In:
Journal of Physical Organic Chemistry, Wiley, Vol. 19, No. 4 ( 2006-04), p. 269-275
Abstract:
The effects of the substituent X on the homolysis rate constants ( k d ) of SG1‐propionate type alkoxyamines (SG1‐CHMeCOOX) are analyzed by a multiparametric equation with υ , the steric constant and σ I , the polar inductive/field Hammett constant of X. An influence of long‐range polar and steric effects on k d was observed, that is, decrease in k d with increasing size of the X group and increase in k d with increasing polarity of the X group. Copyright © 2006 John Wiley & Sons, Ltd.
Type of Medium:
Online Resource
ISSN:
0894-3230
,
1099-1395
Language:
English
Publisher:
Wiley
Publication Date:
2006
detail.hit.zdb_id:
1475025-9
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