In:
Advanced Synthesis & Catalysis, Wiley, Vol. 360, No. 7 ( 2018-04-03), p. 1414-1419
Abstract:
A palladium‐catalyzed cross‐coupling of α‐oxo ketene dithioacetals and bromodifluoroacetate derivatives has been developed for the synthesis of a class of CF 2 ‐containing tetra‐substituted olefins, which has potential to extend to drug design and material application. The process is proposed to involve two single electron transfer processes accompanied by an alternative loop from palladium(0) to palladium(I), likely due to unique structural properties of ketene dithioacetals with β,β‐dialkylthiol substituents on the olefin double bond. magnified image
Type of Medium:
Online Resource
ISSN:
1615-4150
,
1615-4169
DOI:
10.1002/adsc.201701554
Language:
English
Publisher:
Wiley
Publication Date:
2018
detail.hit.zdb_id:
2041384-1
detail.hit.zdb_id:
2033084-4
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