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  • Schropp, Ruud E. I.  (3)
  • Yang, Yuzhao  (3)
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  • 1
    In: Advanced Energy Materials, Wiley, Vol. 10, No. 43 ( 2020-11)
    Abstract: Lattice matching and passivation are generally seen as the main beneficial effects in 2D/3D perovskite heterostructured solar cells, but the understanding of the mechanisms involved is still incomplete. In this work, it is shown that 2D/3D heterostructure are unstable under common thermal processing conditions, caused by the lattice expansion of strained 2D perovskite. Therefore an innovative fabrication technology involving a compressively strained PEA 2 PbI 4 layer is proposed to compensate the internal tensile strain and stabilize the 2D/3D heterostructure. Moreover, a small amount of PEA + diffusing into the grain boundaries of 3D perovskite forms 2D perovskite and passivates the defects there. Combining the effects of strain compensation and diffusion passivation, the stabilized 2D/3D perovskite solar cells deliver a reproducible and robust laboratory power conversion efficiency (PCE) of 21.31% for the p‐i‐n type devices, along with a high V OC of 1.18 V. A certified PCE of 20.22% is confirmed by an independent national metrology institute.
    Type of Medium: Online Resource
    ISSN: 1614-6832 , 1614-6840
    URL: Issue
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 2594556-7
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  • 2
    Online Resource
    Online Resource
    AIP Publishing ; 2019
    In:  APL Materials Vol. 7, No. 12 ( 2019-12-01)
    In: APL Materials, AIP Publishing, Vol. 7, No. 12 ( 2019-12-01)
    Abstract: Organic-inorganic perovskite solar cells (PSCs) have achieved an inspiring third-party-certificated power conversion efficiency (PCE) of 25.2%, which is comparable with commercialized silicon (Si) and copper indium gallium selenium solar cells. However, their notorious instability, including their deterioration at elevated temperature, is still a serious issue in commercial applications. This thermal instability can be ascribed to the high volatility and reactivity of organic compounds. As a result, solar cells based on inorganic perovskite materials have drawn tremendous attention, owing to their excellent stability against thermal stress. In the last few years, PSCs based on inorganic perovskite materials have seen an astonishing development. In particular, CsPbI3 and CsPbI2Br PSCs demonstrated outstanding PCEs, exceeding 18% and 16%, respectively. In this review, we systematically discuss the properties of inorganic perovskite materials and the device configuration of inorganic PSCs as well as review the progress in PCE and stability. Encouragingly, all-inorganic PSCs, in which all functional layers are inorganic, provide a feasible approach to overcome the thermal instability issue of traditional organic-inorganic PSCs, leading to new perspectives toward commercial production of PSCs.
    Type of Medium: Online Resource
    ISSN: 2166-532X
    Language: English
    Publisher: AIP Publishing
    Publication Date: 2019
    detail.hit.zdb_id: 2722985-3
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  • 3
    In: Advanced Materials, Wiley, Vol. 32, No. 8 ( 2020-02)
    Abstract: Although inorganic perovskite solar cells (PSCs) are promising in thermal stability, their large open‐circuit voltage ( V OC ) deficit and difficulty in large‐area preparation still limit their development toward commercialization. The present work tailors C 60 via a codoping strategy to construct an efficient electron‐transporting layer (ETL), leading to a significant improvement in V OC of the inverted inorganic CsPbI 2 Br PSC. Specifically, tris(pentafluorophenyl)borane (TPFPB) is introduced as a dopant to lower the lowest unoccupied molecular orbital (LUMO) level of the C 60 layer by forming a Lewis acidic adduct. The enlarged free energy difference provides a favorable enhancement in electron injection and thereby reduces charge recombination. Subsequently, a nonhygroscopic lithium salt (LiClO 4 ) is added to increase electron mobility and conductivity of the film, leading to a reduction in the device hysteresis and facilitating the fabrication of a large‐area device. Finally, the as‐optimized inorganic CsPbI 2 Br PSCs gain a champion power conversion efficiency (PCE) of 15.19%, with a stabilized power output (SPO) of 14.21% (0.09 cm 2 ). More importantly, this work also demonstrates a record PCE of 14.44% for large‐area inorganic CsPbI 2 Br PSCs (1.0 cm 2 ) and reports the first inorganic perovskite solar module with the excellent efficiency exceeding 12% (10.92 cm 2 ) by a self‐developed quasi‐curved heating method.
    Type of Medium: Online Resource
    ISSN: 0935-9648 , 1521-4095
    URL: Issue
    RVK:
    Language: English
    Publisher: Wiley
    Publication Date: 2020
    detail.hit.zdb_id: 1474949-X
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