful to examine large changes in CaCO3 dissolution.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
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  • 4
    In: Climate of the Past, Copernicus GmbH, Vol. 17, No. 5 ( 2021-10-15), p. 2091-2117
    Abstract: Abstract. The evolution of the Cenozoic cryosphere from unipolar to bipolar over the past 30 million years (Myr) is broadly known. Highly resolved records of carbonate (CaCO3) content provide insight into the evolution of regional and global climate, cryosphere, and carbon cycle dynamics. Here, we generate the first Southeast Atlantic CaCO3 content record spanning the last 30 Myr, derived from X-ray fluorescence (XRF) ln(Ca / Fe) data collected at Ocean Drilling Program Site 1264 (Walvis Ridge, SE Atlantic Ocean). We present a comprehensive and continuous depth and age model for the entirety of Site 1264 (∼ 316 m; 30 Myr). This constitutes a key reference framework for future palaeoclimatic and palaeoceanographic studies at this location. We identify three phases with distinctly different orbital controls on Southeast Atlantic CaCO3 deposition, corresponding to major developments in climate, the cryosphere and the carbon cycle: (1) strong ∼ 110 kyr eccentricity pacing prevails during Oligocene–Miocene global warmth (∼ 30–13 Ma), (2) increased eccentricity-modulated precession pacing appears after the middle Miocene Climate Transition (mMCT) (∼ 14–8 Ma), and (3) pervasive obliquity pacing appears in the late Miocene (∼ 7.7–3.3 Ma) following greater importance of high-latitude processes, such as increased glacial activity and high-latitude cooling. The lowest CaCO3 content (92 %–94 %) occurs between 18.5 and 14.5 Ma, potentially reflecting dissolution caused by widespread early Miocene warmth and preceding Antarctic deglaciation across the Miocene Climatic Optimum (∼ 17–14.5 Ma) by 1.5 Myr. The emergence of precession pacing of CaCO3 deposition at Site 1264 after ∼ 14 Ma could signal a reorganisation of surface and/or deep-water circulation in this region following Antarctic reglaciation at the mMCT. The increased sensitivity to precession at Site 1264 between 14 and 13 Ma is associated with an increase in mass accumulation rates (MARs) and reflects increased regional CaCO3 productivity and/or recurrent influxes of cooler, less corrosive deep waters. The highest carbonate content (%CaCO3) and MARs indicate that the late Miocene–early Pliocene Biogenic Bloom (LMBB) occurs between ∼ 7.8 and 3.3 Ma at Site 1264; broadly contemporaneous with the LMBB in the equatorial Pacific Ocean. At Site 1264, the onset of the LMBB roughly coincides with appearance of strong obliquity pacing of %CaCO3, reflecting increased high-latitude forcing. The global expression of the LMBB may reflect increased nutrient input into the global ocean resulting from enhanced aeolian dust and/or glacial/chemical weathering fluxes, due to enhanced glacial activity and increased meridional temperature gradients. Regional variability in the timing and amplitude of the LMBB may be driven by regional differences in cooling, continental aridification and/or changes in ocean circulation in the late Miocene.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2021
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  • 5
    Online Resource
    Online Resource
    Copernicus GmbH ; 2018
    In:  Climate of the Past Vol. 14, No. 3 ( 2018-03-08), p. 321-338
    In: Climate of the Past, Copernicus GmbH, Vol. 14, No. 3 ( 2018-03-08), p. 321-338
