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  • Ramakrishnan, Balasubramanian  (6)
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  • 1
    Online Resource
    Online Resource
    Royal Society of Chemistry (RSC) ; 2022
    In:  Environmental Science: Processes & Impacts Vol. 24, No. 12 ( 2022), p. 2217-2236
    In: Environmental Science: Processes & Impacts, Royal Society of Chemistry (RSC), Vol. 24, No. 12 ( 2022), p. 2217-2236
    Abstract: Certain chemicals/materials that are contaminants of emerging concern (CECs) have been widely detected in water bodies and terrestrial systems worldwide while other CECs occur at undetectable concentrations. The primary sources of CECs in farmlands are agricultural inputs, such as wastewater, biosolids, sewage sludge, and agricultural mulching films. The percent increase in cropland area during 1950–2016 was 30 and the rise in land use for food crops during 1960–2018 was 100–500%, implying that there could be a significant CEC burden in farmlands in the future. In fact, the alarming concentrations (μg kg −1 ) of certain CECs such as PBDEs, PAEs, and PFOS that occur in farmlands are 383, 35 400 and 483, respectively. Also, metal nanoparticles are reported even at the mg kg −1 level. Chronic root accumulation followed by translocation of CECs into plants results in their detectable concentrations in the final plant produce. Thus, there is a continuous flow of CECs from farmlands to agricultural produce, causing a serious threat to the terrestrial food chain. Consequently, CECs find their way to the human body directly through CEC-laden plant produce or indirectly via the meat of grazing animals. Thus, human health could be at the most critical risk since several CECs have been shown to cause cancers, disruption of endocrine and cognitive systems, maternal–foetal transfer, neurotoxicity, and genotoxicity. Overall, this comprehensive review provides updated information on contamination of chemicals/materials of concern in farmlands globally, sources for their entry, uptake by crop plants, and their likely impact on the terrestrial food chain and human health.
    Type of Medium: Online Resource
    ISSN: 2050-7887 , 2050-7895
    Language: English
    Publisher: Royal Society of Chemistry (RSC)
    Publication Date: 2022
    detail.hit.zdb_id: 2703791-5
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  • 2
    Online Resource
    Online Resource
    Royal Society of Chemistry (RSC) ; 2022
    In:  RSC Advances Vol. 12, No. 20 ( 2022), p. 12396-12415
    In: RSC Advances, Royal Society of Chemistry (RSC), Vol. 12, No. 20 ( 2022), p. 12396-12415
    Abstract: Soil pollution by the contaminants of emerging concern (CECs) or emerging contaminants deserves attention worldwide because of their toxic health effects and the need for developing regulatory guidelines. Though the global soil burden by certain CECs is in several metric tons, the source-tracking of these contaminants in soil environments is difficult due to heterogeneity of the medium and complexities associated with the interactive mechanisms. Most CECs have higher affinities towards solid matrices for adsorption. The CECs alter not only soil functionalities but also those of plants and animals. Their toxicities are at nmol to μmol levels in cell cultures and test animals. These contaminants have a higher propensity in accumulating mostly in root-based food crops, threatening human health. Poor understanding on the fate of certain CECs in anaerobic environments and their transfer pathways in the food web limits the development of effective bioremediation strategies and restoration of the contaminated soils and endorsement of global regulatory efforts. Despite their proven toxicities to the biotic components, there are no environmental laws or guidelines for certain CECs. Moreover, the information available on the impact of soil pollution with CECs on human health is fragmentary. Therefore, we provide here a comprehensive account on five significantly important CECs, viz. , (i) PFAS, (ii) micro/nanoplastics, (iii) additives (biphenyls, phthalates), (iv) novel flame retardants, and (v) nanoparticles. The emphasis is on (a) degree of soil burden of CECs and the consequences, (b) endocrine disruption and immunotoxicity, (c) genotoxicity and carcinogenicity, and (d) soil health guidelines.
