In:
European Journal of Inorganic Chemistry, Wiley, Vol. 2008, No. 28 ( 2008-10), p. 4404-4412
Abstract:
Three copper(II) complexes with a binucleating N 2 O donor ligand, [Cu 2 (L 1 )(μ 2 ‐pz)(CH 3 COO) 2 ] ( 1 ), [Cu 4 ( L 1 ) 2 (μ 4 ‐O)(μ 2 ‐CH 3 COO) 2 (μ 1,1 ‐N 3 )(N 3 )] ( 2 ), and [Cu 2 (L 2 )(μ 1,1 ‐N 3 )(μ 1,3 ‐N 3 ) 2 ] ∞ ( 3 ) [pz = pyrazolato, HL 1 = 2,6‐bis(morpholinomethyl)‐4‐ tert ‐butylphenol and HL 2 = 2,6‐bis(morpholinomethyl)‐4‐methylphenol] have been synthesized and characterized by elemental analysis, FTIR and UV/Vis spectroscopy, and X‐ray crystallography. X‐ray crystallographic studies revealed that a series of di‐, tetra‐, and polynuclear complexes have been formed by varying the bridging ligand, counteranion, and reaction conditions. These show effective catalytic properties for the hydrogen peroxide oxidation of toluene and benzene. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
Type of Medium:
Online Resource
ISSN:
1434-1948
,
1099-0682
DOI:
10.1002/ejic.v2008:28
DOI:
10.1002/ejic.200800556
Language:
English
Publisher:
Wiley
Publication Date:
2008
detail.hit.zdb_id:
1475009-0
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