    Abstract: Abstract. Ocean Drilling Program (ODP) Site 982 represents a key location for understanding the evolution of climate in the North Atlantic over the past 12 Ma. However, concerns exist about the validity and robustness of the underlying stratigraphy and astrochronology, which currently limits the adequacy of this site for high-resolution climate studies. To resolve this uncertainty, we verify and extend the early Pliocene to late Miocene shipboard composite splice at Site 982 using high-resolution XRF core scanning data and establish a robust high-resolution benthic foraminiferal stable isotope stratigraphy and astrochronology between 8.0 and 4.5 Ma. Splice revisions and verifications resulted in  ∼  11 m of gaps in the original Site 982 isotope stratigraphy, which were filled with 263 new isotope analyses. This new stratigraphy reveals previously unseen benthic δ18O excursions, particularly prior to 6.65 Ma. The benthic δ18O record displays distinct, asymmetric cycles between 7.7 and 6.65 Ma, confirming that high-latitude climate is a prevalent forcing during this interval. An intensification of the 41 kyr beat in both the benthic δ13C and δ18O is also observed  ∼  6.4 Ma, marking a strengthening in the cryosphere–carbon cycle coupling. A large  ∼  0.7 ‰ double excursion is revealed  ∼  6.4–6.3 Ma, which also marks the onset of an interval of average higher δ18O and large precession and obliquity-dominated δ18O excursions between 6.4 and 5.4 Ma, coincident with the culmination of the late Miocene cooling. The two largest benthic δ18O excursions  ∼  6.4–6.3 Ma and TG20/22 coincide with the coolest alkenone-derived sea surface temperature (SST) estimates from Site 982, suggesting a strong connection between the late Miocene global cooling, and deep-sea cooling and dynamic ice sheet expansion. The splice revisions and revised astrochronology resolve key stratigraphic issues that have hampered correlation between Site 982, the equatorial Atlantic and the Mediterranean. Comparisons of the revised Site 982 stratigraphy to high-resolution astronomically tuned benthic δ18O stratigraphies from ODP Site 926 (equatorial Atlantic) and Ain el Beida (north-western Morocco) show that prior inconsistencies in short-term excursions are now resolved. The identification of key new cycles at Site 982 further highlights the requirement for the current scheme for late Miocene marine isotope stages to be redefined. Our new integrated deep-sea benthic stable isotope stratigraphy and astrochronology from Site 982 will facilitate future high-resolution late Miocene to early Pliocene climate research.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
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  • 6
    In: Climate of the Past, Copernicus GmbH, Vol. 14, No. 1 ( 2018-01-15), p. 39-55
    Abstract: Abstract. The Paleocene–Eocene Thermal Maximum (PETM, 56 Ma) was a phase of rapid global warming associated with massive carbon input into the ocean–atmosphere system from a 13C-depleted reservoir. Many midlatitude and high-latitude sections have been studied and document changes in salinity, hydrology and sedimentation, deoxygenation, biotic overturning, and migrations, but detailed records from tropical regions are lacking. Here, we study the PETM at Ocean Drilling Program (ODP) Site 959 in the equatorial Atlantic using a range of organic and inorganic proxies and couple these with dinoflagellate cyst (dinocyst) assemblage analysis. The PETM at Site 959 was previously found to be marked by a  ∼  3.8 ‰ negative carbon isotope excursion (CIE) and a  ∼  4 °C surface ocean warming from the uppermost Paleocene to peak PETM, of which  ∼  1 °C occurs before the onset of the CIE. We record upper Paleocene dinocyst assemblages that are similar to PETM assemblages as found in extratropical regions, confirming poleward migrations of ecosystems during the PETM. The early stages of the PETM are marked by a typical acme of the tropical genus Apectodinium, which reaches abundances of up to 95 %. Subsequently, dinocyst abundances diminish greatly, as do carbonate and pyritized silicate microfossils. The combined paleoenvironmental information from Site 959 and a close-by shelf site in Nigeria implies the general absence of eukaryotic surface-dwelling microplankton during peak PETM warmth in the eastern equatorial Atlantic, most likely caused by heat stress. We hypothesize, based on a literature survey, that heat stress might have reduced calcification in more tropical regions, potentially contributing to reduced deep sea carbonate accumulation rates, and, by buffering acidification, also to biological carbonate compensation of the injected carbon during the PETM. Crucially, abundant organic benthic foraminiferal linings imply sustained export production, likely driven by prokaryotes. In sharp contrast, the recovery of the CIE yields rapid (≪ 10 kyr) fluctuations in the abundance of several dinocyst groups, suggesting extreme ecosystem and environmental variability.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
