In:
Zeitschrift für Naturforschung B, Walter de Gruyter GmbH, Vol. 32, No. 6 ( 1977-6-1), p. 657-663
Abstract:
The study on the mass spectroscopic behavior of the title compounds is based on AP-measurements, the investigation of deuterated derivatives, and the analysis of chain length effects. It is shown that, among other things, the stable [M-STol] + -ions produced by 9 homologs will not enter a cyclization reaction within 10 -5 sec. The reactive [M-STol] + -species of S,S′-di-p-tolyl dithioadipate possess an abnormal fragmentation behavior (consecutive lass of CO and H 2 O), the details of which are elucidated by employment of 2 H-labelled compounds and investigation of S,S′-di-p-tolyl 2,5-dimethyldithioadipate. Obviously, the sulfur of the thiol ester group seems to play a decisive role in this and other decomposition processes.
Type of Medium:
Online Resource
ISSN:
1865-7117
,
0932-0776
DOI:
10.1515/znb-1977-0612
Language:
English
Publisher:
Walter de Gruyter GmbH
Publication Date:
1977
detail.hit.zdb_id:
2078109-X
detail.hit.zdb_id:
124635-5
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