In:
Current Organic Chemistry, Bentham Science Publishers Ltd., Vol. 23, No. 20 ( 2019-12-24), p. 2155-2167
Abstract:
Lignocellulosic biomass can be converted to significant platform molecule 5-
hydroxymethylfurfural (HMF), from which one can envision a number of biofuels and chemicals through either chemical or biological conversions. Chemoselective hydrogenation
is one of the important pathways for the upgrading of HMF into furanyl diols consisting of 2,5-bis(hydroxymethyl)furan (BHMF) and 2,5-bis(hydroxymethyl)tetrahydrofuran
(BHMTHF). BHMF and BHMTHF are all-purpose intermediates for the manufacture of chemicals, fuels, and functional materials. In this context, we comprehensively summarized
the studies on the chemoselective hydrogenation of HMF into furanyl diols in terms of different H-donors, including molecular H2, alcohols, formic acid, and other alternative
H-donors. Through the systematic survey of the previous works, a feasible research direction is discussed for the production of furanyl diols.
Type of Medium:
Online Resource
ISSN:
1385-2728
DOI:
10.2174/1385272823666190802095801
Language:
English
Publisher:
Bentham Science Publishers Ltd.
Publication Date:
2019
Permalink