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  • 7
    In: Climate of the Past, Copernicus GmbH, Vol. 14, No. 3 ( 2018-03-08), p. 303-319
    Abstract: Abstract. A consistent chronostratigraphic framework is required to understand the effect of major paleoclimate perturbations on both marine and terrestrial ecosystems. Transient global warming events in the early Eocene, at 56–54 Ma, show the impact of large-scale carbon input into the ocean–atmosphere system. Here we provide the first timescale synchronization of continental and marine deposits spanning the Paleocene–Eocene Thermal Maximum (PETM) and the interval just prior to the Eocene Thermal Maximum 2 (ETM-2). Cyclic variations in geochemical data come from continental drill cores of the Bighorn Basin Coring Project (BBCP, Wyoming, USA) and from marine deep-sea drilling deposits retrieved by the Ocean Drilling Program (ODP). Both are dominated by eccentricity-modulated precession cycles used to construct a common cyclostratigraphic framework. Integration of age models results in a revised astrochronology for the PETM in deep-sea records that is now generally consistent with independent 3He age models. The duration of the PETM is estimated at ∼ 200 kyr for the carbon isotope excursion and ∼ 120 kyr for the associated pelagic clay layer. A common terrestrial and marine age model shows a concurrent major change in marine and terrestrial biota ∼ 200 kyr before ETM-2. In the Bighorn Basin, the change is referred to as Biohorizon B and represents a period of significant mammalian turnover and immigration, separating the upper Haplomylus–Ectocion Range Zone from the Bunophorus Interval Zone and approximating the Wa-4–Wa-5 land mammal zone boundary. In sediments from ODP Site 1262 (Walvis Ridge), major changes in the biota at this time are documented by the radiation of a “second generation” of apical spine-bearing sphenolith species (e.g., S. radians and S. editus), the emergence of T. orthostylus, and the marked decline of D. multiradiatus.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2018
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  • 8
    Online Resource
    Online Resource
    Copernicus GmbH ; 2022
    In:  Climate of the Past Vol. 18, No. 12 ( 2022-12-16), p. 2631-2641
    In: Climate of the Past, Copernicus GmbH, Vol. 18, No. 12 ( 2022-12-16), p. 2631-2641
    Abstract: Abstract. The marine biological carbon pump, which exports organic carbon out of the surface ocean, plays an essential role in sequestering carbon from the atmosphere, thus impacting climate and affecting marine ecosystems. Orbital variations in solar insolation modulate these processes, but their influence on the tropical Pacific during the Late Cretaceous is unknown. Here we present a high-resolution composite record of elemental barium from deep-sea sediments as a proxy for organic carbon export out of the surface oceans (i.e., export production) from Shatsky Rise in the tropical Pacific. Variations in export production in the Pacific during the Maastrichtian, from 71.5 to 66 million years ago, were dominated by precession and less so by eccentricity modulation or obliquity, confirming that tropical surface-ocean carbon dynamics were influenced by seasonal insolation in the tropics during this greenhouse period. We suggest that precession paced primary production in the tropical Pacific and recycling in the euphotic zone by changing water column stratification, upwelling intensity, and continental nutrient fluxes. Benthic foraminiferal accumulation rates covaried with export production, providing evidence for bentho-pelagic coupling of the marine biological carbon pump across these high-frequency changes in a cool greenhouse planet.