    Type of Medium: Online Resource
    ISSN: 2046-2069
    Language: English
    Publisher: Royal Society of Chemistry (RSC)
    Publication Date: 2022
    detail.hit.zdb_id: 2623224-8
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  • 3
    Online Resource
    Online Resource
    Royal Society of Chemistry (RSC) ; 2023
    In:  Environmental Science: Advances Vol. 2, No. 4 ( 2023), p. 586-611
    In: Environmental Science: Advances, Royal Society of Chemistry (RSC), Vol. 2, No. 4 ( 2023), p. 586-611
    Abstract: Microalgae are a source of scientific curiosity and inspiration for their utilization as ‘inoculants’ in agriculture and the commercial production of high-value products. Their diversity and abundance in the soil environment highlight the fact that these integral members of the soil microbial community modify the physical and chemical conditions of soils and interact with other microorganisms and even with higher plants with varying degrees of association. However, to date, the agronomic benefits of the nitrogen fixation trait of cyanobacteria have not been fully realized. Thus, the ecological functions of these organisms in the biological soil crusts should be thoroughly evaluated and widely applied given that climate change events can increase desertification. Currently, the crop yield increments and pest control due to these biostimulants and the reclamation of saline and sodic soils by these bioameliorants are considered economically marginal. Similarly, the carbon capture and storage by eukaryotic microalgae and cyanobacteria in soils are poorly understood. Limitations in their commercial production for agricultural use include inadequate technological innovations and the enormous expectation for yield increments, together with the contemporary monetization of their environmental benefits. Thus, this critical review presents the desirable reappraisal of their agronomic benefits and the invigoration of research and culture collections to utilize these organisms or their metabolites, considering the evolutionary consequences and environmental advantages and finally their commercial production for widespread application in agriculture.
    Type of Medium: Online Resource
    ISSN: 2754-7000
    Language: English
    Publisher: Royal Society of Chemistry (RSC)
    Publication Date: 2023
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  • 4
    Online Resource
    Online Resource
    Elsevier BV ; 2021
    In:  Science of The Total Environment Vol. 769 ( 2021-05), p. 145079-
    In: Science of The Total Environment, Elsevier BV, Vol. 769 ( 2021-05), p. 145079-
    Type of Medium: Online Resource
    ISSN: 0048-9697
    RVK:
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2021
    detail.hit.zdb_id: 1498726-0
    detail.hit.zdb_id: 121506-1
    SSG: 12
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  • 5
    In: Soil Systems, MDPI AG, Vol. 7, No. 1 ( 2023-02-24), p. 19-
    Abstract: The presence of microplastics and nanoplastics (MNPs) in soils is becoming pervasive in most agroecosystems. The recent estimates suggest that the soil burden of MNPs in the agroecosystems is more than 0.5 megatons (Mt) annually. In all the agroecosystems, the transformation, migration, and transferring of MNPs, along with other contaminants, and the trophic transfer of MNPs can threaten the food web. MPs can exhibit negative and positive effects, or none, on the physical/chemical properties of soil, soil microbiota, invertebrates, and plant systems, depending on the polymer compositions, additives, and exposure time. Difficulties in comparing the studies on the effects of MNPs, as well as the discrepancies among them, are mostly due to variations in the methods followed for sampling, detection, quantification, and the categorization of particles, abundance, and exposure time. Since agricultural soils are important environmental reservoirs for diverse chemicals and contaminants, they provide milieus for several types of interactions of MNPs with soil biota. The present review critically examines the sources and transformation of MNPs in agricultural soils, the release and fate of additives, as well as their role as vectors of other potential contaminants and influence on soil physical/chemical properties, toxicities to soil biota (i.e., microorganisms, invertebrates, and plants), current regulatory guidelines for the mitigation of MNPs, and future research directions.
    Type of Medium: Online Resource
    ISSN: 2571-8789
    Language: English
    Publisher: MDPI AG
    Publication Date: 2023
    detail.hit.zdb_id: 2932897-4
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  • 6
    In: Environmental Advances, Elsevier BV, Vol. 5 ( 2021-10), p. 100091-
    Type of Medium: Online Resource
    ISSN: 2666-7657
    Language: English
    Publisher: Elsevier BV
    Publication Date: 2021
    detail.hit.zdb_id: 3052479-9
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