In:
Applied Organometallic Chemistry, Wiley, Vol. 29, No. 11 ( 2015-11), p. 736-738
Abstract:
A simple, yet efficient system for PdCl 2 /CuI to catalyze the homo‐coupling reactions of various terminal alkynes has been developed using 3‐(diphenylphosphino)propanoic acid as ligand in the presence of oxygen. The alkynes, including aromatic, heteroaromatic and aliphatic alkynes, were transformed at room temperature into the corresponding 1,3‐diynes in moderate to excellent yields. The turnover number was up to 1.04 × 10 3 . Copyright © 2015 John Wiley & Sons, Ltd.
Type of Medium:
Online Resource
ISSN:
0268-2605
,
1099-0739
Language:
English
Publisher:
Wiley
Publication Date:
2015
detail.hit.zdb_id:
1480791-9
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