In:
CrystEngComm, Royal Society of Chemistry (RSC), Vol. 24, No. 47 ( 2022), p. 8321-8325
Abstract:
Herein, we have investigated the host–guest inclusion complexes formed on interaction of the symmetric tetramethyl-substituted cucurbit[6]uril (TMeQ[6] ) with glycine (Gly) under different conditions. The interactions have been studied both in solution (by 1 H NMR spectroscopy and mass spectrometry) and in the solid state by single crystal X-ray diffraction. The molecular structures of two products are reported, namely TMeQ[6]·(H 2 O) 2 (PO 4 )(NH 3 CH 2 COOH) 2 (1) and TMeQ[6]·Ca(H 2 O) 5 ·(Cl) 3 (NH 3 CH 2 COOH)·16H 2 O (2). Complex 1 adopts a hydrogen-bonded dimeric structure with two glycinium ions contained within a TMeQ[6] molecule with the NH 3 + portions of the two molecules located just above the opposite rims of the bowl and forming hydrogen bonds with C–O. In 2, there are centrosymmetric dimers bridged by pairs of calcium ions.
Type of Medium:
Online Resource
ISSN:
1466-8033
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2022
detail.hit.zdb_id:
2025075-7
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