In:
Chemistry – A European Journal, Wiley, Vol. 26, No. 6 ( 2020-01-27), p. 1278-1285
Abstract:
The reaction of Fe(OAc) 2 and Hbpypz with neutral TCNQ results in the formation of [Fe 2 (bpypz) 2 (TCNQ) 2 ](TCNQ) 2 ( 1 ), in which Hbpypz=3,5‐bis(2‐pyridyl)pyrazole and TCNQ=7,7′,8,8′‐tetracyano‐ p ‐quinodimethane. Crystal packing of 1 with uncoordinated TCNQ and π–π stacking of bpypz − ligands produces an extended two‐dimensional supramolecular coordination assembly. Temperature dependence of the dc magnetic susceptibility and heat capacity measurements indicate that 1 undergoes an abrupt spin crossover (SCO) with thermal spin transition temperatures of 339 and 337 K for the heating and cooling modes, respectively, resulting in a thermal hysteresis of 2 K. Remarkably, the temperature dependence of dc electrical transport exhibits a transition that coincides with thermal SCO, demonstrating the thermally induced magnetic and electrical bistability of 1 , strongly correlating magnetism with electrical conductivity. This outstanding feature leads to thermally induced simultaneous switching of magnetism and electrical conductivity and a magnetoresistance effect.
Type of Medium:
Online Resource
ISSN:
0947-6539
,
1521-3765
DOI:
10.1002/chem.201903934
Language:
English
Publisher:
Wiley
Publication Date:
2020
detail.hit.zdb_id:
1478547-X
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