In:
Angewandte Chemie, Wiley, Vol. 129, No. 29 ( 2017-07-10), p. 8606-8609
Abstract:
Reduction of tungsten hexacarbonyl by the divalent samarium(II) complex [Sm 2 (N 4 Et 8 )(thf) 4 ] ((N 4 Et 8 ) 4− = meso ‐octaethylcalix[4]pyrrolide) in toluene at ambient temperature gave the remarkable heteronuclear mixed‐valent samarium(II/III)/tungsten complex [{(thf) 2 Sm II (N 4 Et 8 )Sm III (thf)} 2 {(μ‐OC) 2 W 2 (CO) 8 }], which features the trapping of a rare [W 2 (CO) 10 ] 2− anion with an unsupported W−W bond.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v129.29
DOI:
10.1002/ange.201702636
Language:
English
Publisher:
Wiley
Publication Date:
2017
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505868-5
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506609-8
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514305-6
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505872-7
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1479266-7
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505867-3
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506259-7
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