In:
Chemistry – A European Journal, Wiley, Vol. 9, No. 3 ( 2003-02-03), p. 591-591
Abstract:
The cover picture shows the molecular structure of an azido‐substituted hexabenzylhexaazaisowurtzitane (carbon: red, nitrogen: blue). The hexaazaisowurtzitane cage system, a 2,4,6,8,10,12‐hexaazatetracyclo[5.5.0.0 5,9 .0 3,11 ]dodecane, consists, just as this shown derivative, entirely of carbon, nitrogen and hydrogen (omitted in this image). The synthesis of hexaazaisowurtzitanes is limited solely to the condensation of certain benzylamines with glyoxal. Further derived hexaazaisowurtzitanes exhibit properties that are useful for the possible application as energetic materials and/or propellants (see background). An investigation of the influence of azido‐ and fluoro‐substituted benzyl amines on the formation of this cage system is described by T. M. Klapötke, B. Krumm et al. on p. 687 ff.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.200390069
Language:
English
Publisher:
Wiley
Publication Date:
2003
detail.hit.zdb_id:
1478547-X
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