    Type of Medium: Online Resource
    ISSN: 1814-9332
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2022
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  • 9
    In: Biogeosciences, Copernicus GmbH, Vol. 20, No. 3 ( 2023-02-06), p. 597-618
    Abstract: Abstract. Marine plankton is an important component of the global carbon cycle. Whereas the production and seafloor export of organic carbon produced by the plankton, the biological pump, has received much attention, the long-term variability in plankton calcification, controlling the carbonate counter pump, remains less well understood. However, it has been shown that changes in pelagic calcification (biological compensation) could affect the ocean's buffering capacity and thus regulate global carbon budget on geological timescales. Here we use Neogene pelagic sediments deposited on the Ceara Rise in the tropical Atlantic to characterize the variability in pelagic carbonate production with a focus on warm climates. A re-evaluation of published records of carbonate accumulation at the Ceara Rise reveals a systematic increase in sedimentation rates since the late Miocene, but the carbonate accumulation rate does not show a clear trend. Instead, we observe substantial orbital timescale variability in carbonate accumulation, combined with a trend towards less carbonate on average at sites located below 4 km, likely due to the effect of carbonate dissolution. To evaluate long-term changes against possible orbital-scale variability, we generated new high-resolution records of carbonate accumulation rate at Ocean Drilling Program (ODP) Site 927 across two Quaternary interglacials (MIS 5 and MIS 9), the Pliocene warm period (MIS KM5) and the Miocene Climatic Optimum (MCO). We observe that the highest carbonate accumulation rates occurred during the Pliocene but that each of the studied intervals was characterized by large-magnitude orbital variability. Prominent variations in carbonate accumulation prior to the Quaternary preservation cycles appear to follow Earth obliquity and eccentricity. These results imply that pelagic carbonate accumulation in the tropical ocean, buffered from large temperature changes, varied on orbital timescales. The magnitude of the orbital-scale variability was similar or even higher than the long-term mean differences among the studied intervals. Since preservation can be excluded as a driver of these changes prior to the Quaternary, the observed variations must reflect changes in the export flux of pelagic biogenic carbonate. We conclude that the overall carbonate production by pelagic calcifiers responded to local changes in light, temperature, and nutrients delivered by upwelling, which followed long orbital cycles, as well as to long-term shifts in climate and/or ocean chemistry. The inferred changes on both timescales were sufficiently large such that when extrapolated on a global scale, they could have played a role in the regulation of the carbon cycle and global climate evolution during the transition from the Miocene warm climates into the Quaternary icehouse.
    Type of Medium: Online Resource
    ISSN: 1726-4189
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2023
    detail.hit.zdb_id: 2158181-2
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  • 10
    In: Geoscientific Model Development, Copernicus GmbH, Vol. 12, No. 7 ( 2019-07-25), p. 3149-3206
    Abstract: Abstract. The early Eocene (56 to 48 million years ago) is inferred to have been the most recent time that Earth's atmospheric CO2 concentrations exceeded 1000 ppm. Global mean temperatures were also substantially warmer than those of the present day. As such, the study of early Eocene climate provides insight into how a super-warm Earth system behaves and offers an opportunity to evaluate climate models under conditions of high greenhouse gas forcing. The Deep Time Model Intercomparison Project (DeepMIP) is a systematic model–model and model–data intercomparison of three early Paleogene time slices: latest Paleocene, Paleocene–Eocene thermal maximum (PETM) and early Eocene climatic optimum (EECO). A previous article outlined the model experimental design for climate model simulations. In this article, we outline the methodologies to be used for the compilation and analysis of climate proxy data, primarily proxies for temperature and CO2. This paper establishes the protocols for a concerted and coordinated effort to compile the climate proxy records across a wide geographic range. The resulting climate “atlas” will be used to constrain and evaluate climate models for the three selected time intervals and provide insights into the mechanisms that control these warm climate states. We provide version 0.1 of this database, in anticipation that this will be expanded in subsequent publications.
    Type of Medium: Online Resource
    ISSN: 1991-9603
    Language: English
    Publisher: Copernicus GmbH
    Publication Date: 2019
    detail.hit.zdb_id: 2456725-5
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