In:
Organic Chemistry Frontiers, Royal Society of Chemistry (RSC), Vol. 10, No. 15 ( 2023), p. 3732-3740
Abstract:
Diphosphine ligands are highly popular but costly toolkit in organic chemistry. In this study, we disclose a modular approach for cis -diphosphinoalkenes and diphosphine ligand libraries. It experimentally features a concerted addition process, 1,4-O/S migration, and the construction of cis -only diphosphinoalkenes in a five-membered ring (C–P–O–P–C) manner. This modular assembly approach should contribute to the stereoselective establishment of a greater diphosphine ligand library of compounds, including DPPENs, DPPEs, and beyond.
Type of Medium:
Online Resource
ISSN:
2052-4129
Language:
English
Publisher:
Royal Society of Chemistry (RSC)
Publication Date:
2023
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