In:
The Journal of Chemical Physics, AIP Publishing, Vol. 36, No. 2 ( 1962-01-15), p. 406-412
Abstract:
Thermodynamic data obtained for 3,3-dimethyl-2-thiabutane (methyl t-butyl sulfide) were used to determine the heights of the barriers hindering internal rotation in the molecule. The chemical thermodynamic properties in the ideal gas state (0 to 1000°K) were calculated from calorimetric, spectroscopic, and molecular structure information. Experimental studies provided the following information: values of heat capacity for the solid (15°K to the triple point), the liquid (triple point to 364°K), and the vapor (360 to 500°K); the triple point temperature; the heat of fusion; thermodynamic functions for the solid and liquid (0 to 355°K); heat of vaporization (330 to 372°K); parameters of the equation of state; vapor pressure (307 to 410°K); and the standard heat of formation at 298.15°K.
Type of Medium:
Online Resource
ISSN:
0021-9606
,
1089-7690
Language:
English
Publisher:
AIP Publishing
Publication Date:
1962
detail.hit.zdb_id:
3113-6
detail.hit.zdb_id:
1473050-9
Permalink