In:
Polymers and Polymer Composites, SAGE Publications, Vol. 19, No. 6 ( 2011-07), p. 451-458
Abstract:
The effects of solution temperature and molecular weight on the rheological responses of poly(vinyl alcohol) (PVA) semidilute solutions (13 g/dL- 19 g/dL) in dimethyl sulfoxide (DMSO) have been studied using PVA with two different number-average degrees of polymerization (P n ): 1700 and 4000. For the rheological experiments using dynamic shear, the PVA solution with a P n of 1700 showed rather simple Newtonian fluid behaviour, whereas that with P n of 4000 exhibited non-Newtonian shear thinning behaviour. Steady shear rheology experiments suggested that the lower P n PVA solutions were Newtonian fluids, which is consistent with the dynamic shear rheology results. However, an abrupt decrease of shear viscosity at high shear rates was observed for the higher P n PVA solutions at lower temperatures, such as 30 °C and 50 °C. At higher temperatures of 70 °C and 90 °C, the higher molecular weight PVA solutions exhibited simple shear thinning behaviour without any further complications of flow instability. The fact that temperature plays a critical role in controlling the observed flow instability of the PVA solutions in DMSO strongly suggests that there exist enhanced inter-chain interactions by hydrogen bonding of PVA chains beyond the chain entanglements, particularly for the higher P n PVA semidilute solutions at low temperatures. Therefore, it is important to consider both chain entanglements and hydrogen bonding interactions in order to process PVA solutions without causing undesirable flow instability.
Type of Medium:
Online Resource
ISSN:
0967-3911
,
1478-2391
DOI:
10.1177/096739111101900602
Language:
English
Publisher:
SAGE Publications
Publication Date:
2011
detail.hit.zdb_id:
2099644-5
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