In:
Advanced Functional Materials, Wiley, Vol. 31, No. 15 ( 2021-04)
Abstract:
Electrocatalytic water splitting for the production of hydrogen proves to be effective and available. In general, the thermal radiation synthesis usually involves a slow heating and cooling process. Here, a high‐frequency induction heating (IH) is employed to rapidly prepare various self‐supported electrocatalysts grown on Ni foam (NF) in liquid‐ and gas‐phase within 1–3 min. The NF not only serves as an in situ heating medium, but also as a growth substrate. The as‐synthesized Ni nanoparticles anchored on MoO 2 nanowires supported on NF (Ni‐MoO 2 /NF‐IH) enable catalysis of hydrogen evolution reaction (HER), showing a low overpotential of −39 mV (10 mA cm −2 ) and maintaining the stability of 12 h in alkaline condition. Moreover, the NiFe layered double hydroxide (NiFe LDH/NF‐IH) is also synthesized via IH and affords outstanding oxygen evolution reaction (OER) activity with an overpotential of 246 mV (10 mA cm −2 ). The Ni‐MoO 2 /NF‐IH and NiFe LDH/NF‐IH are assembled to construct a two‐electrode system, where a small cell voltage of ≈1.50 V enables a current density of 10 mA cm −2 . More importantly, this IH method is also available to rapidly synthesize other freestanding electrocatalysts on NF, such as transition metal hydroxides and metal nitrides.
Type of Medium:
Online Resource
ISSN:
1616-301X
,
1616-3028
DOI:
10.1002/adfm.202009580
Language:
English
Publisher:
Wiley
Publication Date:
2021
detail.hit.zdb_id:
2029061-5
detail.hit.zdb_id:
2039420-2
SSG:
11
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