In:
Angewandte Chemie, Wiley, Vol. 128, No. 2 ( 2016-01-11), p. 734-737
Abstract:
Dioxygen‐tolerant [NiFe] hydrogenases catalyze not only the conversion of H 2 into 2 H + and 2 e − but also the reduction of O 2 to H 2 O. Chemists have sought to mimic such bifunctional catalysts with structurally simpler compounds to facilitate analysis and improvement. Herein, we report a new [NiFe]‐based catalyst for O 2 reduction via an O 2 adduct. Structural investigations reveal the first example of a side‐on iron(IV) peroxo complex.
Type of Medium:
Online Resource
ISSN:
0044-8249
,
1521-3757
DOI:
10.1002/ange.201507022
Language:
German
Publisher:
Wiley
Publication Date:
2016
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514305-6
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505872-7
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1479266-7
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506259-7
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