In:
physica status solidi c, Wiley, Vol. 12, No. 7 ( 2015-07), p. 989-995
Abstract:
The development of a new process to obtain amorphous alumina thin films is presented. We show for the first time the direct liquid injection chemical vapor deposition (DLI CVD) of alumina thin films using dimethylaluminum isopropoxide (DMAI) precursor in two oxidizing atmospheres. At high process temperature (500‐700 °C), the film growth takes place in the presence of O 2 whereas at low temperature (150‐300 °C) H 2 O vapor is used. The materials characteristics, such as the surface morphology and roughness (SEM and AFM), crystal structure (XRD), composition (EPMA) and chemistry (XPS) are discussed in detail. Very smooth films, with typical roughness values lower than 2.0 nm are obtained. The thin films are all composed of an amorphous material with varying composition. Supported by both EPMA and XPS results, film composition evolves from a partial oxyhydroxide to a stoichiometric oxide at low deposition temperature (150‐300 °C) in the presence of H 2 O. At higher growth temperature (500‐700 °C) in the presence of O 2 , the composition changes from that of a stoichiometric oxide to a mixture of an oxide with aluminum carbide. (© 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Type of Medium:
Online Resource
ISSN:
1862-6351
,
1610-1642
DOI:
10.1002/pssc.201510009
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
2105580-4
detail.hit.zdb_id:
2102966-0
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