In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 72, No. 2 ( 2017-2-1), p. 107-113
Abstract:
Two isostructural fluorinated metal-organic frameworks, formulated as [ M 2 (Fbix)(1,4-NDC) 2 ] n ( M =Cd for 1 and Mn for 2 ), were synthesized by employing 1,4-naphthalenedicarboxylic acid (1,4-H 2 NDC) and the flexible fluorinated ligand 2,3,5,6-tetrafluoro-1,4-bis(imidazole-1-yl-methyl)benzene (Fbix) under hydrothermal conditions. Their structures were determined by single-crystal X-ray diffraction and further characterized by infrared spectroscopy, powder X-ray diffraction, and thermogravimetric analyses. Structure analyses have revealed that compounds 1 and 2 show an unusual hex net based on infinite rod-shaped secondary building units. The solid-state fluorescence spectra of 1 and 2 were measured and indicate a ligand-based emission for both complexes.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-2016-0191
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
2017
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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