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  • Wang, Tianyu  (4)
  • Physics  (4)
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  • Physics  (4)
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  • 1
    In: Advanced Materials, Wiley
    Abstract: Developing high‐performance polarization‐sensitive ultraviolet photodetectors is crucial for their application in military remote sensing, detection, bio‐inspired navigation, and machine vision. However, the significant absorption in the visible light range severely limits the application of polarization‐sensitive ultraviolet photodetectors, such as high‐quality anti‐interference imaging. Here, based on a wide‐bandgap organic semiconductor single crystal (trans‐1,2‐bis(5‐phenyldithieno[2,3‐b:3′,2′‐d]thiophen‐2‐yl)ethene, BPTTE), high‐performance polarization‐sensitive solar‐blind ultraviolet photodetectors with a dichroic ratio close to 4.26 are demonstrated. The strong anisotropy of 2D grown BPTTE single crystals in molecular vibration and optical absorption is characterized by various techniques. Under voltage modulation, stable and efficient detection of polarized light is demonstrated, attributed to the intrinsic anisotropy of transition dipole moment in the bc crystal plane, rather than other factors. Finally, high‐contrast polarimetric imaging and anti‐interference imaging are successfully demonstrated based on BPTTE single crystal photodetectors, highlighting the potential of organic semiconductors for polarization‐sensitive solar‐blind ultraviolet photodetectors.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2024
    detail.hit.zdb_id: 1474949-X
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  • 2
    Online Resource
    Online Resource
    American Meteorological Society ; 2023
    In:  Journal of Climate Vol. 36, No. 2 ( 2023-01-15), p. 485-510
    In: Journal of Climate, American Meteorological Society, Vol. 36, No. 2 ( 2023-01-15), p. 485-510
    Abstract: The Kuroshio Extension (KE) system has been observed to experience a decadal cycle between dynamically stable and unstable states. However, divergent conclusions on its interaction with the atmosphere obfuscate the understanding of its oscillatory nature at the preferred decadal time scale. Here, using satellite observations and the ERA-Interim reanalysis in 2002–16, physical process-oriented diagnoses suggest that the wintertime finer-scale thermodynamic response to mesoscale oceanic surface conditions and slow oceanic Rossby wave adjustment frame a coupled ocean–atmosphere delayed oscillator for the decadal KE variability. During the stable state of the KE system, the downstream KE transition region is rich in mesoscale oceanic warming associated with warm eddies, which induces surface wind convergence and upward motion, probably via the enhanced turbulent mixing. Meanwhile, increased finer-scale diabatic heating in the lower troposphere with abundant moisture supply from warmer water likely facilitates the deep-reaching updraft that adiabatically cools the middle troposphere. The background northwesterly wind helps to spread out the cooling, leading to southward deflection of local atmospheric eddy available potential energy (EAPE) production by baroclinic conversion. Consequently, the synoptic eddy activity displaces southward across the basin with additional energy supply from the increased diabatic production of EAPE downstream. Anomalous synoptic eddy thermal and vorticity forcing eventually fosters the basin-scale equivalent-barotropic cyclonic circulation anomaly, which is further maintained by energy conversion from the background state. The resultant wind-driven negative sea surface height anomalies propagate westward into the upstream KE region with a delay of ∼4 years and can trigger the unstable state of the KE system.
    Type of Medium: Online Resource
    ISSN: 0894-8755 , 1520-0442
    RVK:
    Language: Unknown
    Publisher: American Meteorological Society
    Publication Date: 2023
    detail.hit.zdb_id: 246750-1
    detail.hit.zdb_id: 2021723-7
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  • 3
    In: Advanced Materials, Wiley, Vol. 35, No. 17 ( 2023-04)
    Abstract: To facilitate solar‐driven overall CO 2 and H 2 O convsersion into fuels and O 2 , a series of covalent microporous polymers derived from Tröger's base are synthesized featuring flexural backbone and unusual charge‐transfer properties. The incorporation of rigid structural twist Tröger's base unit grants the polymers enhanced microporosity and CO 2 adsorption/activation capacity. Density function theory calculations and photo‐electrochemical analyses reveal that an electric dipole moment (from negative to positive) directed to the Tröger's base unit is formed across two obliquely opposed molecular fragments and induces an intramolecular electric field. The Tröger's base unit located at folding point becomes an electron trap to attract photogenerated electrons in the molecular network, which brings about suppression of carrier recombination and designates the reaction site in synergy with the conjugated network. In response to the discrepancy in reaction pathways across the reaction sites, the product allocation in the catalytic reaction is thereby regulated. Optimally, CMP‐nTB achieves the highest photocatalytic CO production of 163.53 µmol g −1 h −1 with approximately unity selectivity, along with H 2 O oxidation to O 2 in the absence of any photosensitizer or co‐catalyst. This work provides new insight for developing specialized artificial organic photocatalysts.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2023
    detail.hit.zdb_id: 1474949-X
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  • 4
    Online Resource
    Online Resource
    Wiley ; 2016
    In:  Advanced Materials Vol. 28, No. 6 ( 2016-02), p. 1044-1059
    In: Advanced Materials, Wiley, Vol. 28, No. 6 ( 2016-02), p. 1044-1059
    Abstract: Helical structures such as double helical DNA and the α‐helical proteins found in biological systems are among the most beautiful natural structures. Chiral nanoarchitectonics, which is used here to describe the hierarchical formation and fabrication of chiral nanoarchitectures that can be observed by atomic force microscopy (AFM), scanning tunneling microscopy (STM), scanning electron microscopy (SEM), or transmission electron microscopy (TEM), is one of the most effective ways to mimic those natural chiral nanostructures. This article focuses on the formation, structure, and function of the most common chiral nanoarchitectures: nanoscale chiral twists and helices. The types of molecules that can be designed and how they can form hierarchical chiral nanoarchitectures are explored. In addition, new and unique functions such as amplified chiral sensing, chiral separation, biological effects, and circularly polarized luminescence associated with the chiral nanoarchitectures are discussed.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2016
    detail.hit.zdb_id: 1474949-X
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