In:
Angewandte Chemie, Wiley, Vol. 133, No. 18 ( 2021-04-26), p. 10041-10046
Abstract:
The successful integration or hybridization of perovskite oxides with their halide cousins would enable the formation of both multi‐anionic and multi‐cationic solid solutions with unique metal‐ion sites and synergistic properties that could potentially surpass the performance of classic perovskites. However, such solid solutions had not been produced previously owing to their distinct formation energies and different synthesis conditions. Solid solutions combining perovskite oxides with fluorides were produced in this study by mechanochemical synthesis. The obtained perovskite oxide–halide solid solutions had highly mixed elements and valences, uniform element distributions, and single‐phase crystalline structures. The solid solution with an optimized combination of oxides and fluorides exhibited enhanced catalytic performance in the oxygen evolution reaction.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.v133.18
DOI:
10.1002/ange.202101120
Language:
English
Publisher:
Wiley
Publication Date:
2021
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